델타-헥사클로로사이클로헥산

델타-헥사클로로사이클로헥산
델타-헥사클로로사이클로헥산 구조식 이미지
카스 번호:
319-86-8
한글명:
델타-헥사클로로사이클로헥산
동의어(한글):
델타-헥사클로로사이클로헥산;(1a,2a,3a,4b,5a,6b)-1,2,3,4,5,6-헥사클로로사이클로헥세인;1-알파,2-알파,3-알파,4-베타,5-알파,6-베타-헥사클로로사이클로헥세인;델타-1,2,3,4,5,6-헥사클로로사이클로헥세인;델타-1,2,3,4,5,6-헥사클로로사이클로헥세인, 이성질체;델타-벤젠 헥사클로라이드;델타-벤젠헥사클로라이드;델타-헥사클로로사이클로헥세인;델타-1,2,3,4,5,6-헥사클로로사이클로헥산
상품명:
LINDANE
동의어(영문):
HCH;GAMMA-HCH;Δ-HCH;G-BHC;GEXANE;BENZENE HEXACHLORIDE;δ-hexachlorocyclohexane;GAMMA-BENZENE HEXACHLORIDE;d-1,2,3,4,5,6-Hexachlorocyclohexane;1ALPHA,2ALPHA,3BETA,4ALPHA,5ALPHA,6BETA-HEXACHLOROCYCLOHEXANE
CBNumber:
CB2281876
분자식:
C6H6Cl6
포뮬러 무게:
290.83
MOL 파일:
319-86-8.mol
MSDS 파일:
SDS

델타-헥사클로로사이클로헥산 속성

녹는점
113-115 °C(lit.)
끓는 점
373.64°C (rough estimate)
밀도
1.7152 (rough estimate)
증기압
3.52 at 25 °C (Banerjee et al., 1990)
굴절률
1.576-1.674 (589.3 nm 20℃)
인화점
11 °C
저장 조건
2-8°C
용해도
에탄올, 벤젠 및 클로로포름에 용해됨
물리적 상태
고체
물리적 상태
단단한 모양
BRN
1907334
Henry's Law Constant
(x 10-7 atm·m3/mol): 2.5 at 20 °C (approximate - calculated from water solubility and vapor pressure)
EPA
.delta.-Hexachlorocyclohexane (319-86-8)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N,F,Xn
위험 카페고리 넘버 20/21-25-48/22-50/53-64-39/23/24/25-23/24/25-11-40-21-67-65-38-52/53
안전지침서 36/37-45-60-61-22-16-7-62
유엔번호(UN No.) UN 2811 6.1/PG 1
WGK 독일 3
RTECS 번호 GV4900000
유해 물질 데이터 319-86-8(Hazardous Substances Data)
독성 Acute oral LD50 for rats 1,000 mg/kg (RTECS, 1985).
기존화학 물질 KE-05-0687
유해화학물질 필터링 97-1-62;06-4-51
함량 및 규제정보 물질구분: 유독물질; 혼합물(제품)함량정보: 헥사클로로시클로헥산 및 이를 1.5% 이상 함유한 혼합물
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H225 고인화성 액체 및 증기 인화성 액체 구분 2 위험 GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H370 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킴(노출되어도 특정 표적장기 독성을 일으키지 않는다는 결정적인 노출경로가 있다면 노출경로를 기재) 특정 표적장기 독성 - 1회 노출 구분 1 위험 GHS hazard pictograms P260, P264, P270, P307+P311, P321,P405, P501
H412 장기적 영향에 의해 수생생물에 유해함 수생 환경유해성 물질 - 만성 구분 3 P273, P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.

델타-헥사클로로사이클로헥산 C화학적 특성, 용도, 생산

화학적 성질

BHC is a white-to-brownish crystalline solid with a musty, phosgene-like odor.

물리적 성질

Solid crystals or fine platelets with a faint musty-like odor

용도

δ-1,2,3,4,5,6-Hexachlorocyclohexane is an organochloride annd is one of the isomers of hexachlorocyclohexane. aδ-1,2,3,4,5,6-Hexachlorocyclohexane is also an byproduct of insecticide Lindane (L465990) .

일반 설명

Slightly musty odor.

반응 프로필

LINDANE may be incompatible with strong oxidizing and reducing agents. Incompatible with some amines, nitrides, azo/diazo compounds, with alkali metals, and with epoxides.

건강위험

ACUTE/CHRONIC HAZARDS: Highly toxic. May cause irritation on contact. Hazardous decomposition products.

잠재적 노출

The major commercial usage of BHC is based upon its insecticidal properties. α-BCH is used as an Agricultural chemical, pesticide, pharmaceutical, and veterinary drug. The 7-isomer has the highest acute toxic ity, but the other isomers are not without activity. It is gen erally advantageous to purify the 7-isomer from the less active isomers. The γ-isomer acts on the nervous system of insects, principally at the level of the nerve ganglia. As a result, lindane has been used against insects in a wide range of applications including treatment of animals, buildings, humans for ectoparasites, clothes; water for mosquitoes; living plants; seeds and soils. Some applications have been abandoned due to excessive residues, e.g., stored food stuffs. By voluntary action, the principal domestic producer of technical grade BHC requested cancellation of its BHC registrations on September 1, 1976. As of July 21, 1978, all registrants of pesticide products containing BHC voluntar ily canceled their registrations or switched their former BHC products to lindane formulations.

환경귀착

Biological. Dehydrochlorination of δ-BHC by a Pseudomonas sp. under aerobic con ditions was reported by Sahu et al. (1992). They also reported that when deionized water containing δ-BHC was inoculated with Pseudomonas sp., the concentration of δ-BHC decreased to undetectable levels after 8 days with concomitant formation of chloride ions and δ-pentachlorocyclohexane. In four successive 7-day incubation periods, δ-BHC (5 and 10 mg/L) was recalcitrant to degradation in a settled domestic wastewater inoculum (Tabak et al., 1981).
Chemical/Physical. δ-BHC dehydrochlorinates in the presence of alkalies. The hydrol ysis half-lives at pH values of 7 and 9 are 191 days and 11 hours, respectively (Worthing and Hance, 1991).

운송 방법

UN2761 Organochlorine pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Decomposes on contact with powdered iron, aluminum, zinc, and on contact with strong bases producing trichlorobenzene.

폐기물 처리

A process has been developed for the destructive pyrolysis of benzene hexachloride @ 400 500℃ with a catalyst mixture which contains 5 10% of either cupric chloride, ferric chloride; zinc chloride; or aluminum chloride on activated carbon.

델타-헥사클로로사이클로헥산 준비 용품 및 원자재

원자재

준비 용품


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