2-브로모에틸아민 브롬화수소산염

2-브로모에틸아민 브롬화수소산염
2-브로모에틸아민 브롬화수소산염 구조식 이미지
카스 번호:
2576-47-8
한글명:
2-브로모에틸아민 브롬화수소산염
동의어(한글):
2-브로모에틸아민브롬화수소산염
상품명:
2-Bromoethylamine hydrobromide
동의어(영문):
2BEHR;JACS-2576-47-8;BromoethylamineHbr;2-Bromoethanamine HBr;AMINOETHYL BROMIDE HBR;2-BROMOETHYLAMINE HBR 99%;2-(DIALLYLAMINO)ETHYLAMINE;2-Bromoethylazanium bromide;bromoethylamine,hydrobromide;2-BROMOETHYLAMMONIUM BROMIDE
CBNumber:
CB7232631
분자식:
C2H7Br2N
포뮬러 무게:
204.89
MOL 파일:
2576-47-8.mol
MSDS 파일:
SDS

2-브로모에틸아민 브롬화수소산염 속성

녹는점
172 °C
끓는 점
181.3℃[at 101 325 Pa]
밀도
1.9061 (rough estimate)
증기압
0.001Pa at 25℃
굴절률
1.5393 (estimate)
저장 조건
Store below +30°C.
용해도
>500g/L
물리적 상태
결정질 분말 또는 결정
색상
흰색~밝은 베이지
수소이온지수(pH)
2.9 (10g/l, H2O, 20℃)
수용성
> 500g/L(20℃)
감도
Hygroscopic
BRN
3607605
LogP
0.795 at 25℃
CAS 데이터베이스
2576-47-8(CAS DataBase Reference)
EPA
2-Bromoethylamine hydrobromide (2576-47-8)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi,C,Xn
위험 카페고리 넘버 36/37/38-68-52/53-43-22
안전지침서 26-36/37-61-36/37/39-36
WGK 독일 3
RTECS 번호 KQ8225000
F 고인화성물질 3-10
위험 참고 사항 Irritant
TSCA Yes
위험 등급 IRRITANT, CORROSIVE
HS 번호 29211980
독성 LD50 orally in Rabbit: > 200 - 2000 mg/kg
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H412 장기적 영향에 의해 수생생물에 유해함 수생 환경유해성 물질 - 만성 구분 3 P273, P501
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P273 환경으로 배출하지 마시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P501 ...에 내용물 / 용기를 폐기 하시오.
NFPA 704
0
2 1

2-브로모에틸아민 브롬화수소산염 MSDS


2-Bromoethylamine hydrobromide

2-브로모에틸아민 브롬화수소산염 C화학적 특성, 용도, 생산

화학적 성질

slight yellow to white crystalline powder. Soluble in water and methanol, insoluble in ether. Hygroscopic and moisture sensitive. Incompatible with strong oxidizing agents.

용도

2-Bromoethylamine hydrobromide is used to construct C2-symmetric imidazolidinylidene ligands with a dioxolane backbone. It acts as a building block which is used for proteomics research. It is also used as organic and pharmaceutical intermediates for the preparation of first-aid medicines.

주요 응용

2-Bromoethylamine hydrobromide (BEA-HBr) can be used as a reactant in the preparation of:
Amino-functionalized ionic liquid, 1-aminoethyl-3-methylimidazolium hexafluorophosphate ([2-aemim][PF6]). [2-aemim][PF6] is employed as a catalyst in the synthesis of 4H-pyrans derivatives by treating with aromatic aldehydes, malononitrile, ethyl acetoacetate via Knoevenagel condensation reaction.
2-(N-aryl-N-aroyl)amino-4,5-dihydrothiazole derivatives via cyclocondensation reaction.
It can be also employed as an alkylating agent for the surface modification of nylon to obtain primary/secondary/tertiary amine groups.

제조 방법

2-Bromoethylamine hydrobromide was synthesized by bromination of ethanolamine. Drop into hydrobromic acid in the reaction pot, cool, add ethanolamine dropwise under stirring, and finish adding dropwise within half an hour, then steam the hydrobromic acid of 85% of the input quantity (the feed quantity of hydrobromic acid is 8.89 times the weight of ethanolamine) , about 20h steamed. After the concentrated solution is cooled to 70-80°C, it is put into pre-chilled acetone, cooled to below 5°C, and the crystallized 2-bromoethylamine hydrobromide is filtered out. Yield 70%.

일반 설명

Crystals.

공기와 물의 반응

Water soluble.

반응 프로필

The acidic organic salt (HBr) of the amine. Acidic salts are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

건강위험

ACUTE/CHRONIC HAZARDS: When heated to decomposition 2-Bromoethylamine hydrobromide emits very toxic fumes of bromide ion, NOx and hydrogen bromide.

화재위험

Flash point data for 2-Bromoethylamine hydrobromide are not available; however, 2-Bromoethylamine hydrobromide is probably combustible.

2-브로모에틸아민 브롬화수소산염 준비 용품 및 원자재

원자재

준비 용품


2-브로모에틸아민 브롬화수소산염 공급 업체

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