- (R)-DM-BINAP
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- $1.00 / 1KG
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2019-08-30
- CAS:137219-86-4
- Min. Order: 1KG
- Purity: 95%-99%
- Supply Ability: 100KG
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Product Name: | (R)-DM-BINAP | Synonyms: | (R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL;(R)-(+)-2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL;RACEMIC-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL;RAC-XYLYL-BINAP;(R)-3,5-XYLYL-BINAP;(R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-B;(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98%(R)-3,5-xylyl-BINAP;(R)-(+)-2,2'-bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl | CAS: | 137219-86-4 | MF: | C52H48P2 | MW: | 734.89 | EINECS: | 681-153-6 | Product Categories: | BINAP Series;Chiral Phosphine | Mol File: | 137219-86-4.mol | ![(R)-DM-BINAP Structure](CAS/GIF/137219-86-4.gif) |
| (R)-DM-BINAP Chemical Properties |
Melting point | 203-206°C | Boiling point | 825.3±65.0 °C(Predicted) | alpha | 169 º (c=1 in chloroform) | storage temp. | Inert atmosphere,Room Temperature | Water Solubility | Insoluble in water | form | crystal | color | white to pale yellow | optical activity | [α]20/D +169°, c = 1 in chloroform |
Risk Statements | 36/37/38 | Safety Statements | 26-37 | WGK Germany | 3 | TSCA | No | HS Code | 2931.90.6000 |
| (R)-DM-BINAP Usage And Synthesis |
Reaction |
- Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.
- Ligand used in the enantioselective fluorination of oxindoles.
- Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
- Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
- Asymmetric hydroboration of unsaturated imines.
| Uses | (R)-(+)-XylBINAP is a phosphine-based ligand used in the preparation of various catalysts, such as Pd catalysts for the asymmetric dearomative alkenylation of indoles through a reductive-?Heck reaction. | Uses | Takasago Ligands and Complexes for Asymmetric Reactions |
| (R)-DM-BINAP Preparation Products And Raw materials |
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