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ChemicalBook >> CAS DataBase List >> SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)

SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)

SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) price.
  • $193
  • Product name: SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
  • CAS: 35789-01-6
  • MF: C6H19NSi2Sm
  • MW: 311.76
  • EINECS:
  • MDL Number:MFCD03427097
  • Synonyms:SAMARIUM TRIS(HEXAMETHYLDISILAZIDE);TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]SAMARIUM(III);Tris[N,N-bis(trimethylsilyl)amide]samarium;Tris[N,N-bis(triMethylsilyl)aMide]saMariuM [[(CH3)3Si]2N]3SM;1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt;Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium;samarium tris(hexamethylsilazide);Tris[N,N-bis(trimethylsilyl)amide]samarium [[(CH3)3Si]2N]3Sm FW 631.51 M.p. 93-1060C
1 prices
Selected condition:
Brand
  • Sigma-Aldrich
Package
  • 1g
  • ManufacturerSigma-Aldrich
  • Product number547980
  • Product descriptionTris[N,N-bis(trimethylsilyl)amide]samarium(III) 98%
  • Packaging1g
  • Price$193
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 547980 Tris[N,N-bis(trimethylsilyl)amide]samarium(III) 98% 1g $193 2024-03-01 Buy

Properties

Melting point :93-106 °C(lit.)
Boiling point :83-4°C/1x10-4mmHg
Flash point :36 °F
form :solid

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H228 Flammable solid Flammable solids Category 1
Category 2
Danger
Warning
GHS hazard pictograms P210, P240,P241, P280, P370+P378
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3
Danger
Warning
GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Reactant for synthesis of:
  • Heterobimetallic samarium(III) complexes
  • Binuclear lanthanide complexes

Catalyst for:
  • Coordination polymerization of renewable butyrolactone-based vinyl monomers
  • Intramolecular hydroamination of non-activated alkenes
  • Chiral functionalization of isoxazoles
  • Enantioselective hydroamination / cyclization

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