1-메톡시-9H-카바졸-3-카브알데하이드

1-메톡시-9H-카바졸-3-카브알데하이드
1-메톡시-9H-카바졸-3-카브알데하이드 구조식 이미지
카스 번호:
723-97-7
한글명:
1-메톡시-9H-카바졸-3-카브알데하이드
동의어(한글):
1-메톡시-9H-카바졸-3-카브알데하이드
상품명:
1-Methoxy-9H-carbazole-3-carbaldehyde
동의어(영문):
Murrayanine;1-Methoxy-9H-carbazole-3-carbaldehyde;9H-Carbazole-3-carboxaldehyde, 1-methoxy-
CBNumber:
CB32223213
분자식:
C14H11NO2
포뮬러 무게:
225.24
MOL 파일:
723-97-7.mol

1-메톡시-9H-카바졸-3-카브알데하이드 속성

녹는점
168°C
끓는 점
466.4±25.0 °C(Predicted)
밀도
1.312±0.06 g/cm3(Predicted)
산도 계수 (pKa)
16.49±0.30(Predicted)

안전

1-메톡시-9H-카바졸-3-카브알데하이드 C화학적 특성, 용도, 생산

개요

This simple carbazole alkaloid is found in the stem bark of Mu"aya koenigii Spreng. It is best purified by sublimation of the crude base when it yields colour_x0002_less crystals. The ultraviolet spectrum in ethanol has absorption maxima at 238, 247,274,289 and 335 mJJ.. The structure has been shown to be 3-formyl-lmethoxycarbazole by spectroscopic methods and synthesis. It yields an oxime, m.p. l55-6°C; a picrate, m.p. 198-2000 C and the 2:4-dinitrophenylhydrazone, m.p. > 300°C. The N-methyl derivative forms colourless needles from C6H6- light petroleum, m.p. l48-9°C. When subjected to Wolff-Kishner reduction, the alkaline phase yields l-hydroxy-3-methyl-carbazole.

정의

ChEBI: A natural product found in Clausena harmandiana.

참고 문헌

Chakraborty, Barman, Bose., Tetrahedron, 21, 681 (1965)
Synthesis: Crum, Sprague., Chern. Cornrnun., 417 (1966)
Chakraborty, Chowdhury., J. Org. Chern., 33, 1265 (1968)

1-메톡시-9H-카바졸-3-카브알데하이드 준비 용품 및 원자재

원자재

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