Гиббереллиновая кислота химические свойства, назначение, производство
Описание
Gibberellic acid (GA) is a tetracyclic di-terpenoid compound. It is one of the major hormones that can be synthesized in plants and fungi. It has various kinds of physiological effects including stimulating seed germination, inducing mitotic division of the leaves, triggering transitions from meristem to shoot growth, vegetative to flowering, determining sex expression and grain development through crosstalk with many environmental signals such as light, temperature and water. In lab and greenhouse, it can be used to trigger germination of seeds which has previously remained dormant. It can also used to induce the production of larger amount and bigger grapes, boosting the grape industry. In industry, GA can be produced from Solid-state Fermentation (SSF) which can have relatively high yield.
Химические свойства
white powder
Использование
Gibberellic Acid is a a pentacyclic diterpene acid. Gibberellic Acid is a hormone that is found in plants which promotes the growth and elongation of cells. Gibberellic acid acts as a plant growth reg
ulator on account of its physiological and morphological effects in extremely low concentrations. Generally Gibberellic acid affects only the plant parts above the soil surface.
Определение
ChEBI: A C19-gibberellin that is a pentacyclic diterpenoid responsible for promoting growth and elongation of cells in plants.
Биосинтез
The presence of GA in actively growing tissues, i.e., shoot apices, young leaves, and flowers. Gibberellins (GAs; Gibberellic acids) being synthesized via the terpenoid pathway, require 3 enzymes viz., terpene synthase (TPSs), cytochrome P450 monooxygenase (P450s) and 2-oxoglutarate dependent dehydrogenase (2 ODDs), for the biosynthesis of bioactive GA from geranylgeranyl diphosphate in plants. Two terpene synthases, ent-copalyl diphosphate synthase (CPS) and ent-kaurene synthase (KS), located in plastids, are involved in the conversion of GGDP to tetracyclic hydrocarbon intermediate ent-kaurene. ent-Kaurene is then converted to GA12 by 2 P450s. First, ent-Kaurene oxidase (KO), present in the plastid's outer membrane, catalyzes the sequential oxidation of C-19 to produce ent-kaurenoic acid. Second, the kaurenoic acid oxidase (KAO) in the endoplasmic reticulum is converted to GA12. Bioactive GA4 is converted from GA12 through oxidations on C-20 and C-3 by GA 20-oxidase (GA20ox) and GA 3-oxidase (GA3ox)[3].
Общее описание
White powder.
Реакции воздуха и воды
Slightly water soluble .
Профиль реактивности
Gibberellic acid is readily degraded by acids. .
Пожароопасность
Flash point data for Gibberellic acid are not available. Gibberellic acid is probably combustible.
Сельскохозяйственное использование
Plant growth hormone, Plant regulator: Gibberellic acids (Gibberellins) are naturally occurring plant hormones that are used as plant growth
regulators to stimulate both cell division and elongation
that affects leaves and stems. Applications of this hormone also hastens plant maturation and seed germination.
Delayed harvesting of fruits, allowing them to grow larger.
Gibberellic acids are applied to growing field crops, small
fruits, grapes, vines and tree fruit, and ornamentals, shrubs
and vines.
Торговое название
ACTIVOL®; BERELEX®; BRELLIN®;
BOLL-SET®; CEKUGIB®; CROP BOOSTER®;
CYTOPLEX HMS®, DYNOGEN®; FALGRO®;
FLORALTONE® (with 2,3,5-triiodobenzoic acid);
FLORGIB®; FOLI-ZYME®; GIBBEX®; GIBBERELLIN
A 3 ®; GIBBERELLIN X®; GIBBREL®; GIBGRO®;
GIB-SOL®; GIB-TABS®; GIBRESCOL®; GROCEL®;
KALGIBB®; MAXON®; N-LARGE®; NOVAGIB®;
PGR-IV®; PRO-GIBB®; REGULEX®; RELEASE®;
RELAX®; RYZUP®; STIMULATE®; VIGOR®
Профиль безопасности
Mildly toxic by
ingestion. Questionable carcinogen with
experimental tumorigenic data. hlutation
data reported. When heated to
decomposition it emits acrid smoke and
irritating fumes.
Методы очистки
It crystallises from EtOAc, EtOAc/pet ether, MeOH/pet ether or Me2CO/pet ether. [Cross J Chem Soc 3022 1960, Beilstein 18 III/IV 6533.]
использованная литература
[1]
https://en.wikipedia.org/wiki/Gibberellic_acid [2]
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4002599/[3] Gupta, Ramwant, and S K Chakrabarty. “Gibberellic acid in plant: still a mystery unresolved.” Plant signaling & behavior vol. 8,9 (2013): e25504. doi:10.4161/psb.25504
[4]Celik, Ismail et al. “Evalution of toxicity of abcisic acid and gibberellic acid in rats: 50 days drinking water study.” Journal of enzyme inhibition and medicinal chemistry vol. 22,2 (2007): 219-26. doi:10.1080/14756360600988955
Гиббереллиновая кислота препаратная продукция и сырье
сырьё
препарат