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(-)-FENCHONE

(-)-FENCHONE Structure
CAS No.
4695-62-9
Chemical Name:
(-)-FENCHONE
Synonyms
fenchanone;L-FENCHONE;(-)-FENCHONE;2-fenchanone;(S)-Fenchone;L(-)-FENCHONE;(1S)-Fenchone;FENCHONE, (-)-;ALPHA-FENCHONE;dextro-fenchone
CBNumber:
CB9283112
Molecular Formula:
C10H16O
Molecular Weight:
152.23
MOL File:
4695-62-9.mol
MSDS File:
SDS
Modify Date:
2023/11/28 16:31:43

(-)-FENCHONE Properties

Melting point 5-6 °C(lit.)
alpha D20 +66.9°
Boiling point 192-194 °C(lit.)
Density 0.948 g/mL at 25 °C(lit.)
FEMA 2479 | D-FENCHONE
refractive index n20/D 1.461(lit.)
Flash point 127 °F
storage temp. 2-8°C
solubility Chloroform (Sparingly), Methanol (Slightly)
form Liquid
color Clear colorless to pale yellow
Odor at 100.00 %. camphor thuja cedarleaf herbal earthy woody
Odor Type balsamic
optical activity [α]20/D +62±1°, neat
Water Solubility 2.147g/L(25 ºC)
JECFA Number 1396
Merck 14,3968
BRN 2206555
Dielectric constant 12.0(20℃)
LogP 2.089 (est)
EPA Substance Registry System Bicyclo[2.2.1]heptan-2-one, 1,3,3-trimethyl-, (1S,4R)- (4695-62-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02
Signal word  Danger
Hazard statements  H226
Precautionary statements  P210-P240-P241-P280a-P303+P361+P353-P501a
Risk Statements  10
Safety Statements  23-24/25
RIDADR  UN 1224 3/PG 3
WGK Germany  3
RTECS  RB7875200
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29142990
Toxicity LD50 orally in rats: 6.16 g/kg (Jenner)
NFPA 704
2
0 0

(-)-FENCHONE price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) CRM40747 (+)-Fenchone solution certified reference material, 2000?μg/mL in methanol, ampule of 1?mL 4695-62-9 1ML ₹9296.7 2022-06-14 Buy
Sigma-Aldrich(India) 46208 (+)-Fenchone analytical standard 4695-62-9 1ML ₹4026.9 2022-06-14 Buy
Sigma-Aldrich 46210 (+)-Fenchone purum, ≥98.0% (sum of enantiomers, GC) 4695-62-9 100ML ₹13639.5 2022-06-14 Buy
Sigma-Aldrich(India) 46210 (+)-Fenchone purum, ≥98.0% (sum of enantiomers, GC) 4695-62-9 100ML ₹13639.5 2022-06-14 Buy
Sigma-Aldrich(India) 46208 (+)-Fenchone analytical standard 4695-62-9 5ML ₹11842.55 2022-06-14 Buy
Product number Packaging Price Buy
CRM40747 1ML ₹9296.7 Buy
46208 1ML ₹4026.9 Buy
46210 100ML ₹13639.5 Buy
46210 100ML ₹13639.5 Buy
46208 5ML ₹11842.55 Buy

(-)-FENCHONE Chemical Properties,Uses,Production

Description

d-Fenchone has a camphor-like odor, powerful and sweet, and a warm, somewhat bitter, burning taste. d-Fenchone is isolated from cedarleaf oil (thuja oil).

Chemical Properties

clear colorless to pale yellow liquid

Occurrence

Reported found in several essential oils: Thuja plicata, Thuja occidentalis, Thuja standishii, Russian anise, fennel, a few Artemisia varieties (A frigida, A verlotorum, A santolinaefolia), Lavanda stoechas, Lavanda burmannii, and others; the highest levels are found in fennel oil (12 to 19%); two optically active forms have been isolated Also reported found in basil, caraway, cedar leaf oil, cloves, dill, licorice and thyme

Uses

As flavor in foods; in perfumes.

Preparation

Isolated from cedarleaf oil (thuja oil).

Definition

ChEBI: A fenchone that has 1S,4R stereochemistry. A colourless, oily liquid found in fennel oil, it is used in perfumery and as flavour in foods.

General Description

Produced and qualified by HWI pharma services GmbH.
Exact content by quantitative NMR can be found on the certificate.

Purification Methods

The oily liquid is purified by distillation in a vacuum and is very soluble in EtOH and Et2O. [Boyle et al. J Chem Soc, Chem Commun 395 1971, Hückel Justus Liebigs Ann Chem 549 186 1941, (±)-isomer: Braun & Jacob Chem Ber 66 1461 1933.] It forms two oximes, cis-oxime: m 167o (crystallises from pet ether) [] D +46.5o (c 2, EtOH), O-benzoyloxime m 81o, [] D +49o

(-)-FENCHONE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 129)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
Zhengzhou Alfa Chemical Co.,Ltd +8618530059196 China 13127 58 Inquiry
Career Henan Chemica Co +86-0371-86658258 +8613203830695 China 30253 58 Inquiry
Hefei TNJ Chemical Industry Co.,Ltd. 0551-65418671 China 34571 58 Inquiry
Dideu Industries Group Limited +86-29-89586680 +86-15129568250 China 25247 58 Inquiry
Dayang Chem (Hangzhou) Co.,Ltd. 571-88938639 +8617705817739 China 52861 58 Inquiry
TargetMol Chemicals Inc. +1-781-999-5354 United States 19973 58 Inquiry
ShenZhen Trendseen Biological Technology Co.,Ltd. 13417589054 China 11681 58 Inquiry
GIHI CHEMICALS CO.,LIMITED +8618058761490 China 49999 58 Inquiry
(1S)-1,3,3-trimethyl-norbornan-2-one L(-)-1,3,3-TRIMETHYL-2-NORBORBANONE L(-)-1,3,3-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-ONE LAEVO-1,3,3-TRIMETHYLBICYCLO[2.2.1]-2-HEPTANONE L-ALPHA-FENCHONE L(-)-FENCHONE L-FENCHONE (-)-FENCHONE FENCHONE, (-)- D(+)-1,3,3-Trimethylbicylo[2.2.1]heptan-2-one fenchanone Bicyclo2.2.1heptan-2-one, 1,3,3-trimethyl-, (1S,4R)- 2-fenchanone d-FENCHONE, NATURAL (+)-1,3,3-Trimethyl-2-norbornanone, (1S)-1,3,3-Trimethylbicyclo[2.2.1]heptan-2-one D(+)-Fenchone,97% (+)-Fenchone,(+)-1,3,3-Trimethyl-2-norbornanone, (1S)-1,3,3-Trimethylbicyclo[2.2.1]heptan-2-one D(+)-Fenchone, 97% 100GR D(+)-Fenchone, 97% 25GR (1S)-Fenchone (S)-(+)-Fenchone (S)-Fenchone (+)-Fenchone purum, >=98.0% (sum of enantiomers, GC) (1S,4R)-fenchone 1,3,3-trimethyl-,(1r,4s)-(+)-2-norbornanon 1,3,3-trimethyl-,(1S)-Bicyclo[2.2.1]heptan-2-one 2-Norbornanone, 1,3,3-trimethyl-, (1R,4S)-(+)- 2-Norbornanone, 1,3,3-trimethyl-, (1S,4R)-(+)- 3,3-trimethyl-(1s)-bicyclo(2.2.1)heptan-2-on 3,3-trimethyl-(1s)-bicyclo[2.2.1]heptan-2-on Bicyclo(2.2.1)heptan-2-one, 1,3,3-trimethyl-, (1R)- Bicyclo[2.2.1]heptan-2-one, 1,3,3-trimethyl-, (1S)- d-1,3,3-Trimethyl-2-norbornanone d-1,3,3-Trimethyl-2-norcamphanone (-)-1,3,3-TRIMETHYL-2-NOEBORNANOL (-)-1,3,3-TRIMETHYL-2-NORBORNANONE (1R)-1,3,3-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-ONE (1R)-(-)-FENCHONE ALPHA-FENCHONE (+)-FENCHONE SOLUTION (+)-Fenchone@100 μg/mL in Methanol (+)-1,3,3-Trimethyl-2-norbornanone dextro-fenchone inhibit,(+)Fenchone,(+) Fenchone,Inhibitor,(+)-Fenchone 4695-62-9 KETONE Asymmetric Synthesis Chiral Building Blocks Alphabetic Analytical Chromatography Product Catalog Analytical Standards Terpenes Bicyclic Monoterpenes Ketones Organic Building Blocks FA - FL Miscellaneous Natural Products Bicyclic Monoterpenes