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Methyl Orange

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CAS:547-58-0
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Related articles

  • The synthesis of methyl orange
  • Methyl orange is an organic substance with the chemical formula of C14H14N3SO3Na, which is often used as an acid-base indicato....
  • Mar 31,2022
Methyl Orange Basic information
Description References
Product Name:Methyl Orange
Synonyms:STOCK METHYL ORANGE SOLUTION;SODIUM 4-(DIMETHYLAMINO)AZOBENZENE-4'-SULFONATE;S NO 176;ORANGE III;ORANGE ACID 52;P-DIMETHYLAMINOAZOBENZENESULFONIC ACID SODIUM SALT;P-[[P-(DIMETHYLAMINO)PHENYL]AZO]BENZENESULFONIC ACID, SODIUM SALT;TROPAEOLIN D
CAS:547-58-0
MF:C14H14N3NaO3S
MW:327.33
EINECS:208-925-3
Product Categories:Intermediates of Dyes and Pigments;Organics;Piperazine derivates;Indicator Solutions;Indicators;Titration;Analytical Chemistry;Indicator (pH);pH Indicators;Chemistry;Azo;bulk reagents
Mol File:547-58-0.mol
Methyl Orange Structure
Methyl Orange Chemical Properties
Melting point 300 °C
density 0.987 g/mL at 25 °C
Fp 37 °C
storage temp. Store at +5°C to +30°C.
solubility 5g/l
Colour Index 13025
form Powder/Solid
pka3.4(at 25℃)
color Yellow-Orange
Specific Gravity0.987
OdorOdorless
PH6.5 (5g/l, H2O, 20℃)
PH Range3.1(Red)-4.4(Orange)
Water Solubility Soluble in ethanol. Partially soluble in hot water. Slightly soluble in cold water and pyrimidine. Insoluble in ether and alcohol.
λmax507nm, 522nm, 464nm
Merck 14,6105
BRN 4732884
Stability:Stable. Incompatible with strong oxidizing agents.
Biological ApplicationsDetecting microorganisms; treating dermatological diseases,vaginal affections; dental materials; wound dressing materials
Major ApplicationLiquid crystals, thin films, sensors, sol-gel matrix, waveguides, host-guest chemistry, display device, corrosion inhibitor, glass coatings, paints, wound dressing materials, pharmaceuticals, dental materials, measuring nucleic acid
CAS DataBase Reference547-58-0
EPA Substance Registry SystemMethyl orange (547-58-0)
Safety Information
Hazard Codes T
Risk Statements 25-10
Safety Statements 45-24/25-16-36/37/39
RIDADR UN 3143 6.1/PG 3
WGK Germany 3
RTECS DB6327000
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29270000
Hazardous Substances Data547-58-0(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 60 mg/kg
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Methyl Orange Usage And Synthesis
DescriptionMethyl orange is an orange, azoic dye. It has a transition range from 3.1 to 4.4. Methyl orange does not have a full spectrum of color change, but has a sharper end point. Methyl orange shows red color in acidic medium (pH < 3.1) and yellow color in basic medium (pH > 4.4). It is used as a pH-indicator in 0.1% aqueous solution for the titration of mineral acids (not organic acids) and strong bases. Methyl orange is also used in dyeing and printing textiles as a dyestuff.
References[1] https://en.wikipedia.org/wiki/Methyl_orange
[2] Mohammed Bassim Alqaragully (2014) International Journal of Advanced Research in Chemical Science, 1, 48-59
Chemical PropertiesOrange-yellow powder. Soluble in hotwater; insoluble in alcohol.
UsesMethyl orange is a pH indicator frequently used in titrations, also used for histological microscopy.
UsesAs indicator in 0.1% aqueous solution. pH: 3.1 red, 4.4 yellow. Employed for titrating most mineral acids, strong bases, estimating alkalinity of waters; useless for organic acids. In dyeing and printing of textiles.
Preparation4-Aminobenzenesulfonic acid diazo, and N,N-dimethylaniline coupling.
DefinitionAn acid–base indicator that is red in solutions below a pH of 3 and yellow above a pH of 4.4. As the transition range is clearly on the acid side, methyl orange is suitable for the titration of an acid with a moderately weak base, such as sodium carbonate.
Definitionmethyl orange: An organic dyeused as an acid–base indicator. Itchanges from red below pH 3.1 toyellow above pH 4.4 (at 25°C) and isused for titrations involving weakbases.
General DescriptionOrange powder.
Air & Water ReactionsAzo dyes can be explosive when suspended in air at specific concentrations. Insoluble in water.
Reactivity ProfileMethyl Orange is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.
Properties and Applicationsorange. The strong sulfuric acid for green light yellow, diluted into red orange. The dye solution to join strong hydrochloric acid for orange red; Add thick sodium hydroxide solution for green light yellow.
Standard Light Fastness Soaping Persperation Fastness Oxygen bleaching Fastness to seawater
Fading Stain Fading Stain Fading Stain
ISO
AATCC
Purification MethodsRecrystallise it twice from hot water, then wash it with a little EtOH followed by diethyl ether. It is an indicator: pH 3.1 (red) and pH 4.4 (yellow). [Beilstein 16 IV 510.]
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