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(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE

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(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE Suppliers list
Company Name: Richest Group Ltd
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Products Intro: Product Name:(2R,3R)-(-)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene
CAS:71042-55-2
Purity:99%min Package:100g/bottle;500g/bottle;1kg/bottle;10kg/drum;50kg/drum;100kg/drum;468T/drum;
Company Name: Alfa Chemistry
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Products Intro: Product Name:(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene
CAS:71042-55-2
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Company Name: Aromsyn Co., Ltd.
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Products Intro: Product Name:(5R,6R)-5,6-Bis(diphenylphosphino)bicyclo[2.2.1]hept-2-ene
CAS:71042-55-2
Purity:NLT 95% Package:1G;1KG;100KG Remarks:AS105669
Company Name: Aladdin Scientific
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Products Intro: Product Name:(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene
CAS:71042-55-2
Purity:95% Package:$69.9/20mg;$277.9/100mg;Bulk package Remarks:95%
Company Name: Amadis Chemical Company Limited
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Products Intro: Product Name:(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE
CAS:71042-55-2
Purity:0.97 Package:mgs,gs,kgs Remarks:A866501
(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE Basic information
Product Name:(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE
Synonyms:(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE;(2R,3R)-(-)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene,min.95%(R,R)-NORPHOS;(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE (R,R)-NORPHOS;(R,R)-NORPHOS;(-)-NORPHOS;(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO) B IC.(2.2.1)HEPT-5-EN;(2R,3R)-(-)-2,3-Bis(diphenylphosphino)-bicylo[2.2.1]hept-5-ene;(1α,4α)-5β,6α-Bis(diphenylphosphino)bicyclo[2.2.1]hepta-2-ene
CAS:71042-55-2
MF:C31H28P2
MW:462.51
EINECS:
Product Categories:Chiral Phosphine;NORPhos Series;organophosphine ligand
Mol File:71042-55-2.mol
(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE Structure
(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE Chemical Properties
Melting point 120-125 °C
Boiling point 577.0±50.0 °C(Predicted)
alpha -47° (c 1, CHCl3)
storage temp. 2-8°C
form crystal
color white
Sensitive air sensitive
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
F 10-23
TSCA No
HS Code 2931.90.6000
MSDS Information
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ACROS English
SigmaAldrich English
(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE Usage And Synthesis
Reactions
  1. Ligand used in the enantioselective rhodium catalyzed hydrogenation of α–dehydroaminoesters and enamides.
  2. Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
  3. Ligand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines.
  4. Iridium or Rhodium-catalyzed asymmetric Diels-Alder reaction.
Reactions of 71042-55-2
(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE Preparation Products And Raw materials
Tag:(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE(71042-55-2) Related Product Information
(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE 1,5-Bis(diphenylphosphino)pentane 1,2-Bis(diphenylphosphino)ethane R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE 1,2-BIS(PHENYLPHOSPHINO)ETHANE (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE diphenyl(2-phosphinoethyl)phosphine Norbornene 1,2-Bis-(diphenylphosphino)propane (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh (2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE