![](/CAS/GIF/150-30-1.gif)
DL-Phenylalanine synthesis
- Product Name:DL-Phenylalanine
- CAS Number:150-30-1
- Molecular formula:C9H11NO2
- Molecular Weight:165.19
![3-Phenylpyruvic acid](/CAS/GIF/156-06-9.gif)
156-06-9
173 suppliers
$45.00/1g
![DL-Phenylalanine](/CAS/GIF/150-30-1.gif)
150-30-1
544 suppliers
$10.00/25G
Yield:150-30-1 62%
Reaction Conditions:
with [Cp*Ir(N-phenyl-2-pyridinecarboxamidate)Cl];ammsnium formate in methanol at 37; for 6 h;chemoselective reaction;
Steps:
General Procedure for Reductive Amination of α-Ketoacids
General procedure: α-Ketoacid (0.2 mmol) and Ir1 (1 mol%) were added to a 1.5-dram vial equipped with amagnetic stir bar in methanol (1 mL). Solid HCOONH4 (2 mmol, 10 equiv.) was added to thevial and the solution was stirred at 37 °C for 6 h. The precipitate was filtered, washed with asmall amount of cold methanol, and dried under vacuum to give the desired α-amino acid.
References:
Nguyen, Dat P.;Sladek, Rudolph N.;Do, Loi H. [Tetrahedron Letters,2020,vol. 61,# 32,art. no. 152196] Location in patent:supporting information
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828-01-3
139 suppliers
$21.00/1g
![DL-Phenylalanine](/CAS/GIF/150-30-1.gif)
150-30-1
544 suppliers
$10.00/25G
![N-(Diphenylmethylene)glycerine tert-butyl ester](/CAS/GIF/81477-94-3.gif)
81477-94-3
261 suppliers
$6.00/1g
![Benzyl bromide](/CAS/GIF/100-39-0.gif)
100-39-0
424 suppliers
$10.00/10g
![DL-Phenylalanine](/CAS/GIF/150-30-1.gif)
150-30-1
544 suppliers
$10.00/25G
![DIETHYL 2-ACETAMIDO-2-BENZYLMALONATE](/CAS/20180702/GIF/3235-26-5.gif)
3235-26-5
2 suppliers
$28.60/50mg
![DL-Phenylalanine](/CAS/GIF/150-30-1.gif)
150-30-1
544 suppliers
$10.00/25G