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(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE

(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE Structure
CAS No.
470480-32-1
Chemical Name:
(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE
Synonyms
(S,S,R,R)-TANGPHOS;(S,S',R,R')-TANGPHOS;(1S,1S',2R,2R')-1,1'-DI-TERT-BUTYL-(2,2')-DIPHOSPHOLANE;(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE;(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE;(2R)-1-tert-butyl-2-[(2R)-1-tert-butylphospholan-2-yl]phospholane;2,2'-Biphospholane, 1,1'-bis(1,1-dimethylethyl)-, (1S,1'S,2R,2'R)-;(1S,1S'',2R,2R'')-(+)-1,1''-DI-T-BUTYL-[2,2'']-DIPHOSPHOLANE (S,S,R,R)-TANGPHOS;(1S,1'S,2R,2'R)-(+)-1,1'-Di-t-butyl-[2,2']-diphospholane,min.95%(S,S,R,R)-TANGPHOS
CBNumber:
CB9117701
Molecular Formula:
C16H32P2
Molecular Weight:
286.37
MOL File:
470480-32-1.mol

(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE Properties

Melting point 60-65 °C
Boiling point 353.6±12.0 °C(Predicted)

SAFETY

Risk and Safety Statements

Risk Statements  36/37/38
Safety Statements  22-24/25
WGK Germany  3

(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE Chemical Properties,Uses,Production

Uses

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation

Catalytic ligand used in:

  • Preparation of α-borono-substituted alkylarenes by asymmetric hydroboration of styrenes catalyzed by copper(I)
  • Enantioselective synthesis of spiroindane di-Me acetic acid via hydrogenation of spiroindane di-Me acetic acid catalyzed by Ru(II)
  • Asymmetric γ-addition of thiols to allenoates
  • Rhodium-catalyzed intermolecular enantioselective hydroacylation of alkynes to give alpha- and beta-substituted unsaturated ketones by kinetic resolution
  • Stereoselective preparation of β-amino nitriles via rhodium-catalyzed asymmetric hydrogenation of amino acrylonitriles

(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 12)Suppliers
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Capot Chemical Co.,Ltd. 571-85586718 +8613336195806 China 29798 60 Inquiry
Qingdao Dexin Chemical Co., Ltd +86-15553333686 +86-15553333686 China 2862 58 Inquiry
ABCR GmbH & CO. KG 49 721 95061 0 Germany 6846 75 Inquiry
Sigma-Aldrich 021-61415566 800-8193336 China 51471 80 Inquiry
Shandong Jiuyue Biological Technology Co., LTD 15553348166 China 3538 58 Inquiry
Chiron AS +47 73 87 4490 Norway 2801 72 Inquiry
3B Scientific Corporation 847.281.9822 United States 6744 47 Inquiry
SIGMA-RBI 800 736 3690 (Orders) Switzerland 6913 91 Inquiry
Meryer (Shanghai) Chemical Technology Co., Ltd. 021-61259108 18621169109 China 40240 62 Inquiry
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 China 94658 76 Inquiry
(S,S',R,R')-TANGPHOS (S,S,R,R)-TANGPHOS (1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE (1S,1S',2R,2R')-1,1'-DI-TERT-BUTYL-(2,2')-DIPHOSPHOLANE (1S,1'S,2R,2'R)-(+)-1,1'-Di-t-butyl-[2,2']-diphospholane,min.95%(S,S,R,R)-TANGPHOS (1S,1S'',2R,2R'')-(+)-1,1''-DI-T-BUTYL-[2,2'']-DIPHOSPHOLANE (S,S,R,R)-TANGPHOS 2,2'-Biphospholane, 1,1'-bis(1,1-dimethylethyl)-, (1S,1'S,2R,2'R)- (2R)-1-tert-butyl-2-[(2R)-1-tert-butylphospholan-2-yl]phospholane (1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE 470480-32-1 C16H32P2 Privileged Ligands Chiral Catalysts, Ligands, and Reagents ChiralQuest Ligands Asymmetric Synthesis