(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene

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Products Intro: Product Name:1,2-Bis((2R,5R)-2,5-diisopropylphospholan-1-yl)benzene
CAS:136705-65-2
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Products Intro: Product Name:(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene
CAS:136705-65-2
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Products Intro: Product Name:1,2-Bis((2R,5R)-2,5-diisopropylphospholan-1-yl)benzene
CAS:136705-65-2
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(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene manufacturers

(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene Basic information
Reaction
Product Name:(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene
Synonyms:(R,R)-I-PR-DUPHOS;(+)-1,2-BIS((2R,5R)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE;(+)-1,2-BIS[(2R,5R)-2,5-DIISOPROPYLPHOSPHOLANO]BENZENE;BisRRdiipropylphospholanobenzene;(+)-1,2-Bis[(2R, 5R)-2,5-diisopropylphospholano]benzene, Kanata purity;(+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene,98+%(R,R)-i-Pr-DUPHOS;1,2-Bis[(2R,5R)-2,5-diisopropyl-1-phospholanyl]benzene, 97+%;(+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene (R,R)-i-Pr-DUPHOS
CAS:136705-65-2
MF:C26H44P2
MW:418.58
EINECS:
Product Categories:organophosphine ligand
Mol File:136705-65-2.mol
(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene Structure
(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene Chemical Properties
Melting point 40°C
alpha +85° (c 1, hexane)
Boiling point 502.0±20.0 °C(Predicted)
refractive index n20/D 1.5701
Fp >110°(230°F)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
color white
optical activity[α]20/D +103°, c = 1 in chloroform
Water Solubility Insoluble in water.
Sensitive Air Sensitive
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
MSDS Information
(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene Usage And Synthesis
Reaction
  1. The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
  2. Forms superior catalysts for asymmetric reductive aminations.
  3. Catalyst used for the asymmetric hydrogenation of enol phosphonates.
  4. A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines. 
Reactions of 136705-65-2
UsesIt is used as ligands like DuPhos and BPE ligands and are highly efficient privileged ligands.
UsesDuPhos and BPE Ligands: Highly Efficient Privileged Ligands
General DescriptionOptical rotation devation ± 13
(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene Preparation Products And Raw materials
Tag:(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene(136705-65-2) Related Product Information
(S,S)-I-PR-DUPHOS-RH (-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.98%(S,S)-i-Pr-DUPHOS-Rh (S,S)-I-PR-DUPHOS,(-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene,98+%(S,S)-i-Pr-DUPHOS (R,R)-I-PR-DUPHOS-RH,(+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene)1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.98%(R,R)-i-Pr-DUPHOS-Rh DI-I-BUTYLPHOSPHINE (+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE (+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene