- X-PHOS
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- $5.00 / 1KG
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2024-08-21
- CAS:564483-18-7
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 10000kg
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Product Name: | X-PHOS | Synonyms: | X-PHOS;2-(DICYCLOHEXYLPHOSPHINO)-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL;2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRIISO-PROPYL-1,1'-BIPHENYL;2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL;2-Dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl, X-PHOS;2-(Dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1'-biphenyl,min.98%X-Phos;2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 98+%;ChemDose(R), X-Phos impregnated tablets, 2-Dicyclohexylphosphino-2μ,4μ,6μ-triisopropylbiphenyl impregnated tablets | CAS: | 564483-18-7 | MF: | C33H49P | MW: | 476.72 | EINECS: | 611-387-6 | Product Categories: | Achiral Phosphine;Aryl Phosphine;Buchwald Ligands Series;Buchwald Ligands&Precatalysts;564483-18-7 | Mol File: | 564483-18-7.mol | ![X-PHOS Structure](CAS/GIF/564483-18-7.gif) |
| X-PHOS Chemical Properties |
Melting point | 187-190 °C(lit.) | Boiling point | 569.8±50.0 °C(Predicted) | storage temp. | Inert atmosphere,Room Temperature | solubility | Benzene (Slightly) | form | Powder | color | white | Sensitive | Air Sensitive | Stability: | Air Sensitive | InChIKey | UGOMMVLRQDMAQQ-UHFFFAOYSA-N | CAS DataBase Reference | 564483-18-7(CAS DataBase Reference) |
| X-PHOS Usage And Synthesis |
Reaction |
- Exceptional ligands for Pd-catalyzed amination and amidation of aryl sulfonates.
- Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling reaction and carbonyl enolate coupling.
- Ligand used for the chemoselective amination of aryl chlorides.
- Ligand used for the Pd-catalyzed borylation of aryl chlorides, for the formation of trifluoroborates.
- Ligand used for the Pd-catalyzed amination of vinyl halides and triflates.
- Ligand used for the Pd-catalyzed three-component synthesis of indoles.
- Ligand used for the Pt-catalyzed regioselective hydrosilylation of functionalized terminal arylalkynes.
- Ligand used for the Pd-catalyzed synthesis of carbazoles.
- Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling of aryl chloride and NHC-boranes.
- Ligand used for the direct arylation of picoline N-oxide.
- Ligand used for the Negishi coupling of 2-heterocyclic organozinc reagents.
- Catalyst for a phosphine-catalyzed Heine reaction.
- Ligand used for the palladium-catalyzed oxidative coupling of indoles and heteroarenes.
- Ligand used for the silver-catalyzed hydrogenation of aldehydes.
- Ligand used for the palladium-catalyzed cyanation of heterycyclic halides.
![Reactions of 564483-18-7_1](/NewsImg/2018-04-26/201842617492634047.jpg)
![Reactions of 564483-18-7_2](/NewsImg/2018-04-26/201842617493334843.jpg)
![Reactions of 564483-18-7_3](/NewsImg/2018-04-26/201842617494022476.jpg)
| Chemical Properties | White crystalline powder | Uses | Exceptional ligands for Pd-catalyzed amination and amidation of aryl sulfonates. XPHOS is used as a regent in the synthesis of novel [1,2,4]triazolo[4,3-a]pyrazine derivatives as potential selective c-met inhibitors with improved pharmacokinetic properties. | Uses | suzuki reaction | General Description | This product has been enhanced for catalytic efficiency. |
| X-PHOS Preparation Products And Raw materials |
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