ChemicalBook > Product Catalog >Chemical Reagents >Desulfurizer >1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)

1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)

CAS No.: 140681-55-6

Chemical Name:: 1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)

Synonyms: Selectfluor;Selectfluoro;1-(chloroMethyl)-4-fluoro-1,4-diazabicyclo[2.2.2]octane-1,4-diiuM;selectfluor fluorinating reagent;1-(ChloroMethyl)-4-fluoro-1,4-diazabicyclo[2.2.2]octane-1,4-diiuM tetrafluoroborate;selectfluor fluorinating;SELECTFLUOR I;1-(Chloromethyl)-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane ditetrafluoroborate;Selecetfluor;fluorinating reagent

CBNumber:: CB1254109

Molecular Formula:: C7H14B2ClF9N2

Molecular Weight:: 354.26

MOL File:: 140681-55-6.mol

MSDS File:: SDS

Modify Date:: 2024/3/7 16:58:36

Request For Quotation

1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) Properties

Melting point	260 °C(lit.)
Density	1.71 at 20℃
vapor pressure	0.001Pa at 25℃
storage temp.	2-8°C
solubility	Acetonitrile (Slightly), DMSO (Slightly), Methanol (Very Slightly, Heated), Water
form	Powder
color	White
Water Solubility	soluble
Sensitive	Moisture Sensitive
Merck	14,8425
BRN	5368649
InChIKey	ZQGDSZPGKPJABN-UHFFFAOYSA-N
LogP	-3.39 at 20℃
Surface tension	73.1mN/m at 1g/L and 19℃
CAS DataBase Reference	140681-55-6(CAS DataBase Reference)
EPA Substance Registry System	1,4-Diazoniabicyclo[2.2.2]octane, 1-(chloromethyl)-4-fluoro-, bis[tetrafluoroborate(1-)] (140681-55-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05,GHS07

Signal word

Danger

Hazard statements

H302-H317-H318-H412

Precautionary statements

P261-P273-P280-P301+P312-P302+P352-P305+P351+P338

Hazard Codes

Xn,O,F,Xi

Risk Statements

22-36/37/38-41-52/53-43

Safety Statements

26-36/37/39-61-21

RIDADR

UN 3088 4.2/PG 2

WGK Germany

Hazard Note

Oxidising Agent

TSCA

HazardClass

PackingGroup

HS Code

29335990

Toxicity

LD50 in male rats: 640 mg/kg orally; >2 g/kg dermally (Banks, 1998)

NFPA 704

	0
2		0

1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) price More Price(9)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	439479	1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) >95% in F+ active	140681-55-6	5G	₹4384.13	2022-06-14	Buy
Sigma-Aldrich(India)	439479	1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) >95% in F+ active	140681-55-6	25G	₹17027.73	2022-06-14	Buy
Sigma-Aldrich(India)	439479	1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) >95% in F+ active	140681-55-6	100G	₹45248.5	2022-06-14	Buy
ALFA India	ALF-L17003-22	1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate), 98+%	140681-55-6	1ea	₹18270	2022-05-26	Buy
ALFA India	ALF-L17003-14	1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate), 98+%	140681-55-6	25g	₹15047	2022-05-26	Buy

Product number	Packaging	Price	Buy
439479	5G	₹4384.13	Buy
439479	25G	₹17027.73	Buy
439479	100G	₹45248.5	Buy
ALF-L17003-22	1ea	₹18270	Buy
ALF-L17003-14	25g	₹15047	Buy

1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) Chemical Properties,Uses,Production

Description

1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)(Selectfluor) is a white solid (mp 190 °C), stable in air and to moisture. It is a dicationic salt soluble in cold water or dilute hydrochloric acid. However, it decomposes in dilute sodium hydroxide and reacts with cold DMSO (rapidly and exothermally) and with DMF (slowly on heating). It is moderately soluble in acetonitrile but only slightly soluble in lower alcohols and acetone, which makes the former the solvent of choice. Occasionally, reactions in these solvents were accelerated by adding a small amount of water or trifluoroacetic acid. Bulk quantities of Selectfluor should be stored in a cool, dry place and not heated above 80 °C. Fainzil’berg et al. have measured the reduction potentials of Selectfluor and other N-F compounds. With a positive reduction potential, E1/2 ) 0.33 V, Selectfluor is predicted to be a more reactive fluorinating reagent than, e.g., N-fluorobenzenesulfonimide, with E1/2 ) -1.24 V[1].

Chemical Properties

White powder

General Description

This product is a fluorine donor also called Selectfluor and has been enhanced for catalysis.

Toxicology

1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (F-TEDA-BF4) is moderately toxic (male rat oral LD50 640 mg kg?1; female rat 350–500 mg kg?1), and is an irritant to the eye and respiratory system. Always use approved dust mask (or respirator), gloves, and safety glasses when handling the solid. Carry out solubility tests on a sensible scale when seeking alternative solvents (note the problem with DMSO referred to above).

Advantages

As the advantages of non-toxicity, non-corrosion and chemical stability, 1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) have been widely used in industry and public life.

References

[1] Rajendra P. Singh, Jean’ne M. Shreeve. “Recent Highlights in Electrophilic Fluorination with 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane Bis(tetrafluoroborate).” ChemInform 35 16 (2004).

1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) Preparation Products And Raw materials

Raw materials

Fluorine

Preparation Products

PyriMidine, 2-[4-(1-piperazinyl)phenyl]-

1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) Suppliers

Global( 381)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
TCI Chemicals (India) Pvt. Ltd.	1800 425 7889	New Delhi, India	6778	58	Inquiry
Alfa Aesar	1 800 209 7001	Maharashtra, India	6913	58	Inquiry
A.J Chemicals	91-9810153283	New Delhi, India	6124	58	Inquiry
CLEARSYNTH LABS LTD.	+91-22-45045900	Hyderabad, India	6351	58	Inquiry
VASIN BIO LIFE SCIENCES PVT LTD	9491644688	Hyderabad, India	2096	58	Inquiry
Siddhi Specialities	91-0-9742033800	Bangalore, India	162	58	Inquiry
ALTAIR ALCHEMY Laboratories	91--9014276848	Hyderabad, India	324	58	Inquiry
HiMedia Laboratories	91-22-61471919	Maharashtra, India	1843	58	Inquiry
Shaanxi Didu New Materials Co. Ltd	+86-89586680 +86-13289823923	China	9003	58	Inquiry
Shandong Juchuang Chemical Co., LTD	+undefined15030412209	China	387	58	Inquiry

Supplier	Advantage
TCI Chemicals (India) Pvt. Ltd.	58
Alfa Aesar	58
A.J Chemicals	58
CLEARSYNTH LABS LTD.	58
VASIN BIO LIFE SCIENCES PVT LTD	58
Siddhi Specialities	58
ALTAIR ALCHEMY Laboratories	58
HiMedia Laboratories	58
Shaanxi Didu New Materials Co. Ltd	58
Shandong Juchuang Chemical Co., LTD	58

1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate): Properties and Synthesis
1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) is a stable, non-volatile, and powerful electr....
Jun 14，2024

1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate): Its application and toxicity
1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo [2.2.2] octane bis (tetrafluoroborate) is a kind of selective fluorine reagent, wh....
Apr 17，2023

Application and Prevention of 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)
1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) is an electrophilic fluorination reagent used ....
Aug 10，2022

1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) Spectrum

1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)(140681-55-6)IR1 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)(140681-55-6)IR2

140681-55-6(1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate))Related Search:

NITRONIUM TETRAFLUOROBORATE AZURE B TETRAFLUOROBORATE Lead(II) tetrafluoroborate N-OCTANE Potassium tetrafluoroborate

Fluoroboric acid Sodium tetrafluoroborate LITHIUM PERIODATE BLOCKING REAGENT GE (Chloromethylene)dimethyliminium chloride

1-Bromopentane Bromoacetonitrile PotassiuM triMethylacetate, 95% Androstenedione ZINC-COPPER COUPLE

Fluorine 1,2-Dianilinoethane Tetramethylammonium borohydride

chevron_left

1of4

chevron_right

N-FLUORO-N'-(CHLOROMETHYL)TRIETHYLENEDIAMINE BIS(TETRAFLUOROBORATE) N-CHLOROMETHYL-N'-FLUOROTRIETHYLENEDIAMMONIUM BIS (TETRAFLUOROBORATE) SELECTFLUOR F-TEDA-BF4 SELECTFLUOR(R) REAGENT SELECTFLUOR(TM) FLUORINATING REAGENT 1-CHLOROMETHYL-4-FLUORO-1,4-DIAZONIABICYCLO[2.2.2]OCTANE BIS f-teda-bf_4 4-(chloromethyl)-1-fluoro-1,4-diazoniabicyclo[2,2,2]octane tetrafluoroboron N-Fluoro-N'-chloromethyltriethylenediamine 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate), 98+% F-TEDA, 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate), N-Chloromethyl-Nμ-fluorotriethylenediammonium bis(tetrafluoroborate) Selectfluor(R) fluorinating reagent F-TEDA, N-Chloromethyl-Nμ-fluorotriethylenediammonium bis(tetrafluoroborate) 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo2.2.2 aoctane bis(tetrafluoroborate), 96% 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo2.2.2üoctane bis(tetrafluoroborate), 98+% 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate),96% 1-chloromethy 1-4-fluoro-1, 4-diazoniabicyclo〔2.2.2〕octanebis(tetrafluoroborate) 1-(Chloromethyl)-4-fluoro-1,4-diazoniabicyclo[2.2.2]oc F-TEDA F-TEDA-BF4 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) N-Chloromethyl-N′-fluorotriethylenediammonium bis(tetrafluoroborate) 1-(Chloromethyl)-4-fluoro-1,4-diazoniabicyclo Selectfluor (Air Prods. Chem.) 4-diazoniabicyclo[2.2.2]octane,1-(chloromethyl)-4-fluoro-bis[tetrafluorobo 4-diazoniabicyclo[2.2.2]octane,1-(chloromethyl)-4-fluoro-bis[tetrafluoroborate(1-)] rate(1-)] 1-CHLOROMETHYL-4-FLUORO-1,4-DIAZONIABICYCLO[2.2.2]OCTANE BIS(TETRAFLUOROBORATE) N-Fluoro-N'-chloromethyltriethylenediaminebis(tetrafluoroborate)(SELECTFLUORTM) 1-chlorome.-4-fluoro-1,4-diazoniabicyclo octane bis(bf4) F-TEDA-BF_4~SELECTFLUOR(rg Fluorinating 1-CHLOROME.-4-FLUORO-1,4-DIAZONIABICYCLO SELECTFLUOR FLUORINATING REAGENT, >95% F + ACTIVE Selectfluor fluorinating reagent,1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate), N-Chloromethyl-N′-fluorotriethylenediammonium bis(tetrafluoroborate), F-TEDA 2-(chloroMethyl)-4-fluoro-1,4-diazabicyclo[2.2.2]octane-1,4-diiuM diboranuide 1-CHLOROMETHYL-4-FLUORO-1,4-DIAZONIABICYCLO[2.2.2]OCTANE BIS(TETRAFLUOROB+) T 1-(Chloromethyl)-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane Bis(tetrafluoroborate) F-TEDA-BF4 Selectfluor® N-Fluoro-N-chloroMethyltriethylenediaMine bis(tetrafluoroborate), (Selectfluor) 1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]oCLane bis(tetrafluoroborate) 1,4-Diazoniabicyclo2.2.2octane, 1-(chloromethyl)-4-fluoro-, bistetrafluoroborate(1-) 1-CHLOROMETHYL-4-FLUOR-1,4-DIAZONIABICYCLO 2.2.2. OCTANE BIS (TETRAFLUOROBORATE) 1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane FTB Selectfluor Selectfluor(R) fluorinating reagent >95% in F+ active 1-ChloroMethyl-4-fluoro-1,4-1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate), 96% 1-(Chloromethyl)-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate), min. 97% SelectFluor(R) 1-(CHLOROMETHYL)-4-FLUORO-1,4-DIAZABICYCLO[2.2.2]OCTANE-1,4-DIIUM; BIS(TETRAFLUOROBORANUIDE) bis(tetrafluoroboranuide) 1-(Chloromethyl)-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate), min. 97% SelectFluor SELECTFLUOR(TM) o[2.2.2]octane bis(tetrafL uoro-1,4-diazoniabicycL [tris(λ2-fluoranidyl)-λ1-boranetriiumyl]-λ2-fluoranide 4-(chloromethyl)-1-fluoro-1,4-diazabicyclo[2.2.2]octane-1,4-diium 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)(SelectFluor) N-Fluoro-N'-(chloromethyl)triethylenediamineBis(tetrafluoroborate)> SELECTFLUOR FLUORINATING REAGENT (Selectfluor) 1,4-Diazoniabicyclo[2.2.2]octane, 1-(chloromethyl)-4-fluoro-, tetrafluoroborate(1-) (1:2) 1- Chloromethyl-4-fluoro-1, 4-diazabicyclic [2.2.2] octane bis (tetrafluoroborate) salt