퍼밤

퍼밤
퍼밤 구조식 이미지
카스 번호:
14484-64-1
한글명:
퍼밤
동의어(한글):
퍼밤
상품명:
FERBAM
동의어(영문):
f40;F 40;FERBAM;ferban;FERBERK;FERMATE;cormate;ferbame;ferbeck;hokmate
CBNumber:
CB0474797
분자식:
C9H18FeN3S6
포뮬러 무게:
416.49
MOL 파일:
14484-64-1.mol

퍼밤 속성

녹는점
180°C (dec.)
밀도
0.21[at 20℃]
증기압
2 x 10-11 Pa (est.)
저장 조건
0-6°C
용해도
DMSO (약간 용해됨)
용해도
Insoluble[in water]
물리적 상태
고체
물리적 상태
단단한 모양
수용성
130mg l-1(실온)
색상
검은색
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
Merck
14,4013
노출 한도
NIOSH 10 mg/m3, IDLH 800 mg/m3; OSHA PEL: TWA 15 mg/m3; ACGIH TLV: TWA 10 mg/m3.
안정성
안정적인. 강한 산화제와 호환되지 않습니다.
InChIKey
WHDGWKAJBYRJJL-UHFFFAOYSA-K
LogP
-1.597 at 20℃
CAS 데이터베이스
14484-64-1
IARC
3 (Vol. 12, Sup 7) 1987
EPA
Ferbam (14484-64-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi,N
위험 카페고리 넘버 36/37/38-50/53
안전지침서 26-36/37/39-61-60
유엔번호(UN No.) UN3077 9/PG 3
OEB B
OEL TWA: 10 mg/m3
RTECS 번호 NO8750000
TSCA Yes
위험 등급 6.1
포장분류 II
HS 번호 29302000
유해 물질 데이터 14484-64-1(Hazardous Substances Data)
독성 LD50 in male mice, rats (mg/kg): 3000, 2700 i.p. (Hodge)
IDLA 800 mg/m3
기존화학 물질 KE-16965
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H330 흡입하면 치명적임 급성 독성 물질 흡입 구분 1, 2 위험 GHS hazard pictograms P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
H361 태아 또는 생식능력에 손상을 일으킬 것으로 의심됨 생식독성 물질 구분 2 경고 P201, P202, P281, P308+P313, P405,P501
H373 장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킬 수 있음 특정 표적장기 독성 - 반복 노출 구분 2 경고 P260, P314, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P201 사용 전 취급 설명서를 확보하시오.
P202 모든 안전 조치 문구를 읽고 이해하기 전에는 취급하지 마시오.
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P271 옥외 또는 환기가 잘 되는 곳에서만 취급하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P284 호흡 보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.
P391 누출물을 모으시오.
P403+P233 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 저장하시오.
P405 밀봉하여 저장하시오.
P501 ...에 내용물 / 용기를 폐기 하시오.
NFPA 704
0
2 0

퍼밤 C화학적 특성, 용도, 생산

화학적 성질

Ferbam is a combustible, odorless dark brown to black powder or granular solid

용도

Ferbam is a protective fungicide applied to foliage to control scab on pome fruit, peach leaf curl, blue mould on tobacco and other diseases on many other crops. It is often used in combinations with other dithiocarbamates to extend the spectrum of activity.

정의

A wettable powder containing 76% ferbam.

일반 설명

Ferbam is a carbamate fungicide. It is a stable, black powder and combustible and gives off irritating or toxic fumes (or gases) in a fire. Ferbam is incompatible with strong oxidants. It is used for foliar protectant against scab, rust, mould, and many fungal diseases on fruits, vegetables, melons, and ornamentals. Also, it works as a repellent towards Japanese beetles. The major uses of ferbam are in the control of apple scab and cedar apple rust, peach leaf curl, tobacco blue mould, and cranberry diseases. Ferbam is a broad-spectrum registered fungicide for the control of certain diseases in fruit trees, small fruit and berry crops, potatoes, ornamentals, conifers, and tobacco and for use on citrus, pome, stone fruits, and cranberries. Major areas of use include Florida, Massachusetts, New Jersey, and other countries. Ferbam is used as water-dispersible granule, 76WG.

공기와 물의 반응

Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.

반응 프로필

FERBAM is a dithiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.

위험도

Irritant to eyes and mucous membranes. Questionable carcinogen.

건강위험

Ferbam is an irritant of the eyes and respiratory tract; in animals it causes central nervous system depression, and it is expected that severe exposure will cause the same effect in humans.

농업용

Fungicide: Registered for use in the U.S. and Canada. Not approved for use in EU countries. A dimethyl-dithiocarbamate fungicide. It is widely used, together with other fungicides, to control Postbloom Fruit Drop (PFD) on citrus crops, and as a foliar protectant against scab, rust, mold and many fungus disease on fruits, vegetables, melons and ornamentals. It is registered in several states for use on currents and gooseberries to control leaf spot disease, and on apple, crabapple, hawthorn and quince to control cedar-apple rust disease. It is used to control rust disease on shrubs and ornamentals.

상품명

AI3-14689®; AAFERTIS®; APPLE DUST No. 1®[C]; BERCEMA FERTAM 50®; CASWELL No. 458®; FERBAM 50®; FERBECK®; FERMATE FERBAM FUNGICIDE®[C]; FERMOCIDE®; FERRADOUR®; FERRADOW®; FUKLASIN ULTRA®; HEXAFERB®; HOKMATE®; KARBAM BLACK®; KARBAM CARBAMATE®; KNOCKMATE®; NIACIDE®; STAUFFER FERBAM®; SUP’R-FLO FERBAM FLOWABLE®; TRICARBAMIX®[C]; TRIFUNGOL®; VANCIDE FE95®[C]

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. A fungicide. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also CARBAiMATES.

잠재적 노출

A dithiocarbamate. A potential danger to those involved in the production, formulation and application of this dithiocarbamate; used as a fungicide, rubber accelerator, and plastics prodegradant. Some dithiocarbamates have been used as rubber components

환경귀착

Plant. Decomposes in plants to ethylene thiourea, ethylene thiuram monosul?de, ethylene thiuram disul?de and sulfur (Hartley and Kidd, 1987).
Chemical/Physical. Hydrolyzes in acidic media releasing carbon disul?de. Decomposes in water forming ethylene thiourea (Hartley and Kidd, 1987).
Decomposes >180°C (Windholz et al., 1983) emitting toxic fumes of nitrogen and sulfur oxides (Lewis, 1990; Sax and Lewis, 1987).

신진 대사 경로

Ferbam generates dimethyldithiocarbamic acid by being cleaved in acidic conditions and in biological media. The acid is conjugated with glucose and alanine in plants and with glucuronic acid in mammals. Dimethyldithiocarbamic acid is further degraded to dimethylamine and CS2. An extensive review of the properties of the dithiocarbamate pesticides was published by the World Health Organisation (WHO, 1988) from which much of the following information is taken.

운송 방법

UN2771 Dithiocarbamate and Thiocarbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine,bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Heat alkalies (lime); moisture can cause decomposition. Decomposes on prolonged storage. Dithiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of Dithiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of dithiocarbamate with aldehydes, nitrides, and hydrides. Dithiocarbamate are incompatible with acids, peroxides, and acid halides.

폐기물 처리

Ferbam is hydrolyzed by alkali and is unstable to moisture, lime and heat. Ferbam can be incinerated. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal

퍼밤 준비 용품 및 원자재

원자재

준비 용품


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Hangzhou FandaChem Co.,Ltd.
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Chemson Industrial (Shanghai) Co., Ltd.
86-21-65208861- 8007
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Hubei Jusheng Technology Co.,Ltd.
18871490254
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Hubei xin bonus chemical co. LTD
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CONIER CHEM AND PHARMA LIMITED
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career henan chemical co
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