벤타존

벤타존
벤타존 구조식 이미지
카스 번호:
25057-89-0
한글명:
벤타존
동의어(한글):
벤타존;벤타존(BENTAZON)
상품명:
Bentazone
동의어(영문):
BENTAZON;leader;GALAXY;Bendioxide;3-isopropyl-1h-2,1,3-benzothiadiazin-4(3h)-one-2,2-dioxide;laddok;Adagio;Thianon;bas3510;Bazargan
CBNumber:
CB7235319
분자식:
C10H12N2O3S
포뮬러 무게:
240.28
MOL 파일:
25057-89-0.mol
MSDS 파일:
SDS

벤타존 속성

녹는점
137-139°C
끓는 점
395.7±25.0 °C(Predicted)
밀도
1.3387 (rough estimate)
굴절률
1.5650 (estimate)
인화점
2 °C
저장 조건
APPROX 4°C
용해도
클로로포름(약간 용해됨), 메탄올(약간 용해됨)
산도 계수 (pKa)
pKa (24°): 3.3
물리적 상태
고체
물리적 상태
단단한 모양
색상
하얀색
수용성
0.5g/L(20℃)
Merck
13,1051
BRN
530220
NIST
Bentazone(25057-89-0)
EPA
Bentazon (25057-89-0)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,F
위험 카페고리 넘버 22-36-43-52/53-20/21/22-11
안전지침서 2-24-37-61-36-26-16
유엔번호(UN No.) UN 1648 3/PG 2
WGK 독일 2
RTECS 번호 DK9900000
HS 번호 29349990
유해 물질 데이터 25057-89-0(Hazardous Substances Data)
독성 LD50 in male, female rats (mg/kg): 383.2, 433.6 orally (Ugazio)
기존화학 물질 KE-21678
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H412 장기적 영향에 의해 수생생물에 유해함 수생 환경유해성 물질 - 만성 구분 3 P273, P501
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
0
2 0

벤타존 MSDS


3-Isopropyl-1H-2,1,3-benzothiadiazin-4(3H)-one-2,2-dioxide

벤타존 C화학적 특성, 용도, 생산

개요

Bentazon is unique under these herbicides because it is the only compound that bears a sulfonyl group. A puzzle that is not solved yet is that bentazone is an excellent herbicide but has a very low pI50-value.

화학적 성질

Bentazon is a colorless to white crystalline powder.

용도

Herbicide.

정의

ChEBI: A benzothiadiazine that is 1H-2,1,3-benzothiadiazin-4(3H)-one 2,2-dioxide substituted by an isopropyl group at position 3.

농업용

Selective post-emergent herbicide: A post-emergence herbicide used to control broadleaf weeds in crops such as beans, corn, mint, soybeans, rice, and peanuts. All products formerly marketed in the U.S. contain the sodium salt of bentazon as the active ingredient, referred to as sodium bentazon. Also used in selective post-emergent control of broadlelaf weeds and sedges in alfalfa, asparagus, cereals, clover, digitalis, dry peas, flax, garlic, grasses, green lima beans, mint, onions, potatoes, snap beans for seed, sorghum, soybeans and sugarcane. Not currently registered in the U.S. It is reported to be used in most European countries.

상품명

ASAGIO®; BAS 351-H®; BASAGRAN®; BENDIOXIDE®; BENTA®; BLAST®; ENTRY®; LADDOK®; LEADER®; PLEDGE®; STORM®

Safety Profile

Moderately toxic by ingestion and skin contact. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits very toxic fumes of SO, and NOx.

잠재적 노출

A potential danger to those involved in the manufacture, formulation or application of this selective postemergent thiadiazine herbicide.

환경귀착

Soil. Under aerobic conditions, bentazone was reported to degrade to 6- and 8-hydrox ybentazone compounds. In addition, anthranilic acid and isopropylamide were reported as soil hydrolysis products (Otto et al., 1978). Persistence in soil is less than 6 weeks (Hartley and Kidd, 1987). Bentazone is readily adsorbed onto organic carbon and therefore, is not expected to leach to groundwater (Abernathy and Wax, 1973). The dissipation half life of bentazone in field soil is 5 days (Ross et al., 1989).
Plant. Undergoes hydroxylation of the aromatic ring and subsequent conju-gation in plants (Otto et al., 1978; Hartley and Kidd, 1987) forming 6- and 8-hydroxybentazone compounds (Otto et al., 1978). The half-life in and/or on plants is 2–3 days (
Photolytic. Humburg et al. (1989) reported that 30% degradation of bentazone on glass plates occurred when exposed to UV light (λ = 200–400 nm); however, no photoproduct(s) were reported. The natural sunlight and simulated sunlight irradiation of
Chiron et al. (1995) investigated the photodegradation of bentazone (20 μg/L) in distilled water and Ebro River water using an xenon arc irradiation. In distilled water, bentazone completely disappeared after 16 hours of irradiation. Photodegradation appeared to follow pseudo-first-order kinetics with a half-life of about 2.5 hours. The presence of humic substances (4 mg/L) increased the rate of photodegradation and the disappearance of bentazone was achieved in 8 hours. No significant breakdown photoproducts were identified.

신진 대사 경로

14C-Bentazon degrades in soils under conventional tillage and no-tillage (3-18 years) with varying histories of bentazon application. The half-life for bentazon degradation ranges from 4.6 to 49.5 days; half-lives for some no-tillage soils with the longest histories of application are lower than those of conventional tillage soils. Half-lives for soils with no bentazon history are 3-11 times higher than the half- lives of those previously exposed to bentazon. N- Methylbentazon is the most consistently observed metabolite. The other metabolites identified in soils result from hydroxylation on the phenyl ring and the cleavage of the benzothiadiazine ring, yielding 6- and 8-hydroxybentazons and anthranilic acid via 2-amino-N-isopropylbenzamide.

운송 방법

UN2588 Pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1—Poisonous materials, Technical Name Required.

비 호환성

Keep away from flammable materials, heat and flame. Risk of fire and explosion if formulations contain flammable/explosive solvents.

폐기물 처리

In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

벤타존 준비 용품 및 원자재

원자재

준비 용품


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