![](/CAS/GIF/110-82-7.gif)
Cyclohexane synthesis
- Product Name:Cyclohexane
- CAS Number:110-82-7
- Molecular formula:C6H12
- Molecular Weight:84.16
![Cyclohexanol](/CAS/GIF/108-93-0.gif)
108-93-0
415 suppliers
$11.00/25g
![Cyclohexane](/CAS/GIF/110-82-7.gif)
110-82-7
728 suppliers
$10.00/25g
Yield:110-82-7 99%
Reaction Conditions:
with hydrogen;AIOTfbpy-Pd in 1,2-dichloro-ethane at 150; under 37503.8 Torr; for 24 h;Glovebox;Inert atmosphere;
Steps:
1
General procedure: As shown in Scheme 1, above, in a nitrogen-filled glovebox, AlOTf-bpy-Pd (2.0 mg, 1.2 μmol AlOTf sites), 1,8-cineole (100 μL, 0.6 mmol), and 1.0 mL of 1,2-dichloroethane were transferred into a Parr reactor. The Parr reactor was then sealed under nitrogen, purged with hydrogen several times and charged with hydrogen to 50 bar. After stirring at 100° C. for 24 hours, the pressure was released and the MOF catalyst was removed from the reaction mixture via centrifugation. The supernatant was analyzed by GC-MS to give menthane (a mixture of cis/trans isomers) in >99% yield with 100% of substrate conversion.
References:
US2021/53042,2021,A1 Location in patent:Paragraph 0166; 0168
![Catechol](/CAS/GIF/120-80-9.gif)
120-80-9
495 suppliers
$13.00/25g
![Cyclohexane](/CAS/GIF/110-82-7.gif)
110-82-7
728 suppliers
$10.00/25g
![Hydroquinone](/CAS/GIF/123-31-9.gif)
123-31-9
824 suppliers
$13.00/25g
![Cyclohexane](/CAS/GIF/110-82-7.gif)
110-82-7
728 suppliers
$10.00/25g
![4-Methoxyphenol](/CAS/GIF/150-76-5.gif)
150-76-5
750 suppliers
$5.00/5G
![Cyclohexane](/CAS/GIF/110-82-7.gif)
110-82-7
728 suppliers
$10.00/25g
![Cyclohexene](/CAS/GIF/110-83-8.gif)
110-83-8
290 suppliers
$11.00/25g
![Cyclohexane](/CAS/GIF/110-82-7.gif)
110-82-7
728 suppliers
$10.00/25g