이르가녹스3052

이르가녹스3052
이르가녹스3052 구조식 이미지
카스 번호:
61167-58-6
한글명:
이르가녹스3052
동의어(한글):
이르가녹스3052
상품명:
Irganox 3052
동의어(영문):
AN GM;At 3052;HS 3052;AO-3052;JADEADD GM;JADEWIN GM;Sumilizer GM;IRGANOX 3052;antioxygenGM;PowerNox 3052
CBNumber:
CB6254573
분자식:
C26H34O3
포뮬러 무게:
394.55
MOL 파일:
61167-58-6.mol

이르가녹스3052 속성

녹는점
128-133°C
끓는 점
491℃
밀도
1.03
인화점
185℃
저장 조건
-20°C Freezer, Under inert atmosphere
용해도
클로로포름(약간 용해됨), 에틸아세테이트(약간 용해됨)
산도 계수 (pKa)
11.66±0.48(Predicted)
물리적 상태
고체
물리적 상태
단단한 모양
색상
흰색에서 황백색까지
수용성
123ng/L at 20℃
EPA
2-tert-Butyl-6-(3-tert-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenyl acrylate (61167-58-6)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
기존화학 물질 KE-04233
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P272 작업장 밖으로 오염된 의복을 반출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P321 (…) 처치를 하시오.
P333+P313 피부자극성 또는 홍반이 나타나면 의학적인 조치·조언를 구하시오.
P363 다시 사용전 오염된 의류는 세척하시오.
P501 ...에 내용물 / 용기를 폐기 하시오.

이르가녹스3052 C화학적 특성, 용도, 생산

개요

Irganox 3052 is an antioxidant. It contains 2-(1,1-dimethylethyl)-6-[[3-(1,1-dimethylethyl)-2-hydroxy-5-methylphenylymethyl-4-methylphenyl acrylate. It is non-staining, non-discoloring, has a low volatility and is resistant to extraction. It protects organic substrates against both, thermo-oxidative and purely thermal degradation. It is particularly active under high processing temperature and anaerobic polymerization and processing conditions. It is compatible with HIPS, ABS, BR, IIR, SBR, SBS, SEBS, EPDM, EPM, MBS, MABS, SMA, modified acrylate, hydrocarbon resins, terpene, terpene phenolic resins, rosin, polycarbonates, polyester-carbonates, polymethacrylates, polyolefins, polyamides or polyphenyleneoxides. Irganox 3052 is suitable for food contact applications. It is listed in AICS, EINECS, PICCS, DSL, MITI, TSCA, CHINA and ECL.

용도

Irganox 3052 has been used in to study the mechanical properties and performance of stretch films of plasticized PVC and non-PVC alternatives used for retail fresh meat packaging; heat stabilizers for butadiene-styrene copolymers;

Synthesis

To a 2-liter four-necked flask equipped with a thermometer, stirring apparatus, condenser and dropping funnel were added 340.51 g (1.0 mol) of 2,2'-methylenebis(6-tert-butyl-4-methylphenol), 72.06 g (1.0 mol) of acrylic acid, 500 g of toluene and 209.47 g (2.07 mol) of triethylamine. After replacing the air in the container with nitrogen, 105.8 g (0.69 mol) of phosphorus oxychloride was added dropwise with stirring. After completion of the dropwise addition, the reaction solution was kept at 80 ℃. for 1 hour. After that, the organic layer was washed with water until it became neutral, and toluene was removed under reduced pressure. The residue was then recrystallized from n-hexane to obtain 374.8 g of a white crystalline 2,2'-methylenebis(6-tert-butyl-4-methylphenol) monoacrylate (Irganox 3052) having a melting point of 132 to 134 ℃. Yield, 95%.

이르가녹스3052 준비 용품 및 원자재

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준비 용품


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