Diisopropyl azodicarboxylate
![Diisopropyl azodicarboxylate Structure](CAS/GIF/2446-83-5.gif)
- CAS No.
- 2446-83-5
- Chemical Name:
- Diisopropyl azodicarboxylate
- Synonyms
- DIAD;diisopropyl azodiformate;Diisopropyl diazene-1,2-dicarboxylate;AZODICARBONIC ACID DIISOPROPYL ESTER;(E)-diisopropyl diazene-1,2-dicarboxylate;Propan-2-yl N-propan-2-yloxycarbonyliminocarbamate;Diisopropyl azodicarboxylate [DIAD];AZODICARBOXYLIC ACID DIISOPROPYL ESTER;Diisop;JACS-2446-83-5
- CBNumber:
- CB8764409
- Molecular Formula:
- C8H14N2O4
- Molecular Weight:
- 202.21
- MOL File:
- 2446-83-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/25 20:04:51
Melting point | 3-5 °C |
---|---|
Boiling point | 75 °C/0.25 mmHg (lit.) |
Density | 1.027 g/mL at 25 °C (lit.) |
vapor pressure | 1.04 hPa (20 °C) |
refractive index |
n |
Flash point | 223 °F |
storage temp. | Store below +30°C. |
solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) |
form | Liquid |
color | Clear to slightly turbid yellow-orange to red |
Water Solubility | insoluble |
Sensitive | Light Sensitive |
BRN | 1912326 |
CAS DataBase Reference | 2446-83-5(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() ![]() GHS07,GHS08,GHS09 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335-H351-H411 | |||||||||
Precautionary statements | P202-P261-P273-P302+P352-P305+P351+P338-P308+P313 | |||||||||
Hazard Codes | Xn,Xi,N,F | |||||||||
Risk Statements | 36/38-51/53-5-43-36/37/38-11-48/20/22-40 | |||||||||
Safety Statements | 36-61-47A-36/37/39-29-26-16-60-36/37 | |||||||||
RIDADR | UN 3082 9/PG 3 | |||||||||
WGK Germany | 1 | |||||||||
F | 4.10-8 | |||||||||
Hazard Note | Harmful/Irritant | |||||||||
HazardClass | 9 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29270000 | |||||||||
NFPA 704 |
|
Diisopropyl azodicarboxylate price More Price(10)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 225541 | Diisopropyl azodicarboxylate 98% | 2446-83-5 | 5G | ₹2662.95 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 225541 | Diisopropyl azodicarboxylate 98% | 2446-83-5 | 25G | ₹3225.85 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 225541 | Diisopropyl azodicarboxylate 98% | 2446-83-5 | 100G | ₹6495 | 2022-06-14 | Buy |
TCI Chemicals (India) | A1246 | Diisopropyl Azodicarboxylate (40% in Toluene, ca. 1.9mol/L) | 2446-83-5 | 25G | ₹2000 | 2022-05-26 | Buy |
TCI Chemicals (India) | A1246 | Diisopropyl Azodicarboxylate (40% in Toluene, ca. 1.9mol/L) | 2446-83-5 | 100G | ₹5100 | 2022-05-26 | Buy |
Diisopropyl azodicarboxylate Chemical Properties,Uses,Production
Chemical Properties
CLEAR ORANGE LIQUID
Uses
Diisopropyl Azodicarboxylate is an azodicarboxylic acid derivative used as a reagent in the production of many organic compounds. Diisopropyl Azodicarboxylate is commonly used as an oxidizer in Mitsun obu reactions and can also serve as a selective deprotectant of N-benzyl groups in the presence of other protecting groups.
General Description
Reacted with dioxaphosphorinanes and iron catalyst to generate rearranged phosphonium ylide products.
Purification Methods
Purify the azo compound by distillation at as high a vacuum as possible. Since it is likely to explode, use an oil bath for heating the still, and all operations should be carried out behind an adequate shield. [Kauer Org Synth Coll Vol IV 412 1963, Beilstein 3 III 233]. This reagent is useful in the Mitsunobu reaction [Mitsunobu Synthesis 1 1981, Gennari et al. J Am Chem Soc 108 6394 1986, Evans et al. J Am Chem Soc 108 6394 1986, Hughes Org React 42 335 1992, Dodge et al. Org Synth 73 110 1996, Hughes Org Prep Proc Int 28 127 1996, Ferguson & Marcelle J Am Chem Soc 128 4576 2006; see also di-tert-butyl azodicarboxylate and DEAD above].
Diisopropyl azodicarboxylate Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
BTC pharm India | +918790379245 | AndhraPradesh, India | 1269 | 58 | Inquiry |
V B Organics | +91-9912996647 +91-9912996647 | Telangana, India | 13 | 58 | Inquiry |
NSR Laboratories Pvt. Ltd. | +91-9866989891 +91-9000457345 | Hyderabad, India | 196 | 58 | Inquiry |
Vardhaman P Golechha | 9704422000 | Telangana, India | 294 | 58 | Inquiry |
Sris Synthesis Pvt Ltd., | +91-9989522441 +91-9989522441 | Hyderabad, India | 282 | 58 | Inquiry |
GMFC LABS PVT LTD | +91-9133370278 +91-9133370278 | Hyderabad, India | 44 | 58 | Inquiry |
AMINO ORGANICS | +919866989891 | Hyderabad, India | 275 | 58 | Inquiry |
JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
SYNGENESIS CHEMSCIENCE PRIVATE LIMITED | +91-9067779401 +91-9067779401 | Maharashtra, India | 58 | 58 | Inquiry |
Tosco Pharmachem Pvt Ltd | +91-9573336677 +91-9573336677 | Telangana, India | 49 | 58 | Inquiry |
Supplier | Advantage |
---|---|
BTC pharm India | 58 |
V B Organics | 58 |
NSR Laboratories Pvt. Ltd. | 58 |
Vardhaman P Golechha | 58 |
Sris Synthesis Pvt Ltd., | 58 |
GMFC LABS PVT LTD | 58 |
AMINO ORGANICS | 58 |
JSK Chemicals | 58 |
SYNGENESIS CHEMSCIENCE PRIVATE LIMITED | 58 |
Tosco Pharmachem Pvt Ltd | 58 |
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