프로피온알데히드
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프로피온알데히드 속성
- 녹는점
- -81 °C (lit.)
- 끓는 점
- 46-50 °C (lit.)
- 밀도
- 0.805 g/mL at 25 °C (lit.)
- 증기 밀도
- 2 (vs air)
- 증기압
- 18.77 psi ( 55 °C)
- 굴절률
- n
20/D 1.362(lit.)
- 인화점
- −16 °F
- 저장 조건
- Store at <= 20°C.
- 용해도
- 클로로포름에 용해됨; 알코올 및 에테르와 섞임
- 물리적 상태
- 액체
- 색상
- 하얀색
- Specific Gravity
- 0.815 (20/4℃)
- 냄새
- 프로필렌 글리콜 중 0.10%. 흙, 알코올, 와인, 위스키, 코코아, 견과류
- ?? ??
- 미묘한
- 폭발한계
- 2.3-21%(V)
- Odor Threshold
- 0.001ppm
- 수용성
- 540g/L(20℃)
- 감도
- Air Sensitive
- Merck
- 14,7823
- JECFA Number
- 83
- BRN
- 506010
- Dielectric constant
- 18.9(17℃)
- 노출 한도
- ACGIH: TWA 20 ppm
- 안정성
- 안정적인. 가연성이 높습니다. 산화제, 강산, 강염기와 호환되지 않습니다.
- InChIKey
- NBBJYMSMWIIQGU-UHFFFAOYSA-N
- LogP
- 0.59 at 25℃
- CAS 데이터베이스
- 123-38-6(CAS DataBase Reference)
- NIST
- Propanal(123-38-6)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | F,Xi,Xn | ||
---|---|---|---|
위험 카페고리 넘버 | 11-36/37/38-R36/37/38-R11-41-37/38-20/22 | ||
안전지침서 | 9-16-29-S9-S29-S16 | ||
유엔번호(UN No.) | UN 1275 3/PG 2 | ||
WGK 독일 | 1 | ||
RTECS 번호 | UE0350000 | ||
자연 발화 온도 | 404 °F | ||
TSCA | Yes | ||
위험 등급 | 3 | ||
포장분류 | II | ||
HS 번호 | 29121900 | ||
유해 물질 데이터 | 123-38-6(Hazardous Substances Data) | ||
독성 | LD50 orally in rats: 1.4 g/kg; LC for rats in air: 8000 ppm (Smyth) | ||
기존화학 물질 | KE-29254 |
프로피온알데히드 C화학적 특성, 용도, 생산
개요
Propionaldehyde is a volatile liquid substance which consists of one carbonyl group and its characteristic functional group. The main functional group is an aldehyde which classifies propionaldehyde in the carbonyls. The main trunk of this substance is a short aliphatic chain. The carbonyl group determines, to a large extent, its chemical properties and most importantly its nucleophilic property. Propionaldehyde is readily oxidized if in contact to oxygen and should therefore be stored under inert gases.화학적 성질
Propionaldehyde has a characteristic sharp and pungent odor similar to acetaldehyde.It undergoes reactions typical for the low molecular weight aldehydes, which, because of the terminal carbonyl group, are very reactive. Contamination or the exposure to elevated temperatures may induce a hazardous polymerization.Propionaldehyde is a colorless, flammable liquid with a suffocating fruity odor. It is used as Intermediate for the chemical industry, for example for the manufacture of pharmaceuticals, pesticides, perfumes and plastics.
출처
Reported found in apple aroma and in the essential oils of camphor, Rosa centifolia, clary sage, Pinus excelsa and Pinus silverstris. Also reported found in over 100 natural products including apple, banana, sweet cherry, sour cherry, black currant grapes, melon, pineapple, strawberry, cabbage, carrot, celery, cucumber, garlic, onion, leek, potato, peas, rutabaga, tomato, Scotch spearmint oil, vinegar, bread and bread preferment, blue cheeses, cheddar cheese, Swiss cheese, butter, milk, cream, boiled egg, caviar, fatty fish, cooked turkey, beef, pork and chicken, beer, rum, cognac, whiskies, grape wines, coffee, cocoa, tea, roasted filberts and peanuts, peanut oil, potato chips, pecans, oats, honey, soybeans, Arctic bramble, beans, Bantu beer, plum brandy, cauliflower, Brussels sprouts, rice, prickly pear, peated malt, clary sage, truffle, krill, oysters, loganberry, Chinese quince and maté.용도
Propionaldehyde is produced by the oxo reaction of ethylene with carbon monoxide and hydrogen. n-Propyl alcohol is produced by hydrogenation of propionaldehyde, and propionic acid is made by oxidation of propionaldehyde.n-Propyl alcohol is used as solvent in printing inks and as an intermediate in the preparation of agricultural chemicals. Propionic acid is used as a grain preservative as, for example, in preventing spoilage of wet corn used as animal feed. The use of propionic acid as a grain preservative is an alterna tive to drying by heating, which consumes fuel, and is considered mostly when fuel is expensive.
제조 방법
Propionaldehyde is prepared in the usual way by the oxidation of n-propyl alcohol. It can also be prepared by dehydrogenating the alcohol by passing the vapors over a heated copper or brass catalyst. This avoids the danger of further oxidation to propionic acid.The reactions of propionaldehyde are practically like those of acetaldehyde. It must be remembered that only the two alpha hydrogen atoms are active in replacement and condensation reactions.
정의
ChEBI: An aldehyde that consists of ethane bearing a formyl substituent. The parent of the class of propanals.일반 설명
A clear colorless liquid with an overpowering fruity-like odor. Less dense than water. Flash point 15°F. Vapors are heavier than air.공기와 물의 반응
Highly flammable. Soluble in water.반응 프로필
Propionaldehyde may form explosive peroxides. Reacts vigorously with oxidizing agents. Explosive in the form of vapor when exposed to heat or flame [Lewis]. Incompatible with strong bases and strong reducing agents. Vigorous polymerization reaction with methyl methacrylate. Polymerization may also occur in the presence of acids or caustics .위험도
Flammable, dangerous fire risk, explosive limits in air 3.0–16%. Upper respiratory tract irri- tant.건강위험
Propionaldehyde is a mild irritant to humanskin and eyes. The irritation effect from40 mg was severe in rabbits’ eyes. The toxicityof this compound observed in test animalswas low. Subcutaneous administration in ratsexhibited the symptoms of general anestheticeffect, convulsion, and seizure. Inhalationtoxicity was determined to be low. A concentrationof 8000 ppm (19,000 mg/m3) inair was lethal to rats.LD50 value, oral (rats): 1400 mg/kg
LD50 subcutaneous (rats): 820 mg/kg.
화재위험
Behavior in Fire: Vapor is heavier than air and may travel considerable distance to a source of ignition and flash back.Safety Profile
Moderately toxic by skin contact, ingestion, and subcutaneous routes. Mddly toxic by inhalation. A skin and severe eye irritant. Flammable liquid. Dangerous fire hazard when exposed to heat or flame; reacts vigorously with oxidizers. Explosive in the form of vapor when exposed to heat or flame. Vigorous polymerization reaction with methyl methacrylate. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.잠재적 노출
Used as a synthetic flavoring; as a disinfectant and preservative; to make propionic acid; in plastic and rubber manufacturing; to make alkyl resins and plasticizers.Carcinogenicity
In a mutagenic test in V79 cells, Eder et al. observed that propionaldehyde is not mutagenic at 1 mM, but is toxic at 2mM. Similar to acrolein, Eder et al. suggested that the mutagenicity of this compound is mediated by its bifunctionality, whereas its cytotoxicity is mediated by the aldehyde function.운송 방법
UN1275 Propionaldehyde, Hazard Class: 3; Labels: 3-Flammable liquid.Propionaldehyde is readily oxidized if in contact to oxygen and should therefore be stored under inert gases.
Purification Methods
the aldehyde with CaSO4 or CaCl2, and fractionally distil it under nitrogen or in the presence of a trace of hydroquinone (to retard oxidation). Blacet and Pitts [J Am Chem Soc 74 3382 1952] repeatedly distilled the middle fraction in a vacuum until it no longer gave a solid polymer when cooled to -80o. It is stored with CaSO4. [Beilstein 1 IV 3165.]비 호환성
Incompatible with strong acids; amines. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoa- cids, epoxides. Strong caustics; reducing agents can cause explosive polymerization. Can self-ignite if finely dispersed on porous or combustible material, such as fabric. Heat or UV light can cause decomposition. Aldehydes are fre- quently involved in self-condensation or polymerization reactions. These reactions are exothermic; they are often catalyzed by acid. Aldehydes are readily oxidized to give carboxylic acids. Flammable and/or toxic gases are gener- ated by the combination of aldehydes with azo, diazo com- pounds, dithiocarbamates, nitrides, and strong reducing agents. Aldehydes can react with air to give first peroxo acids, and ultimately carboxylic acids. These autoxidation reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). The addition of stabilizers (anti- oxidants) to shipments of aldehydes retards autoxidation폐기물 처리
Propionaldehyde is destroyed by burning in achemical incinerator equipped with an afterburnerand scrubber. Permanganate oxidationis a suitable laboratory method of destruction.프로피온알데히드 준비 용품 및 원자재
원자재
일산화탄소(가스)
아크롤레인
Dichromate, Ion chromatography standard solution, Specpure, Cr2O7ˉ2 1000μg/ml
Vanadium catalyst
팔라듐 염화물
수소
포스핀(기체)
코발트 카보닐
산화프로필렌
1-클로로프로판
준비 용품
5-메틸-2-피롤-1-일-티오펜-3-카르복실산
Pramipexole
2,3,5-Collidine
2,2-비스(히드록시메틸)프로판 산
2-AMINO-5-METHYLTHIAZOLE
1-(2,6-DIFLUOROPYRIDIN-3-YL)PROPAN-1-ONE
2-Methyl-2-pentenoic acid
프로피온산
고-밀도 폴리에틸렌
N-Ethylpropylamine
2-아미노-5-메틸-티오펜-3-카르복실산에틸에스테르
이미다클로프리드
6-METHYL-3H-THIENO[2,3-D]PYRIMIDIN-4-ONE
2-(Chloromethyl)-6-methylthieno[2,3-d]pyrimidin-4(3H)-one ,97%
ETHYL 3,4-DIHYDRO-6-METHYL-4-OXOTHIENO[2,3-D]PYRIMIDINE-2-CARBOXYLATE
디프로필 케톤
프로필아민
1-페닐-1-프로판올
Imidacloprid
1-프로판올
2-메틸-펜트-4-ENAL
프로피온알데히드 공급 업체
글로벌( 493)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Hebei Weibang Biotechnology Co., Ltd | +8615531157085 |
abby@weibangbio.com | China | 8810 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 |
sales@hbmojin.com | China | 12834 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 |
sales1@chuanghaibio.com | China | 5889 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21634 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29880 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28172 | 58 |
Jinan Finer Chemical Co., Ltd | +86-531-88989536 +86-15508631887 |
sales@finerchem.com | China | 2961 | 58 |
QUALITY CONTROL CHEMICALS INC. | (323) 306-3136 |
orders@qcchemical.com | United States | 26 | 58 |
Xiamen AmoyChem Co., Ltd | +86-86-5926051114 +8618959220845 |
sales@amoychem.com | China | 6383 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22963 | 58 |