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| TITANIUM(IV) BROMIDE Basic information |
Product Name: | TITANIUM(IV) BROMIDE | Synonyms: | TiBr4;Titanium bromide;Titanium bromide (TiBr4), (T-4)-;Titaniumbromide(TiBr4),(T-4)-;TITANIUM(IV) BROMIDE, ANHYDROUS, POWDER, 99.99%;TITANIUM(IV) BROMIDE;TITANIUM TETRABROMIDE;Titanium(IV)bromide,min.98% | CAS: | 7789-68-6 | MF: | Br4Ti | MW: | 367.48 | EINECS: | 232-185-0 | Product Categories: | metal halide | Mol File: | 7789-68-6.mol | ![TITANIUM(IV) BROMIDE Structure](CAS/GIF/7789-68-6.gif) |
| TITANIUM(IV) BROMIDE Chemical Properties |
Melting point | 38-40 °C(lit.) | Boiling point | 230 °C(lit.) | density | 3.25 g/mL at 25 °C(lit.) | Fp | 233°C | solubility | reacts with H2O | form | powder | Specific Gravity | 2.6 | color | Orange | Water Solubility | Soluble in absolute alcohol. Decomposes in waterSoluble in chlorocarbons, benzene and alcohol. | Sensitive | Moisture Sensitive | Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents | Merck | 14,9477 | CAS DataBase Reference | 7789-68-6 |
Hazard Codes | C | Risk Statements | 14-34 | Safety Statements | 26-36/37/39-45 | RIDADR | UN 3260 8/PG 2 | WGK Germany | 3 | F | 3-8-10-21 | TSCA | No | HazardClass | 8 | PackingGroup | II | HS Code | 28275900 |
| TITANIUM(IV) BROMIDE Usage And Synthesis |
Chemical Properties | Orange low melting lumps and powder | Uses | Titanium(IV) bromide is used as a Lewis acid catalyst in organic synthesis. It reacts with tetrahydrofurnan and 2-methylpyridine and forms adducts such as TiBr4(THF)2 and TiBr4(2-MePy). It is also used for the formation of titanium silicide thin films on silicon substrates. | Purification Methods | Purify it by distillation. The distillate forms light orange hygroscopic crystals. Store it in the dark under N2 preferably in sealed brown glass ampules. [Olsen & Ryan J Am Chem Soc 54 2215 1932.] |
| TITANIUM(IV) BROMIDE Preparation Products And Raw materials |
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