2-에틸-1-핵산올

2-에틸-1-핵산올
2-에틸-1-핵산올 구조식 이미지
카스 번호:
104-76-7
한글명:
2-에틸-1-핵산올
동의어(한글):
2-에틸헥산올;2-에틸-1-핵산올;2-에틸-1-헥산올;이소옥타놀;옥탄올;옥탄올(OCOH);2-에틸헥산올
상품명:
2-Ethylhexanol
동의어(영문):
2-ETHYL-1-HEXANOL;OCTANOL;2-Ethylhexan-1-ol;OCTYL ALCOHOL;ISOOCTYL ALCOHOL;2EH;ISOOCTANOL;1-hexanol,2-ethyl-;ALCOHOL C8;2-ETHYLHEXYL ALCOHOL
CBNumber:
CB1394458
분자식:
C8H18O
포뮬러 무게:
130.23
MOL 파일:
104-76-7.mol
MSDS 파일:
SDS

2-에틸-1-핵산올 속성

녹는점
−76 °C(lit.)
끓는 점
183-186 °C(lit.)
밀도
0.833 g/mL at 25 °C(lit.)
증기 밀도
4.49 (vs air)
증기압
0.2 mm Hg ( 20 °C)
FEMA
3151 | 2-ETHYL-1-HEXANOL
굴절률
n20/D 1.431(lit.)
인화점
171 °F
저장 조건
Store below +30°C.
용해도
에 용해됨물
산도 계수 (pKa)
15.05±0.10(Predicted)
물리적 상태
액체
색상
투명한
수소이온지수(pH)
7 (1g/l, H2O, 20℃)
냄새
달콤한.
Odor Threshold
0.013ppm
폭발한계
0.88%, 104°F
?? ??
감귤류
수용성
1g/L(20℃)
JECFA Number
267
Merck
14,3808
BRN
1719280
Dielectric constant
3.4(18℃)
안정성
안정적인. 타기 쉬운. 강한 산화제, 강산과 호환되지 않습니다.
InChIKey
YIWUKEYIRIRTPP-UHFFFAOYSA-N
LogP
2.9 at 25℃
CAS 데이터베이스
104-76-7(CAS DataBase Reference)
NIST
1-Hexanol, 2-ethyl-(104-76-7)
EPA
2-Ethylhexanol (104-76-7)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,Xi
위험 카페고리 넘버 37/38-41-36-21-52/53-36/37/38-20
안전지침서 26-36/39-36/37/39-36-61
WGK 독일 2
RTECS 번호 MP0350000
자연 발화 온도 550 °F
TSCA Yes
HS 번호 29051610
HS 번호 29339990
유해 물질 데이터 104-76-7(Hazardous Substances Data)
독성 LD50 orally in Rabbit: 3730 mg/kg LD50 dermal Rat > 3000 mg/kg
기존화학 물질 KE-13766
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H332 흡입하면 유해함 급성 독성 물질 흡입 구분 4 경고 GHS hazard pictograms P261, P271, P304+P340, P312
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
2
2 0

2-에틸-1-핵산올 MSDS


2-Ethyl-1-hexanol

2-에틸-1-핵산올 C화학적 특성, 용도, 생산

용도

2- 에틸 -1- 헥산 올은 디 옥틸 프탈레이트와 같은 가소제의 제조에 사용됩니다. 또한 2- 에틸 헥실 아크릴 레이트, 아크릴 및 메타 크릴 폴리 에스테르의 특성을 변경하는 데 사용되는 아크릴 레이트 모노머를 윤활유 및 디젤 연료 첨가제로 사용합니다 금속의 코팅, 코팅 및 특정 계면 활성제 및 제초제의 제조시 추출 용제로 사용됩니다.

화학적 성질

2-Ethylhexanol is a clear, colorless to pale yellow oily liquid. It has a mild, oily, sweet, slightly floral odor reminiscent of rose and sweet, fatty-floral taste with a fruity note. Soluble in 720 times water, miscible in most organic solvents.

출처

Reported found in papaya, peach, pear, blackberry, strawberry, cabbage, Parmesan and mozzarella cheese, butter, roasted chicken, cognac, sherry, grape wines, tea, avocado, kiwifruit, crab and clam.

용도

2-Ethylhexanol is the most important C8 alcohol and is mainly used as the alcohol component for the manufacture of ester plasticizers for soft poly(vinyl chloride) (PVC). Other minor uses include the manufacturing of 2-ethylhexyl acrylate, as a dispersing agent and wetting agent, as a solvent for gums and resins, as a cosolvent for nitrocellulose, and in ceramics, paper coatings, rubber latex, textiles, and fragrances.

제조 방법

2-ethylhexanol synthesis: Condensation of acetaldehyde into butanol aldehyde, dehydration to obtain crotonaldehyde, hydrogenation to n-butyraldehyde, condensation dehydration to obtain 2-ethyl-2-hexenal, and then hydrogenation to obtain 2-ethylhexanol.

주요 응용

2-Ethyl-1-hexanol is suitable for use in a study to compare its susceptibilities of dynamic heat capacity and dielectric polarization under isothermal conditions. It may be used to study lipase-catalyzed transesterification (alcoholysis) of rapeseed oil and 2-ethyl-1-hexanol in the absence of solvent. 2-Ethyl-1-hexanol may be used in broadband dielectric spectroscopy studies of the polyalcohols-glycerol, xylitol and sorbitol. It may be used in the preparation of porous beads.

정의

ChEBI: 2-Ethylhexanol is a primary alcohol that is hexan-1-ol substituted by an ethyl group at position 2. It has a role as a volatile oil component and a plant metabolite.

일반 설명

2-ethyl hexanol appears as a dark brown liquid with an aromatic odor. Insoluble in water and less dense than water. Flash point between 140 - 175°F. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion, inhalation and skin absorption.

공기와 물의 반응

Insoluble in water.

반응 프로필

2-Ethylhexanol is an alcohol. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides. 2-Ethylhexanol is incompatible with strong oxidizing agents and strong acids.

건강위험

Anesthesia, nausea, headache, dizziness; mildly irritating to skin and eyes.

화재위험

2-Ethylhexanol is combustible.

Safety Profile

Moderately toxic by ingestion, skin contact, intraperitoneal, subcutaneous, and parented routes. An experimental teratogen. Other experimental reproductive effects. A severe eye and moderate skin irritant. Mutation data reported. A dangerous fire hazard when ex posed to heat or flame; can react vigorously with oxidzing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes. See also ALCOHOLS.

Carcinogenicity

Male and female F344 rats were dosed by oral gavage with 0, 50, 150, or 500 mg/kg 2-ethylhexanol (0.005% in aqueous Cremophor EL, a polyoxyl 35 castor oil), 5 days/week for 2 years. There were no differences of biological importance between the vehicle control and a water control group that was included in the study. There was no evidence of treatment-related neoplastic lesions in any of the exposed groups.

2-에틸-1-핵산올 준비 용품 및 원자재

원자재

준비 용품


2-에틸-1-핵산올 공급 업체

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