Chinese english Japanese Germany Korea
ChemicalBook > Product Catalog >Organic Chemistry >Hydrocarbons and derivatives >Hydrocarbon sulfonate >4-Acetamidobenzenesulfonyl azide

4-Acetamidobenzenesulfonyl azide

4-Acetamidobenzenesulfonyl azide Structure
CAS No.
2158-14-7
Chemical Name:
4-Acetamidobenzenesulfonyl azide
Synonyms
P-ABSA;P-ACETAMIDOBENZENESULFONYL AZIDE;N-(4-azidosulfonylphenyl)acetamide;DKSI122;DKFELEX0337;4-AcetamidobenzenesuL;4-acetamidobenzenesulphon;4-Acetamidobenzenesulfonyl;4-ACETAMIDENZENESULFONYLAZIDE;Acetaminobenzenesulfonyl azide
CBNumber:
CB8746801
Molecular Formula:
C8H8N4O3S
Molecular Weight:
240.24
MOL File:
2158-14-7.mol
MSDS File:
SDS
Modify Date:
2025/1/27 9:38:02
Request For Quotation

4-Acetamidobenzenesulfonyl azide Properties

Melting point 107-111 °C (lit.)
storage temp. 2-8°C
form powder to crystal
color White to Amber to Dark purple
Water Solubility Insoluble in water.
BRN 2219568
InChI InChI=1S/C8H8N4O3S/c1-6(13)10-7-2-4-8(5-3-7)16(14,15)12-11-9/h2-5H,1H3,(H,10,13)
InChIKey NTMHWRHEGDRTPD-UHFFFAOYSA-N
SMILES C1(S(=O)(=O)N=[N+]=[N-])=CC=C(NC(=O)C)C=C1
CAS DataBase Reference 2158-14-7(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
HS Code  29350090
NFPA 704
1
2 0

4-Acetamidobenzenesulfonyl azide price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 404764 4-Acetamidobenzenesulfonyl azide 97% 2158-14-7 5G ₹1948.5 2022-06-14 Buy
Sigma-Aldrich(India) 404764 4-Acetamidobenzenesulfonyl azide 97% 2158-14-7 25G ₹6440.88 2022-06-14 Buy
TCI Chemicals (India) A1786 4-Acetamidobenzenesulfonyl Azide 2158-14-7 5G ₹2400 2022-05-26 Buy
TCI Chemicals (India) A1786 4-Acetamidobenzenesulfonyl Azide 2158-14-7 25G ₹6800 2022-05-26 Buy
TCI Chemicals (India) A1786 4-Acetamidobenzenesulfonyl Azide 2158-14-7 100G ₹16500 2022-05-26 Buy
Product number Packaging Price Buy
404764 5G ₹1948.5 Buy
404764 25G ₹6440.88 Buy
A1786 5G ₹2400 Buy
A1786 25G ₹6800 Buy
A1786 100G ₹16500 Buy

4-Acetamidobenzenesulfonyl azide Chemical Properties,Uses,Production

Uses

4-Acetamidobenzenesulfonyl azide is used as a hydroazidation catalyst for facile preparation of organoazides. It is used as a reagent for synthesis of: monosaccharide-derived alcohols, a late-stage intermolecular C-H olefination, intramolecular isomuenchnone cycloaddition approach to antitumor agents, rhodium-catalyzed carbene cyclization cycloaddition cascade reaction of vinylsulfonates and Suzuki-Miyaura cross coupling reaction.

Synthesis

To a solution of CCA(0.1548 g, 0.6 mmol) in tetrahydrofuran (3-5 mL), PPh3 (0.5246 g, 2 mmol)was added at 0-5°C with stirring. A white suspension was formed to which p-toluenesulfonic acid (0.1720 g, 1 mmol) was added and stirring continued for 15 min. NaN3 (0.065 g, 1 mmol) was added and the temperature was raised up to room temperature. Stirring was continued for 1 min at room temperature. After completion of the reaction (TLC), the reaction mixture was concentrated, washed with EtOAc (4-6 mL), and cold distilled water (5 mL). The organic layer was dried with anhydrous Na2SO4, passed through a short silica-gel column using n-hexane/ethylacetate (10/1) as eluent. 4-Acetamidobenzenesulfonyl azide was obtained after removing the solvent under reduced pressure.
4-Acetamidobenzenesulfonyl azide

structure and hydrogen bonding

Under ambient conditions, 4-acetamidobenzenesulfonyl azide (4-ABSA) belongs to a monoclinic structure with a P21 space group and cell parameters of a = 8.0529 Å, b = 22.988 Å, c = 8.3123 Å, β=93.534°, respectively. The hydrogen-bonding interactions allow molecules to pair up and form π-stacked dimers. The studies of NH4N3 have reported that the hydrogen bonds are affected by the rotation of azide ions with increasing pressure. The cooperativity of hydrogen bonds and π-stacking interactions allow 4-ABSA to become an attractive candidate for studying the influence of non-covalent interactions within the organic azides in the compression process. In addition, the bent azide groups of 4-ABSA are crucial for electron orbit hybridization and nitrogen polymerization.

References

[1] Junru Jiang. “High-Pressure Studies of 4-Acetamidobenzenesulfonyl Azide: Combined Raman Scattering, IR Absorption, and Synchrotron X-ray Diffraction Measurements.” The Journal of Physical Chemistry B 120 46 (2016): 12015–12022.

4-Acetamidobenzenesulfonyl azide Preparation Products And Raw materials

Raw materials

N-acetylsulphanilic acid N-Acetylsulfanilyl chloride

Preparation Products

4-Acetamidobenzenesulfonamide 2-Diazomalonic acid ditert-butyl ester

4-Acetamidobenzenesulfonyl azide Suppliers

Global( 316)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
GLR Innovations +91 9891111994 New Delhi, India 4535 58 Inquiry
REDDY N REDDY PHARMACEUTICALS +91-9848096759 +91-9848096759 Hyderabad, India 1989 58 Inquiry
Innovative Labs +91-9885794886 +91-9885794886 Telangana, India 219 58 Inquiry
Sakam Finechem Pvt., Ltd. 91-40-40271222 Hyderabad, India 556 58 Inquiry
Vihasifinechem Pvt Ltd -40110230 Hyderabad, India 29 58 Inquiry
Ms Life Sciences 08048372386Ext 826 Hyderabad, India 341 58 Inquiry
Innovative Labs 91--9885794886 Mallapur, India 110 58 Inquiry
Vihasibio Sciences Private Limited -40110230 Hyderabad, India 391 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6768 58 Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6905 58 Inquiry
Supplier Advantage
GLR Innovations 58
REDDY N REDDY PHARMACEUTICALS 58
Innovative Labs 58
Sakam Finechem Pvt., Ltd. 58
Vihasifinechem Pvt Ltd 58
Ms Life Sciences 58
Innovative Labs 58
Vihasibio Sciences Private Limited 58
TCI Chemicals (India) Pvt. Ltd. 58
Alfa Aesar 58

Related articles

4-Acetamidobenzenesulfonyl azide Spectrum

4-Acetamidobenzenesulfonyl azide(2158-14-7)IR14-Acetamidobenzenesulfonyl azide(2158-14-7)IR2

2158-14-7(4-Acetamidobenzenesulfonyl azide)Related Search:

Azidotrimethylsilane Diphenylphosphoryl azide 2,4,6-Triisopropylbenzene-sulfonyl azide Tetrabutylammonium azide N-Acetylsulfanilyl chloride
Sulfosulfuron P-AMINOBENZAMIDE GLUTAMIC ACID Sulfanilamide Dimethyl sulfone Sodium azide
Hydrazoic acid 4-Acetamidobenzenesulfonamide Aniline 4-ETHYLAMINO-BENZENESULFONAMIDE Azide
4-Acetamidobenzenesulfonyl azide
chevron_left

1of4

chevron_right
4-ACETYLAMINOBENZENESULFONYL AZIDE 4-acetamidobenzenesulphon 4-ACETAMIDENZENESULFONYLAZIDE 4-Acetamidobenzenesulfonyl azide,p-ABSA 4-acetaMidobenzene-1-sulfonyl azide 4-(Acetylamino)benzenesulphonyl azide, 4-(Azidosulphonyl)acetanilide, p-ABSA Benzenesulfonyl azide, 4-(acetylaMino)- 4-AcetaMidobenzenesulfonyl azide 97% 4-ACETAMIDOBENZENESULPHONYL AZIDE 4-ACETAMIDOBENZENESULFONYL AZIDE 4-AcetamidobenzenesulfonylAzide> 4-Acetamidobenzenesulfonyl azide, 97%, for synthesis 4-AcetamidobenzenesuL 4-Acetamidobenzenesulfonyl azide ISO 9001：2015 REACH TIANFUCHEM--2158-14-7---4-Acetamidobenzenesulfonyl azide N-(4-azidosulfonylphenyl)acetamide P-ABSA P-ACETAMIDOBENZENESULFONYL AZIDE 4-Acetamidobenzenesulfonyl Acetaminobenzenesulfonyl azide P-acetylaminobenzenesulfonyl azide DKFELEX0337 DKSI122 2158-14-7 C8H8N4O3S C8subH8N4O3S C9H9N4O3S CH3CONHC6H4SO2N3 C-X Bond Formation (Non-Halogen) Synthetic Reagents Azidation/Diazo Transfer Benzene derivates Pyridines