ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Amine salt (ammonium salt) >Tetrabutylammonium tetrafluoroborate
Tetrabutylammonium tetrafluoroborate
- CAS No.
- 429-42-5
- Chemical Name:
- Tetrabutylammonium tetrafluoroborate
- Synonyms
- tetrabutylammonium tetrafluoborate;TETRA-N-BUTYLAMMONIUM TETRAFLUOROBORATE;TBABF4;SKL1461;SKL1624;N4,4,4,4BF4;ammonium TetrafL;Tetrabutylammonium fluoborate;TETRABUTYLAMMONIUM FLUOROBORATE;TETRA-N-BUTYLAMMONIUM FLUOROBORATE
- CBNumber:
- CB1273128
- Molecular Formula:
- C16H36BF4N
- Molecular Weight:
- 329.27
- MOL File:
- 429-42-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/2/5 21:01:15
| Melting point | 155-161 °C(lit.) |
|---|---|
| Flash point | >93℃ |
| storage temp. | −20°C |
| solubility | methanol: 0.1 g/mL, clear, colorless |
| form | Crystalline Powder |
| color | White |
| Water Solubility | Slightly soluble |
| Sensitive | Hygroscopic |
| BRN | 3577508 |
| InChIKey | DWWRDPSMLREDKW-UHFFFAOYSA-M |
| CAS DataBase Reference | 429-42-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Tetrabutylammonium tetrafluoroborate(429-42-5) |
| EPA Substance Registry System | 1-Butanaminium, N,N,N-tributyl-, tetrafluoroborate(1-) (429-42-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H315-H318-H335 | |||||||||
| Precautionary statements | P261-P280-P305+P351+P338 | |||||||||
| Hazard Codes | Xi,T,Xn | |||||||||
| Risk Statements | 36/37/38-41-37/38-22 | |||||||||
| Safety Statements | 26-36-37/39-39 | |||||||||
| RIDADR | UN 1759 8/PG III | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant/Hygroscopic | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | TOXIC, HYGROSCOPIC | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29239000 | |||||||||
| NFPA 704 |
|
Tetrabutylammonium tetrafluoroborate price More Price(12)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 217964 | Tetrabutylammonium tetrafluoroborate 99% | 429-42-5 | 5G | ₹3550.6 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 217964 | Tetrabutylammonium tetrafluoroborate 99% | 429-42-5 | 25G | ₹10673.45 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 217964 | Tetrabutylammonium tetrafluoroborate 99% | 429-42-5 | 100G | ₹17081.85 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 86896 | Tetrabutylammonium tetrafluoroborate for electrochemical analysis, ≥99.0% | 429-42-5 | 25G | ₹29898.65 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 217964 | Tetrabutylammonium tetrafluoroborate 99% | 429-42-5 | 500G | ₹75439.43 | 2022-06-14 | Buy |
Tetrabutylammonium tetrafluoroborate Chemical Properties,Uses,Production
Chemical Properties
WHITE FINE CRYSTALLINE POWDER
Uses
Tetrabutylammonium tetrafluoroborate may be used in the following studies:
- As supporting electrolyte in the voltammetric determination of Δ(9)-tetrahydrocannabinol (Δ(9)-THC).
- Synthesis of biologically relevant macrolactones, Sansalvamide A.
- As supporting electrolyte in the determination of the oxidation and reduction potentials of 5,10,15,20-tetra[3-(3-trifluoromethyl)phenoxy]porphyrin by cyclic voltammetry.
- Preparation of 1:1 adduct with 1,10-phenanthroline.
- Used to prepare other tetrabutylammonium salts in aqueous solutions.
- As electrolyte additive in the synthesis of conducting poly(thiophenes).
General Description
Tetrabutylammonium tetrafluoroborate (TBATFB) is a phase transfer catalyst. It can be synthesized by the reaction between 30% aqueous solution of tetrafluoroboric acid and 40% aqueous solution of tetrabutylamonium hydroxide. Tetrabutylammonium tetrafluoroborate acts as an electrolyte and inhibits the self-assembly of alkylthiosulfate on gold.
Purification Methods
Recrystallise it from H2O, aqueous EtOH or from EtOAc by cooling in Dry-ice. Also recrystallise it from ethyl acetate/pentane or dry acetonitrile. Dry it at 80o under vacuum. [Detty & Jones J Am Chem Soc 109 5666 1987, Hartley & Faulkner J Am Chem Soc 107 3436 1985.] The acetate has m 118±2o (from BuCl), the bromide has m 118o (from EtOAc) and the nitrate has m 120o (from *C6H6). [Witschonka & Kraus J Am Chem Soc 69 2472 1947, Wheeler & Sandstedt J Am Chem Soc 77 2024 1955, Beilstein 4 IV 558.]
Tetrabutylammonium tetrafluoroborate Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 361)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| ACME SUJAN CHEMICALS | +91 7588647937 | Maharashtra, India | 90 | 58 | Inquiry |
| Dishman Carbogen Amcis Ltd (Dishman Group) | +91-2717420100 +91-8154017093 | Gujarat, India | 90 | 58 | Inquiry |
| Tatva Chintan Pharma Chem Limited | +91-7574848534 +91-7574848533 | Gujarat, India | 103 | 58 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6257 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6100 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6768 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6905 | 58 | Inquiry |
| Tatva Chintan Pharma Chem Limited | 91-7574848533 | Gujarat, India | 26 | 58 | Inquiry |
| Acme Sujan Chemicals Pvt., Ltd. | 91-257-2236844 | Maharashtra, India | 62 | 58 | Inquiry |
| Maas Pharma Chemicals | +91-9958666224 | Delhi, India | 1607 | 58 | Inquiry |
Tetrabutylammonium tetrafluoroborate Spectrum
Tetrabutylammonium tetrafluoroborate(429-42-5)MSTetrabutylammonium tetrafluoroborate(429-42-5)1HNMRTetrabutylammonium tetrafluoroborate(429-42-5)13CNMRTetrabutylammonium tetrafluoroborate(429-42-5)IR1Tetrabutylammonium tetrafluoroborate(429-42-5)IR2Tetrabutylammonium tetrafluoroborate(429-42-5)Raman
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429-42-5
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C16H36NBF4
Quaternary Ammonium Compounds
B (Classes of Boron Compounds)
Ammonium Polyhalides, etc. (Quaternary)
Tetrafluoroborates
Phase Transfer Catalysts
Synthetic Reagents
Ammonium Salts
Ammonium Salts
halometallate salts
Ammonium SaltsAnalytical Reagents
Electrochemistry
Greener Alternatives: Catalysis
Phase Transfer Catalysts
Supporting Electrolytes for Electrochemistry
Ammonium Polyhalides, etc. (Quaternary)
B (Classes of Boron Compounds)
Quaternary Ammonium Compounds
Tetrafluoroborates