아이오도소벤젠
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아이오도소벤젠 속성
- 녹는점
- 210°C (rough estimate)
- 밀도
- 1.8665 (estimate)
- 저장 조건
- Freezer
- 수용성
- 물에 약간 용해됨
- 용해도
- 메탄올(약간), TFA(약간)에 용해됨
- 물리적 상태
- powder to crystal
- 색상
- White to Yellow to Green
- Merck
- 14,5044
- InChIKey
- JYJVVHFRSFVEJM-UHFFFAOYSA-N
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
안전지침서 | 17-36/37/39 | ||
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유엔번호(UN No.) | 1479 | ||
RTECS 번호 | DA3500000 | ||
위험 등급 | 4.1 | ||
포장분류 | II | ||
HS 번호 | 29039990 |
아이오도소벤젠 C화학적 특성, 용도, 생산
화학적 성질
Iodosobenzene is an amorphous yellow substance; it explodes at 210℃, decomposing with the evolution of iodine vapour, and dissolves in hot water and alcohol. If acids do not oxidise C6H5IO, they give saline compounds in which iodosobenzene appears as a basic oxide of a diatomic metal, C6H5I. Thus, for instance, when an acetic acid solution of iodosobenzene is treated with a solution of nitric acid, it gives large monoclinic crystals of a nitric acid salt having the composition C6H5(NO3)2 [like Ca(NO3)2). Iodosobenzene displaces iodine from potassium iodide (in a solution acidulated with acetic or hydrochloric acid)-ie, it acts with its oxygen like HClO. The action of peroxide of hydrogen, chromic acid, and other similar oxidising agents gives C6H5IO2, which is a neutral substance-i.e, is incapable of giving salts with acids.Iodosobenzene is one of the very first oxidants and remains in use because it has excellent oxygen-transfer behavior and mechanistic cleanliness (Hill & Schardt, 1980; Rezaeifard et al., 2007; Po?towicz et al., 2006).
The Principles of Chemistry Volume 1
용도
Oxygen transfer reagent for stiochiometric or catalytic cross-functionalization of alkenes, alcohols, sulfides, and organometallo Compounds.Iodosobenzene is used as an oxidizing and acetoxylating agent in organic synthesis. It is actively involved in the preparation of (Z)-3,7-dimethyl-2,6-octadien-1-al(neral) from (Z)-3,7-dimethyl-2,6-octadien-1-ol (nerol) in presence of 2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO). It is a useful reagent for the synthesis of a wide variety of heterocyclic compounds. It is also used in the Pd-catalyzed 2-arylation of indoles.
Synthesis
Iodosobenzene has been prepared by the action of sodium or potassium hydroxide solution on iodobenzene dichloride and by addition of water to the dichloride.![Synthesis of Iodosobenzene](/NewsImg/2021-09-25/6376815722936478253169480.jpg)
Iodosobenzene is prepared from iodobenzene.It is prepared by first oxidizing iodobenzene by peracetic acid. Hydrolysis of resulting diacetate affords "PhIO":
C6H5I + CH3CO3H + CH3CO2H → C6H5I(O2CCH3)2 + H2O
C6H5I(O2CCH3)2 + H2O → C6H5IO + 2CH3CO2H
http://orgsyn.org
아이오도소벤젠 준비 용품 및 원자재
원자재
준비 용품
아이오도소벤젠 공급 업체
글로벌( 117)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21673 | 55 |
Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49391 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
factory@coreychem.com | China | 29826 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 |
sales@tnjchem.com | China | 34571 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 |
1026@dideu.com | China | 9030 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 |
info@dycnchem.com | China | 52861 | 58 |
sgtlifesciences pvt ltd | +8617013299288 |
dj@sgtlifesciences.com | China | 12382 | 58 |
Nanjing Doge Biomedical Technology Co., Ltd | +86-25-58227606 +86-15305155328 |
sales@dogechemical.com | China | 4128 | 58 |
GIHI CHEMICALS CO.,LIMITED | +8618058761490 |
info@gihichemicals.com | China | 49999 | 58 |
아이오도소벤젠 관련 검색:
2,5-시클로헥사디엔-1,4-디온 1-브로모벤젠 DDT (디디티) 아이오도벤젠 2-아이오도소벤조산
Nitrobenzene
2',3'-Dideoxythymidine
1-BUTENE
[Hydroxy(tosyloxy)iodo]benzene
IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE),Iodosobenzene-bis(trifluoroacetate)
IODOSOBENZENE DIACETATE,IODOSOBENZENE I,I-DIACETATE,Iodobenzene I,I-diacetate, Iodosobenzene I,I-diacetate
Iodosobenzene
2-Iodoxybenzoic acid
1-HYDROXY-1,3-DIOXO-1,3-DIHYDRO-1L5-BENZO[D][1,2]IODOXOLE-4-CARBOXYLIC ACID
Iodoxybenzene
O-IODOSOBENZOIC ACID, SODIUM SALT
IODOSOBENZENE DIACETATE, [(DIACETOXYIODO)BENZENE; PHENYLIODOSODIACETATE)
BENZOIC ACID, 2-IODYL, 1-METHYLETHYL ESTER