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2-Chlorostyrene

2-Chlorostyrene Structure
CAS No.
2039-87-4
Chemical Name:
2-Chlorostyrene
Synonyms
2-chloro-styren;o-chloro-stryen;o-chloro-styren;O-CHLOROSTYRENE;2-CHLOROSTYRENE;styrene,o-chloro-;Styrene, o-chloro-;ortho-chlorostyrene;o-chlorovinylbenzene;1-Chloro-2-vinylbenzene
CBNumber:
CB9441912
Molecular Formula:
C8H7Cl
Molecular Weight:
138.59
MOL File:
2039-87-4.mol
MSDS File:
SDS
Modify Date:
2023/12/25 17:47:29

2-Chlorostyrene Properties

Melting point -63.1 °C
Boiling point 58-60 °C/7 mmHg (lit.)
Density 1.08 g/mL at 25 °C (lit.)
refractive index n20/D 1.565(lit.)
Flash point 138 °F
storage temp. 2-8°C
form Liquid
color Colorless to Almost colorless
Water Solubility Insoluble in water.
BRN 2038863
Exposure limits ACGIH: TWA 50 ppm; STEL 75 ppm
NIOSH: TWA 50 ppm(285 mg/m3); STEL 75 ppm(428 mg/m3)
CAS DataBase Reference 2039-87-4(CAS DataBase Reference)
NIST Chemistry Reference 2-Chlorostyrene(2039-87-4)
EPA Substance Registry System o-Chlorostyrene (2039-87-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS08,GHS02,GHS07
Signal word  Danger
Hazard statements  H226-H332-H350-H315-H319-H227-H335
Precautionary statements  P210-P233-P240-P241+P242+P243-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P501-P280g-P305+P351+P338-P201-P261-P304+P340+P312-P308+P313-P403+P235
Hazard Codes  T,Xi
Risk Statements  45-20/22-36/37/38
Safety Statements  53-23-36/37/39-45-37/39-26-36
RIDADR  UN 1993 3/PG 3
OEB A
OEL TWA: 50 ppm (285 mg/m3), STEL: 75 ppm (428 mg/m3)
WGK Germany  3
RTECS  WL4160000
Hazard Note  Harmful
HazardClass  3
PackingGroup  III
HS Code  29039990
NFPA 704
2
2 2

2-Chlorostyrene price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 160679 2-Chlorostyrene 97%, contains 0.1% hydroquinone as stabilizer 2039-87-4 5G ₹4189.28 2022-06-14 Buy
Sigma-Aldrich(India) 160679 2-Chlorostyrene 97%, contains 0.1% hydroquinone as stabilizer 2039-87-4 25G ₹30764.65 2022-06-14 Buy
TCI Chemicals (India) C0288 2-Chlorostyrene (stabilized with TBC) min. 96.0 % 2039-87-4 5G ₹4900 2022-05-26 Buy
TCI Chemicals (India) C0288 2-Chlorostyrene (stabilized with TBC) min. 96.0 % 2039-87-4 25G ₹13400 2022-05-26 Buy
Product number Packaging Price Buy
160679 5G ₹4189.28 Buy
160679 25G ₹30764.65 Buy
C0288 5G ₹4900 Buy
C0288 25G ₹13400 Buy

2-Chlorostyrene Chemical Properties,Uses,Production

Chemical Properties

2-Chlorostyrene, also called o-Chlorostyrene, is a flammable liquid that ranges in color from colorless to light yellow. It is used in the manufacture of polychlorostyrene which is a clear, colorless plastic with good foaming, heat distortion and flame-retardant properties.

Uses

2-Chlorostyrene is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff.

Preparation

o-Chlorostyrene is commercially produced as a monomer from o-chloroethylbenzene by an oxidation technique. p-Chlorostyrene is also produced as a mixture with o-chlorostyrene.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

2-Chlorostyrene may be sensitive to heat or prolonged exposure to light. 2-Chlorostyrene may polymerize.

Hazard

Central nervous system impairment and peripheral neuropathy.

Health Hazard

By analogy to styrene, ochlorostyrene is expected to cause central nervous system depression at extremely high concentrations and possibly irritation of the eyes, nose, and mucous membranes.
There are no reports of adverse effects in humans.

Fire Hazard

2-Chlorostyrene is combustible.

Safety Profile

A skin and eye irritant. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORINATED HYDROCARBONS, AROMATIC .

Potential Exposure

In organic synthesis; in the preparation of specialty polymers.

Shipping

UN1993 Flammable liquids, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, Technical Name Required.

Incompatibilities

Contact with elevated temperatures, strong oxidizers, strong bases; or acids may cause fire or explosion. May form peroxides; explosive polymerization may occur.

Global( 166)Suppliers
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A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
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Henan Fengda Chemical Co., Ltd +86-371-86557731 +86-13613820652 China 20308 58 Inquiry
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(2-chlorophenyl)ethylene 1-chloro-2-ethenylbenzene 1-Chloro-2-vinylbenzene 2-chloro-styren Benzene, 1-chloro-2-ethenyl- 2-Chlorostyrene, stabilized, 99% 2-CHLOROSTYRENE , STABILIZED WITH 0.1% 4-TERT-BUTYLCATECHOL 2-CHLOROSTYRENE Stabilised with 0.1% 4-tert-butylcatechol 2-Chlorostyrene, 98%, stab. with 0.1% 4-tert-butylcatechol 2-Chlorostyrene (stabilized with TBC) 1-Ethenyl-2-chlorobenzene 2-Chloro-1-vinylbenzene 2-Chlorostyrene,99%,stabilized 2-Chlorostyrene, Stab. With 0.1% 4-Tert-Butylcatechol 1-Chloro-2-vinylbenzene, 1-Chloro-2-ethenylbenzene benzene,1-chloro-2-ethenyl- o-chloro-stryen o-chloro-styren o-chlorovinylbenzene ortho-chlorostyrene Styrene, o-chloro- styrene,o-chloro- O-CHLOROSTYRENE 2-CHLOROSTYRENE o-Chlorostyrene, 99% (Inhibited) 2-Chlorostyrene (stabilized with TBC)> 2-Chlorostyrene ISO 9001:2015 REACH 2039-87-4 2038-87-47 C8H7Cl HALOGEN Styrenes High Refractive Index MonomersPolymer Science Monomers Photonic and Optical Materials Styrene and Functionalized Styrene Monomers Waveguide Materials