퍼클로로에틸렌
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퍼클로로에틸렌 속성
- 녹는점
- -22 °C (lit.)
- 끓는 점
- 121 °C (lit.)
- 밀도
- 1.623 g/mL at 25 °C (lit.)
- 증기 밀도
- 5.83 (vs air)
- 증기압
- 13 mm Hg ( 20 °C)
- 굴절률
- n
20/D 1.505(lit.)
- 인화점
- 120-121°C
- 저장 조건
- Store at +2°C to +25°C.
- 용해도
- 물: 25°C에서 용해성0.15g/L
- 물리적 상태
- 액체
- 색상
- APHA: ≤10
- 냄새
- 클로로포름 같은 냄새
- Odor Threshold
- 0.77ppm
- 수용성
- 알코올, 에테르, 클로로포름, 벤젠, 헥산과 섞입니다. 물과 약간 섞임.
- 어는점
- -22.0℃
- 최대 파장(λmax)
- λ: 290 nm Amax: 1.00
λ: 295 nm Amax: 0.30
λ: 300 nm Amax: ≤0.20
λ: 305 nm Amax: 0.10
λ: 350 nm Amax: 0.05
λ: 400 nm Amax: 0.03
- Merck
- 14,9190
- BRN
- 1361721
- Henry's Law Constant
- 4.97 at 1.8 °C, 15.5 at 21.6 °C, 34.2 at 40.0 °C, 47.0 at 50 °C, 68.9 at 60 °C, 117.0 at 70 °C (EPICS-GC, Shimotori and Arnold, 2003)
- 노출 한도
- TLV-TWA 50 ppm (～325 mg/m3) (ACGIH), 100 ppm (MSHA and OSHA); TLV-STEL 200 ppm (ACGIH); carcinogenicity: Animal Limited Evidence.
- Dielectric constant
- 2.5（21℃）
- 안정성
- 안정적인. 강산화제, 알칼리 금속, 알루미늄, 강염기와 호환되지 않습니다.
- LogP
- 2.53 at 20℃
- CAS 데이터베이스
- 127-18-4(CAS DataBase Reference)
- IARC
- 2A (Vol. Sup 7, 63, 106) 2014
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | Xn,N,T,F | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 40-51/53-23/25-11-39/23/24/25-23/24/25 | ||
| 안전지침서 | 23-36/37-61-45-24-16-7 | ||
| 유엔번호(UN No.) | UN 1897 6.1/PG 3 | ||
| WGK 독일 | 3 | ||
| RTECS 번호 | KX3850000 | ||
| 자연 발화 온도 | 260℃ | ||
| TSCA | Yes | ||
| 위험 등급 | 6.1 | ||
| 포장분류 | III | ||
| HS 번호 | 29032300 | ||
| 유해 물질 데이터 | 127-18-4(Hazardous Substances Data) | ||
| 독성 | LD50 orally in mice: 8.85 g/kg (Dybing); LC for mice in air: 5925 ppm (Lazarew) | ||
| IDLA | 150 ppm | ||
| 기존화학 물질 | KE-33294 | ||
| 유해화학물질 필터링 | 97-1-297;06-5-12 | ||
| 중점관리물질 필터링 | 별표1-74 | ||
| 함량 및 규제정보 | 물질구분: 제한물질; 혼합물(제품)함량정보: 테트라클로로에틸렌 및 이를 0.1%이상 함유한 혼합물 |
퍼클로로에틸렌 C화학적 특성, 용도, 생산
개요
Perchloroethylene (Tetrachloroethylene) is a colourless liquid with a slightly ethereal odour. It is marginally soluble in water and soluble in most organic solvents.Perchloroethylene has a limited number of uses and applications. It is used as intermediate, as dry cleaning agent in the industrial and professional sector, as surface cleaning agent in industrial settings, as heat transfer medium in industrial settings, and in film cleaning and copying by professionals. It is also used as a chemical intermediate in the production of fluorinated compounds and in industrial surface cleaning metal degreasing. Occupational exposure to perchloroethylene is possible in the manufacturing facilities or the industrial facilities where it is used as an intermediate.화학적 성질
Tetrachloroethylene is a clear, colorless, nonflammable liquid with a characteristic odor. The odor is noticeable @ 47 ppm, though after a short period it may become inconspicuous, thereby becoming an unreliable warning signal. The Odor Threshold is variously given as 5 ppm to 6.17 (3M).용도
Tetrachloroethylene is used as a solvent, indrycleaning, and in metal degreasing.Tetrachloroethylene is a common industrial solvent that is often found as a contaminant in groundwater. Tetrachloroethylene is also a suspected carcinogen to humans and is difficult to degrade biologically as it has no natural source. This compound is a contaminant of emerging concern (CECs).생산 방법
Tetrachloroethylene (PCE) was first prepared in 1821 and commercial production in the United States began in 1925. Several commercial grades are available that differ in the amount and type of added stabilizers (e.g., amines, phenols, and epoxides).The industrial processes for production of tetrachloroethylene include threetechnical routes:
(1) chlorination of trichloroethylene and followed by dehydrochlorination.
(2) oxychlorination of ethylene.
(3) chlorination andpyrolysis of light hydrocarbon.
In China, the chlorination of trichloroethylene and dehydrochlorination process is mainly used for production of tetrachloroethylene, while the other two processes are widely used in other countries.
Carcinogenicity
Tetrachloroethylene is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.퍼클로로에틸렌 준비 용품 및 원자재
원자재
펜타클로로에탄
염소(기체)
트라이클로로에틸렌
1,2-디클로로에탄
1,1,2,2-TETRACHLOROETHANE-D2
Alkali off
디클로로(2,3-)-1-프로판올
디클로로(1,3-)-2-프로판올
글리세린
준비 용품
퍼클로로에틸렌 공급 업체
글로벌( 779)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 |
sales@tnjchem.com | China | 34563 | 58 |
| BLiT (Hefei)Chemical Co.,Ltd | +86-551-62622640 |
sales@blitchem.com | China | 293 | 58 |
| Qingdao Minzhi Yijie new material Co., LTD | +86-13589435123 +86-13589435123 |
qdmzyj@126.com | China | 240 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8615531157085 |
abby@weibangbio.com | China | 8806 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 |
sales1@chuanghaibio.com | China | 5889 | 58 |
| Hebei Dangtong Import and export Co LTD | +86-86-4001020630 +8619831957301 |
admin@hbdangtong.com | China | 1000 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 |
info@fdachem.com | China | 20267 | 58 |
| Yujiang Chemical (Shandong) Co.,Ltd. | +86-17736087130 +86-18633844644 |
catherine@yjchem.com.cn | China | 992 | 58 |
| Qingdao RENAS Polymer Material Co., Ltd. | +86-0532-86867058 +86-18562606086 |
sales@qdrenas.com | China | 476 | 58 |
| Shanghai Bojing Chemical Co.,Ltd. | +86-86-02137122233 +8613795318958 |
bj1@bj-chem.com | China | 299 | 55 |
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