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ChemicalBook CAS DataBase List 2-VINYL-BENZOIC ACID ETHYL ESTER
32082-32-9

2-VINYL-BENZOIC ACID ETHYL ESTER synthesis

8synthesis methods
-

Yield:32082-32-9 99%

Reaction Conditions:

Stage #1: 2,4,6,8-tetramethyl-2,4,6,8-tetravinyl-cyclotetrasiloxanewith tetrabutyl ammonium fluoride;palladium(II) bromide;johnphos in tetrahydrofuran; for 0.166667 h;Inert atmosphere;Hiyama Amino-Acrylate Synthesis;
Stage #2: 2-bromobenzoic acid ethyl ester in tetrahydrofuran at 50; for 8 h;Inert atmosphere;

References:

Heberlig, Graham W.;Wirz, Monica;Wang, Meng;Boddy, Christopher N. [Organic Letters,2014,vol. 16,# 22,p. 5858 - 5861] Location in patent:supporting information

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