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Lithium hypochlorite

Lithium hypochlorite Structure
CAS No.
13840-33-0
Chemical Name:
Lithium hypochlorite
Synonyms
LiOCl;Hypure L;lithiumoxychloride;LITHIUM HYPOCHLORITE;lithiumchlorideoxide;hypochloritedelithium;lithiumhypochloritemixture;Hypochlorousacid,lithiumsalt;Hypochlorous acid, lithium salt;Hypochlorous acid, lithium salt (1:1)
CBNumber:
CB9263318
Molecular Formula:
ClLiO
Molecular Weight:
58.39
MOL File:
13840-33-0.mol
Modify Date:
2023/10/17 17:11:58

Lithium hypochlorite Properties

solubility very soluble in H2O
form powder
color white
EPA Substance Registry System Lithium hypochlorite (13840-33-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS03,GHS07,GHS05,GHS09
Signal word  Danger
Hazard statements  H400-H272-H302-H314
Precautionary statements  P273-P391-P501-P264-P270-P301+P312-P330-P501-P210-P220-P221P280-P370+P378-P501-P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501
Hazard Codes  O,C
Risk Statements  8-22-31-34
Safety Statements  17-26-36/37/39-45
RIDADR  1471
RTECS  NH3486000
HazardClass  5.1
PackingGroup  II

Lithium hypochlorite Chemical Properties,Uses,Production

Chemical Properties

white granules; oxidant; can ignite organic materials; can be prepared by action of chlorine on a solution of LiOH; used as a bleach and an oxidizing agent, sanitizer for swimming pools, cooling water treatment [HAW93] [KIR81] [FMC93]

Uses

Lithium hypochlorite is an algicide, disinfectant, fungicide and food contact surface sanitizer. Its primary pesticidal use is to control algae, bacteria and mildew in swimming pool water systems, hot tubs and spas; approximately 2,000,000 pounds of the active ingredient were used for this purpose in 1989. It also is used to sanitize food and cheese processing plant equipment, dairies, and eating establishment equipment and utensils. Lithium hypochlorite is formulated as a ready-to-use liquid and a soluble solid concentrate. It is applied to swimming pool water using a skimmer basket, and to equipment or utensils by hand or through use of a dish washing machine. Lithium is an element that occurs naturally at low levels in food and drinking water.

General Description

A white granular solid or tablets compressed from the granules, with an odor of chlorine. Noncombustible but accelerates the burning of combustible material. Prolonged exposure of closed containers to heat may result in vigorous decomposition and rupture of the container. Used as a dry bleach. Generally toxic. An irritant.

Air & Water Reactions

Soluble in water. Decomposes slowly in water with the evolution of chlorine gas.

Reactivity Profile

LITHIUM HYPOCHLORITE is a powerful oxidizing agent. particularly in the presence of water or at higher temperature as LITHIUM HYPOCHLORITE decomposes to release oxygen and chlorine gases. Forms highly explosive NCl3 on contact with urea or ammonia. When heated or on contact with acids, produces highly toxic fumes of chlorine gas [Sax, 9th ed., 1996, p. 1905].

Health Hazard

Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

These substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard.

Safety Profile

A powerful oxidizer. An eye, skin, and mucous membrane irritant. When heated to decomposition it emits very toxic fumes of Li2O and Cl-. Used for swimming pool chlorination, and as a laundry bleach. See also LITHIUM COMPOUNDS and HYPOCHLORITES.

Lithium hypochlorite Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 28)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Axiom Chemicals Private Limited 08048956817 Vadodara, India 69 58 Inquiry
Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 China 39916 58 Inquiry
Shaanxi Dideu Newmaterial Co., Ltd. 029-63373950 15353716720 China 10011 58 Inquiry
Spectrum Chemicals & Laboratory Products 310 516 8000 United States 6706 77 Inquiry
MP Biomedicals, Inc. 949 833 2500 United States 6566 81 Inquiry
Pfaltz & Bauer, Inc. (800) 225-5172 United States 6830 72 Inquiry
City Chemicals Corporation 800-248-2436 United States 6462 72 Inquiry
FMC Lithium 704 868 5300 United States 129 72 Inquiry
CHEMICAL LAND21 82- 2 -783 - 8063 South Korea 6315 74 Inquiry
City Chemical LLC 1-203-932-2489 United States 6710 72 Inquiry
hypochloritedelithium Hypochlorous acid, lithium salt Hypochlorousacid,lithiumsalt Hypure L LiOCl lithiumchlorideoxide lithiumhypochloritemixture lithiumoxychloride LITHIUM HYPOCHLORITE Hypochlorous acid, lithium salt (1:1) 13840-33-0 ClOLi LiCLO Inorganics