아지리딘 호모중합체

아지리딘 호모중합체
아지리딘 호모중합체 구조식 이미지
카스 번호:
9002-98-6
한글명:
아지리딘 호모중합체
동의어(한글):
아지리딘호모중합체;아지리딘호모중합체;피이아이-10;피이아이-1000;피이아이-14엠;피이아이-15;피이아이-1500;피이아이-1750;피이아이-250;피이아이-2500;피이아이-275;피이아이-30;피이아이-35;피이아이-45;피이아이-7;피이아이-700;피이아이-1400;폴리에틸렌이민,분지
상품명:
POLYETHYLENEIMINE
동의어(영문):
PEI-10;polyethyleneimine, branched, m.w. 1800;Aziridine,homopolymer;polyethylenimine(10,000);POLYETHYLENEIMINE, BRANCHED;PEI-35;PEI-2500;PEI-1500;polyethylenimine(20,000);Ethyleneimine,homopolymer
CBNumber:
CB9162514
분자식:
C2H5N
포뮬러 무게:
43.07
MOL 파일:
9002-98-6.mol

아지리딘 호모중합체 속성

녹는점
59-60°C
끓는 점
250 °C(lit.)
밀도
1.030 g/mL at 25 °C
증기압
9 mmHg ( 20 °C)
굴절률
n20/D 1.5290
인화점
>230 °F
저장 조건
2-8°C
용해도
DMSO(소량으로 용해)
물리적 상태
액체
색상
옅은 노랑
Specific Gravity
1.045 (20/4℃)
수소이온지수(pH)
pH(50g/l, 25℃) : 10~12
수용성
물에 용해됩니다.
감도
Hygroscopic
InChI
InChI=1S/C2H5N/c1-2-3-1/h3H,1-2H2
InChIKey
NOWKCMXCCJGMRR-UHFFFAOYSA-N
SMILES
C1NC1
LogP
-0.969 (est)
EPA
Aziridine, homopolymer (9002-98-6)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,N,Xi
위험 카페고리 넘버 22-43-51/53-36/38
안전지침서 22-24/25-61-36/37-37-26
유엔번호(UN No.) UN 3082 9 / PGIII
WGK 독일 2
RTECS 번호 TQ7917000
F 고인화성물질 10-34
TSCA Yes
HS 번호 39019090
기존화학 물질 KE-01981
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H411 장기적 영향에 의해 수생생물에 유독함 수생 환경유해성 물질 - 만성 구분 2
예방조치문구:
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
1
2 0

아지리딘 호모중합체 C화학적 특성, 용도, 생산

화학적 성질

Clear viscous liquid

용도

Polyethyleneimine is used as a polyelectrolyte multilayer on charged surfaces to provide a biocompatible coating on surfaces.1Detergents, adhesives, water treatment, printing inks, dyes, cosmetics, and paper industry, adhesion promoter, lamination primer, fixative agent, flocculant, cationic dispersant, stability enhancer, surface activator, chelating agent, scavenger for aldehydes and oxides.

주요 응용

Polyethyleneimine(PEI) can be used as a non-viral synthetic polymer carrier for in vivo delivery of therapeutic nucleic acids. The interaction between the negatively charged nucleic acid and the positively charged polymer backbone leads to the formation of nanoscale complexes. This neutralising complex protects the enclosed nucleic acid from enzymes and maintains its stability until cellular uptake occurs. For example, human serum albumin-coupled PEI shows good pDNA transfection and low toxicity.
PEI can be used to functionalize single-walled nanotubes (SWNTs) to improve their solubility and biocompatibility while maintaining the structural integrity of the original SWNT. Covalently functionalized SWNTs can be used for CO2 uptake and gene delivery.
Branched PEI can also be used to modify the surface properties of adsorbents. PEI-modified aqueous zirconia/PAN nanofibres have a high fluoride adsorption capacity and a wide working pH range, and can therefore be used for groundwater defluoridation.

생산 방법

Polyethylenimine is produced by the homopolymerization of ethylenimine. The reaction is catalyzed by acids, Lewisacids, or haloalkanes. The polymerization is usually carried out at 90 – 110 ℃ in water or in a variety of organic solvents. The average molecular mass of the polyethylenimine prepared as described above is 10 000 – 20 000. Higher molecular mass polymers are prepared by addition of a difunctional alkylating agent, such as chloromethyloxirane or 1,2-dichloroethane. Polyethylenimines with a higher average molecular mass can also be provided by ultrafiltration of polymers with a broad mass distribution. Likewise, polymers of lower molecular mass can be obtained by inclusion of a low molecular mass amine, such as 1,2- ethanediamine, during polymerization. By using these techniques a range of molecular masses from 300 to 10 6 can be obtained. Cross-linking during the polymerization of ethylenimine in organic solvents leads to solid polyethylenimines. Furthermore the polymerization process can be conducted on the surface of organic or inorganic materials, thus fixing the polyethylenimines to a support.

일반 설명

All polyethylene imine polymers are hydrophilic and may contain approx. 30% hydrated water.

상품명

Lupasol, Polymin, Catiofast, Lugalvan (BASF), Epomin (Nippon Shokubai).

생물학적 활성

Polyethylenimine is nondegradable and the molecular weight of PEI affects the cytotoxicity and gene transfer activity. Polyethylenimine acts as a low toxicity and efficient gene vector. 

Structure and conformation

Polyethyleneimine(PEI) exists as both a branched and linear structure. Branched PEI (bPEI) is synthesized via acid-catalyzed polymerization of aziridine, whereas the linear structure (lPEI) is synthesized via ring opening polymerization of 2-ethyl-2-oxazoline followed by hydrolysis.

아지리딘 호모중합체 준비 용품 및 원자재

원자재

준비 용품


아지리딘 호모중합체 공급 업체

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