Lithium dihydrogen phosphate
- CAS No.
- 13453-80-0
- Chemical Name:
- Lithium dihydrogen phosphate
- Synonyms
- monolithiumphosphate;LITHIUM DIHYDROGEN P;lithiumdihydrophosphate;lithiumphosphate(lih2po4);Lithium hydrogen phosphate;LITHIUM PHOSPHATE MONOBASIC;LITHIUM DIHYDROGEN PHOSPHATE;LithiuM Dihydroxide Phosphate;Lithiumdihydrogenphosphate,97%;lithiumdihydrogenorthophosphate
- CBNumber:
- CB9150683
- Molecular Formula:
- H4LiO4P
- Molecular Weight:
- 105.94
- MOL File:
- 13453-80-0.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/3/26 13:32:57
| Melting point | >100°C |
|---|---|
| Density | 2.5 g/mL at 25 °C(lit.) |
| storage temp. | Inert atmosphere,Room Temperature |
| form | Powder |
| Specific Gravity | 2.461 |
| color | white |
| Water Solubility | Slightly soluble in water. |
| Stability | Stable. Incompatible with strong oxidizing agents. |
| InChI | InChI=1S/Li.H3O4P.H/c;1-5(2,3)4;/h;(H3,1,2,3,4); |
| InChIKey | AZOORWHXDYIBGH-UHFFFAOYSA-N |
| SMILES | P(O)(O)(O)=O.[LiH] |
| CAS DataBase Reference | 13453-80-0(CAS DataBase Reference) |
| EPA Substance Registry System | Phosphoric acid, monolithium salt (13453-80-0) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H315-H319 | |||||||||
| Precautionary statements | P264-P270-P280-P301+P312-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 22-36/37/38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | TC6593950 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 28352990 | |||||||||
| Toxicity | mouse,LD50,oral,910mg/kg (910mg/kg),"Aktual'nye Problemy Gigieny Truda. Current Problems of Labor Hygiene," Tarasenko, N.Y., ed. Moscow, Pervyi Moskovskii Meditsinskii Inst., 1978Vol. -, Pg. 28, 1978. | |||||||||
| NFPA 704 |
|
Lithium dihydrogen phosphate price More Price(3)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 563161 | Lithium phosphate monobasic ≥99.99% | 13453-80-0 | 25G | ₹6765.63 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 442682 | Lithium phosphate monobasic 99% | 13453-80-0 | 500G | ₹10121.38 | 2022-06-14 | Buy |
| ALFA India | ALF-A16987-30 | Lithium dihydrogen phosphate, 97% | 13453-80-0 | 250g | ₹5895 | 2022-05-26 | Buy |
Lithium dihydrogen phosphate Chemical Properties,Uses,Production
Description
Lithium dihydrogen phosphate, also known as LDP, is a White crystalline powder with the formula LiH2PO4. It is soluble in water. LiH2PO4 is usually prepared by a stoichiometric reaction of Li2СO3 and 85% orthophosphoric acid[1]. It is often used as a raw material for the preparation of cathode materials for lithium batteries or as phosphate in chemical reactions.
Chemical Properties
White crystalline powder
Uses
Lithium Dihydrogen Phosphate is used in preparation method of lithium hydroxide from lithium-containing low-magnesium brine in lithium phosphate manner.
General Description
This product has been enhanced for energy efficiency.
Solubility in water
At 0°C， the solubility of lithium dihydrogen phosphate in water is about 55.8wt % (126.2 g of LiH2PO4 /100 g of water)[1]. At 22°C, the solubility of lithium dihydrogen phosphate corresponds to ~ 153.8 g of LiH2PO4/100 g of water. At 25°C, it doesn't dissolve in water[2].
References
[1] A.P. Voronov, G.N. Babenko, V.M. Puzikov, A.N. Iurchenko, Growth of LiH2PO4 single crystals from phosphate solutions, Journal of Crystal Growth, 2013, 374, 49–52. [2] R. W. Berg, A. V. Nikiforov, N. J. Bjerrum, Vapor pressure and specific electrical conductivity in the H2O–LiH2PO4–LiPO3 system—a novel electrolyte for water electrolysis at elevated temperature.Ionics, 2021, 27, 703–719.
Lithium dihydrogen phosphate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
| Satyam Pharma Chem Pvt Ltd | +91-2266339900 +91-2266339900 | Maharashtra, India | 48 | 58 | Inquiry |
| Clearsynth Labs | 91-22-45045900 | Maharashtra, India | 3889 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| S.K. CHEMICAL INDUSTRIES | +91-22-66370299 Ext 21 / 91-22-23437380 Ext 25 | New Delhi, India | 262 | 30 | Inquiry |
| Shanghai Huaran Industrial Co.,Ltd | 17749774353 | China | 52 | 58 | Inquiry |
| Shijiazhuang Jianxin Biotechnology Co., LTD | +undefined+86-17692708569 | China | 711 | 58 | Inquiry |
| Hebei Yanxi Chemical Co., Ltd. | +86-17531190177; +8617531190177 | China | 6011 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| GLR Innovations | 58 |
| Satyam Pharma Chem Pvt Ltd | 58 |
| Clearsynth Labs | 58 |
| A.J Chemicals | 58 |
| CHEMSWORTH | 30 |
| Alfa Aesar | 58 |
| S.K. CHEMICAL INDUSTRIES | 30 |
| Shanghai Huaran Industrial Co.,Ltd | 58 |
| Shijiazhuang Jianxin Biotechnology Co., LTD | 58 |
| Hebei Yanxi Chemical Co., Ltd. | 58 |
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