2,4,6-트리클로로페놀

2,4,6-트리클로로페놀
2,4,6-트리클로로페놀 구조식 이미지
카스 번호:
88-06-2
한글명:
2,4,6-트리클로로페놀
동의어(한글):
2,4,6-트리클로로페놀;2,4,6-트라이클로로페놀
상품명:
2,4,6-Trichlorophenol
동의어(영문):
2,4,6-TCP;Phenol, 2,4,6-trichloro-;2,4,6-TrichL;2,4,6-Trichlorophenol (2,4,6-Tcp);OMAL;2,4,6 T;ai3-00142;dowcide2s;phenaclor;BTS 45186
CBNumber:
CB3854536
분자식:
C6H3Cl3O
포뮬러 무게:
197.45
MOL 파일:
88-06-2.mol
MSDS 파일:
SDS

2,4,6-트리클로로페놀 속성

녹는점
64-66 °C(lit.)
끓는 점
246 °C(lit.)
밀도
1.49
증기압
1 mm Hg ( 76.5 °C)
굴절률
1.5300 (estimate)
인화점
99 °C
저장 조건
Store below +30°C.
용해도
0.8g/L
물리적 상태
결정질 덩어리 또는 결정질 분말 및 덩어리
산도 계수 (pKa)
6.15 (Leuenberger et al., 1985)
6.10 (Blackman et al., 1955)
6.0 (Eder and Weber, 1980)
색상
흰색에서 약간 갈색
수용성
0.8g/L
Merck
14,9644
BRN
776729
Henry's Law Constant
9.07 at 25 °C (estimated, Leuenberger et al., 1985a)
CAS 데이터베이스
88-06-2(CAS DataBase Reference)
IARC
2B (Vol. 117) 2019
NIST
Phenol, 2,4,6-trichloro-(88-06-2)
EPA
2,4,6-Trichlorophenol (88-06-2)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,N,T,F
위험 카페고리 넘버 22-36/38-50/53-40-52/53-39/23/24/25-23/24/25-11-51/53
안전지침서 36/37-60-61-45-16
유엔번호(UN No.) UN 3077 9/PG 3
WGK 독일 3
RTECS 번호 SN1575000
TSCA Yes
위험 등급 6.1
포장분류 III
HS 번호 29081000
유해 물질 데이터 88-06-2(Hazardous Substances Data)
독성 LD50 orally in Rabbit: 887 mg/kg
기존화학 물질 KE-34087
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H351 암을 일으킬 것으로 의심됨 (노출되어도 암을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 발암성 물질 구분 2 경고 P201, P202, P281, P308+P313, P405,P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P201 사용 전 취급 설명서를 확보하시오.
P273 환경으로 배출하지 마시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.
NFPA 704
1
2 0

2,4,6-트리클로로페놀 MSDS


2,4,6-TCP

2,4,6-트리클로로페놀 C화학적 특성, 용도, 생산

화학적 성질

Yellow flakes; strong phenolic odor. Soluble in acetone, alcohol, and ether; insoluble in water. Nonflammable.

물리적 성질

Colorless needles or yellow solid with a strong, phenolic, musty or rotten vegetable-type odor. At 40 °C, the lowest concentration at which an odor was detected was 380 μg/L. At 25 °C, the lowest concentration at which a taste was detected was >12 μg/L (Young et al., 1996).

용도

2,4,6-Trichlorophenol is used as a broad range pesticide against insects, fungi, vegetation and bacteria. It has become a common environmental contaminant and probable human carcinogen.

정의

ChEBI: A trichlorophenol with phenolic substituents on positions 2, 4 and 6.

공기와 물의 반응

Insoluble in water.

반응 프로필

2,4,6-Trichlorophenol is incompatible with acid chlorides, acid anhydrides and oxidizing agents. 2,4,6-Trichlorophenol can be converted to the sodium salt by reaction with sodium carbonate. Forms ethers, esters and salts by reaction with metals and amines. Undergoes substitution reactions such as nitration, alkylation, acetylation and halogenation. Can be hydrolyzed by reaction with bases at elevated temperatures and pressures. Reacts with alkalis at high temperatures .

건강위험

In experimental animals, 2,4,6- trichlorophenol causes toxic effects to the liver and hematologic system and cancer. There is no reliable information regarding exposure and toxic effects in humans.

화재위험

Literature sources indicate that 2,4,6-Trichlorophenol is nonflammable.

Safety Profile

Confirmed carcinogen with experimental carcinogenic data. Poison by intraperitoneal route. Moderately toxic by ingestion and skin contact. A skin and severe eye irritant. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl-. Used as a germicide and preservative. See also CHLOROPHENOLS.

Carcinogenicity

2,4,6-Trichlorophenol is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

환경귀착

Biological. In activated sludge, only 0.3% mineralized to carbon dioxide after 5 d (Freitag et al., 1985). In anaerobic sludge, 2,4,6-trichlorophenol degraded to 4-chlorophenol (Mikesell and Boyd, 1985). When 2,4,6-trichlorophenol was statically incubated in the dark at 25 °C with yeast extract and settled domestic wastewater inoculum, significant biodegradation with rapid adaptation was observed. At concentrations of 5 and 10 mg/L, 96 and 97% biodegradation, respectively, were observed after 7 d (Tabak et al., 1981).
Photolytic. Titanium dioxide suspended in an aqueous solution and irradiated with UV light (λ = 365 nm) converted 2,4,6-trinitrophenol to carbon dioxide at a significant rate (Matthews, 1986). A carbon dioxide yield of 65.8% was achieved when 2,4,6-trichlorophenol adsorbed on silica gel was irradiated with light (λ >290 nm) for 17 h (Freitag et al., 1985).
Chemical/Physical. An aqueous solution containing chloramine reacted with 2,4,6-trichlorophenol to yield the following intermediate products after 2 h at 25 °C: 2,6-dichloro-1,4- benzoquinone-4-(N-chloro)imine and 4,6-dichloro-1,2-benzoquinone-2-(N-chloro)imine (Maeda et al., 1987).

Purification Methods

Crystallise the phenol from *benzene, EtOH or EtOH/water. [Beilstein 6 IV 1005.]

2,4,6-트리클로로페놀 준비 용품 및 원자재

원자재

준비 용품


2,4,6-트리클로로페놀 공급 업체

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