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Tetramethylammonium borohydride

Tetramethylammonium borohydride Structure
CAS No.
16883-45-7
Chemical Name:
Tetramethylammonium borohydride
Synonyms
TMAB;Nsc164901;BISMUTH(III) SUBNITRATE 98%;tetramethylammoniumborohydrate;TETRAMETHYLAMMONIUM BOROHYDRIDE;Tetramethylammoniumborohydride,95%;Tetra-methyl ammonium boron hydride;TetraMethylaMMoniuM borohydride 95%;Tetramethylammonium Borohydride Tetramethylammonium borohydride,TMAB
CBNumber:
CB9101342
Molecular Formula:
C4H16BN
Molecular Weight:
88.99
MOL File:
16883-45-7.mol
Modify Date:
2023/6/8 17:06:35

Tetramethylammonium borohydride Properties

Melting point 150°C (dec.)
Density 0,813 g/cm3
storage temp. 2-8°C
Water Solubility almost transparency in Water
form crystal
Specific Gravity 0.813
color white
Sensitive Moisture Sensitive
BRN 3684968
EPA Substance Registry System Methanaminium, N,N,N-trimethyl-, tetrahydroborate(1-) (16883-45-7)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS06
Signal word  Danger
Hazard statements  H261-H301-H315-H319
Precautionary statements  P223-P231+P232-P264-P301+P310-P302+P352-P305+P351+P338
Hazard Codes  F,T,Xi
Risk Statements  15-25-36/38-36/37/38
Safety Statements  26-36/37/39-43-45-36
RIDADR  UN 3134 4.3/PG 2
WGK Germany  3
RTECS  BS8310000
TSCA  Yes
HS Code  2942.00.5000
HazardClass  4.3
PackingGroup  I
NFPA 704
3
3 2
W

Tetramethylammonium borohydride price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 310689 Tetramethylammonium borohydride 95% 16883-45-7 10G ₹1266.53 2022-06-14 Buy
Sigma-Aldrich(India) 310689 Tetramethylammonium borohydride 95% 16883-45-7 10G ₹1266.53 2022-06-14 Buy
Sigma-Aldrich 310689 Tetramethylammonium borohydride 95% 16883-45-7 50G ₹6354.28 2022-06-14 Buy
Sigma-Aldrich(India) 310689 Tetramethylammonium borohydride 95% 16883-45-7 50G ₹6354.28 2022-06-14 Buy
TCI Chemicals (India) T0852 Tetramethylammonium Borohydride [Reducing Reagent] 16883-45-7 5G ₹2300 2022-05-26 Buy
Product number Packaging Price Buy
310689 10G ₹1266.53 Buy
310689 10G ₹1266.53 Buy
310689 50G ₹6354.28 Buy
310689 50G ₹6354.28 Buy
T0852 5G ₹2300 Buy

Tetramethylammonium borohydride Chemical Properties,Uses,Production

Uses

Reactant for:

  • Preparation of iridium tetrahydride complexes bearing a tridentate pincer-type bis(phosphino)silyl ligand
  • Reduction reactions (reducing agent)

Purification Methods

Recrystallisation of the borohydride from H2O three times yields ca 94% pure compound. Dry in high vacuum at 100o for 3hours. The solubility in H2O is 48% (20o), 61% (40o), and in EtOH 0.5% (25o) and MeCN 0.4% (25o). It decomposes slowly in a vacuum at 150o, but rapidly at 250o. The rate of hydrolysis of Me4N.BH4 (5.8M) in H2O at 40o is constant over a period of 100hours at 0.04% of original wt/hour. The rate decreases to 0.02%/hour in the presence of Me4NOH (5% of the wt of Me4N.BH4). [Banus et al. J Am Chem Soc 74 2346 1952, Beilstein 4 IV 148.]

Tetramethylammonium borohydride Preparation Products And Raw materials

Raw materials

Preparation Products

Tetramethylammonium borohydride Suppliers

Global( 70)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 China 39916 58 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29825 58 Inquiry
Hubei Ipure Biology Co., Ltd +8613367258412 China 10326 58 Inquiry
Hefei TNJ Chemical Industry Co.,Ltd. +86-0551-65418671 +8618949823763 China 34571 58 Inquiry
Hebei Guanlang Biotechnology Co., Ltd. +8619930503259 China 18424 58 Inquiry
Shanghai Acmec Biochemical Technology Co., Ltd. +undefined18621343501 China 33350 58 Inquiry
Aladdin Scientific +1-+1(833)-552-7181 United States 57511 58 Inquiry
ABCR GmbH & CO. KG 49 721 95061 0 Germany 6846 75 Inquiry
Ammonium, tetramethyl-, tetrahydroborate(1-) Methanaminium, N,N,N-trimethyl-, tetrahydroborate(1-) Nsc164901 Tetra-methyl ammonium boron hydride Tetramethylammonium tetrahydroborate(1-) Tetramethylammonium borohydride,TMAB TetraMethylaMMoniuM borohydride 95% Tetramethylammonium Borohydride  n,n,n-trimethylmethanaminiumtetrahydroborate(1-) n,n,n-trimethyl-methanaminiutetrahydroborate(1-) tetramethylammoniumborohydrate tetramethyl-ammoniutetrahydroborate(1-) TETRAMETHYLAMMONIUM TETRAHYDRIDOBORATE TETRAMETHYLAMMONIUM BOROHYDRIDE tetramethylammonium tetrahydroborate BISMUTH(III) SUBNITRATE 98% Tetramethylammoniumborohydride,95% Tetramethylammonium Borohydride [Reducing Reagent] TetramethylammoniumBorohydride[ReducingReagent]> TMAB Tetramethylammonium borohydride (6CI) 16883-45-7 C4H16NB CH34NBH4 C4H12NBH4 C4H16BN Borohydrides Synthetic Reagents Quaternary Ammonium Compounds B (Classes of Boron Compounds) Ammonium Polyhalides, etc. (Quaternary) Tetrahydroborates Reduction Ammonium Polyhalides, etc. (Quaternary) B (Classes of Boron Compounds) metal hydrides Quaternary Ammonium Compounds Reduction Synthetic Organic Chemistry Tetrahydroborates