![](/CAS/GIF/15374-45-5.gif)
1,2-BIS(1-NAPHTHYL)ETHANE synthesis
- Product Name:1,2-BIS(1-NAPHTHYL)ETHANE
- CAS Number:15374-45-5
- Molecular formula:C22H18
- Molecular Weight:282.38
![1-Chloromethyl naphthalene](/CAS/GIF/86-52-2.gif)
86-52-2
337 suppliers
$9.00/10g
![1,2-BIS(1-NAPHTHYL)ETHANE](/CAS/GIF/15374-45-5.gif)
15374-45-5
61 suppliers
$45.00/50mg
Yield:15374-45-5 99%
Reaction Conditions:
with (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate;zinc in tetrahydrofuran at 23 - 25; for 5 h;Irradiation;Inert atmosphere;
Steps:
Homocoupling of Organic Halides; General Procedure
General procedure: THF (1.5 mL), organic halide 3 (1.5 mmol, 1.0 equiv) and Ir(dtbbpy)(ppy)2 PF6 (3.5 mg, 0.0025 equiv) were successively added to a test tube containing Zn dust (73 mg, 1.125 mmol, 0.75 equiv). The reaction mixture was stirred under irradiation with a strip of 400 nm LEDs for 5 h, with water cooling to maintain the reaction temperature around 23-25 °C. For the work-up, H2O (5 mL) was added and the mixture was extracted with hexane (3 × 7 mL). The combined extracts were filtered through Na2SO4 and concentrated under vacuum.The residue was purified by flash chromatography eluting with hexane/EtOAc.
References:
Levin, Vitalij V.;Agababyan, Daniil P.;Struchkova, Marina I.;Dilman, Alexander D. [Synthesis,2018,vol. 50,# 15,art. no. SS-2018-C0067-ST,p. 2930 - 2935]
![1-(Bromomethyl)naphthalene](/CAS/GIF/3163-27-7.gif)
3163-27-7
189 suppliers
$7.00/1g
![1,2-BIS(1-NAPHTHYL)ETHANE](/CAS/GIF/15374-45-5.gif)
15374-45-5
61 suppliers
$45.00/50mg
![1-Methylnaphthalene](/CAS/GIF/90-12-0.gif)
90-12-0
266 suppliers
$17.00/25mL
![1,2-BIS(1-NAPHTHYL)ETHANE](/CAS/GIF/15374-45-5.gif)
15374-45-5
61 suppliers
$45.00/50mg
![Ethanethiol, 2-[(1-naphthalenylmethyl)thio]-](/CAS/20210305/GIF/139277-89-7.gif)
139277-89-7
0 suppliers
inquiry
![1-ETHYLNAPHTHALENE](/CAS/GIF/1127-76-0.gif)
1127-76-0
137 suppliers
$6.00/1g
![1,2-BIS(1-NAPHTHYL)ETHANE](/CAS/GIF/15374-45-5.gif)
15374-45-5
61 suppliers
$45.00/50mg
![1-Chloromethyl naphthalene](/CAS/GIF/86-52-2.gif)
86-52-2
337 suppliers
$9.00/10g
![1,2-BIS(1-NAPHTHYL)ETHANE](/CAS/GIF/15374-45-5.gif)
15374-45-5
61 suppliers
$45.00/50mg
![1-Methylnaphthalene](/CAS/GIF/90-12-0.gif)
90-12-0
266 suppliers
$17.00/25mL