n-뷰탈알데히드

n-뷰탈알데히드
n-뷰탈알데히드 구조식 이미지
카스 번호:
123-72-8
한글명:
n-뷰탈알데히드
동의어(한글):
부티르알데히드;n-뷰탈알데히드;n-뷰틸알데하이드;n-뷰틸알데히드;부틸알데히드;뷰틸알데하이드;n-뷰티르알데하이드;뷰탄알;뷰탄알데하이드;뷰탈;뷰트알데하이드;뷰티랄;뷰티르 알데하이드;뷰티르알데하이드;뷰티릴알데하이드;뷰틸 알데하이드
상품명:
Butyraldehyde
동의어(영문):
BUTANAL;N-BUTYRALDEHYDE;N-BUTANAL;propanecarbaldehyde;BUTAL;1-Butanal;BUTYL ALDEHYDE;Butyraldehyd;BUTARALDEHYDE;N-BUTYL ALDEHYDE
CBNumber:
CB6852977
분자식:
C4H8O
포뮬러 무게:
72.11
MOL 파일:
123-72-8.mol
MSDS 파일:
SDS

n-뷰탈알데히드 속성

녹는점
-96 °C
끓는 점
75 °C(lit.)
밀도
0.817
증기 밀도
2.5 (vs air)
증기압
90 mm Hg ( 20 °C)
굴절률
n20/D 1.380(lit.)
FEMA
2219 | BUTYRALDEHYDE
인화점
12 °F
저장 조건
2-8°C
용해도
물: 20°C에서 용해성50g/L
물리적 상태
액체
색상
무색의
수소이온지수(pH)
6-7 (71g/l, H2O, 20℃)
냄새
매운 알데히드; 매콤하고 강렬함.
pH 범위
6-7
Odor Threshold
0.00067ppm
폭발한계
1.7-11.1%(V)
?? ??
초콜릿
수용성
7.1g/100mL(25℃)
감도
Air Sensitive
JECFA Number
86
Merck
14,1591
BRN
506061
노출 한도
No exposure limit is set for n-butyraldehyde.
Dielectric constant
13.4(26℃)
안정성
안정적인. 산화제, 강염기, 강환원제, 강산과 호환되지 않습니다. 가연성이 높습니다.
LogP
1.3 at 20℃ and pH4.4-4.7
표면장력
70mN/m at 1g/L and 20℃
CAS 데이터베이스
123-72-8(CAS DataBase Reference)
NIST
Butanal(123-72-8)
EPA
Butyraldehyde (123-72-8)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F
위험 카페고리 넘버 11-R11
안전지침서 9-29-33-S9-S33-S29-16
유엔번호(UN No.) UN 1129 3/PG 2
WGK 독일 1
RTECS 번호 ES2275000
F 고인화성물질 13-23
자연 발화 온도 390 °F
TSCA Yes
HS 번호 2912 19 00
위험 등급 3
포장분류 II
유해 물질 데이터 123-72-8(Hazardous Substances Data)
독성 Single-dose LD50 orally in rats: 5.89 g/kg (Smyth)
기존화학 물질 KE-03746
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H225 고인화성 액체 및 증기 인화성 액체 구분 2 위험 GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P233 용기를 단단히 밀폐하시오. 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 보관하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P337+P313 눈에 대한 자극이 지속되면 의학적인 조치· 조언를 구하시오.
P370+P378 화재 시 불을 끄기 위해 (Section 5. 폭발, 화재시 대처방법의 적절한 소화제)을(를) 사용하시오.
NFPA 704
3
3 0

n-뷰탈알데히드 C화학적 특성, 용도, 생산

개요

Butyraldehyde (butanal, IUPAC) is a water-white liquid with a pungent aldehyde odor. Butyraldehyde is a dangerous fire risk, with a flammable range of 2.5%–12.5% in air. Boiling point is 168°F (75°C), flash point is 10°F (?12°C), and ignition temperature is 446°F (230°C). It is slightly soluble in water, with a specific gravity of 0.8, which is lighter than water. Vapor density is 0.804, which is lighter than air. In addition to flammability, butyraldehyde is corrosive and causes severe eye and skin burns. It may be harmful if inhaled. The four-digit UN identification number is 1129. The NFPA 704 designation is health 3, flammability 3, and reactivity 2. The primary uses of butyraldehyde are in plastics and rubber and as a solvent.

화학적 성질

Butyraldehyde is a highly flammable, colorless liquid with a pungent odor.

출처

Reported found in the essential oils from flowers, fruits, leaves or bark of Monarda fistulosa L., Litsea cubeba, Bulgarian clary sage, cajeput, Eucalyptus cinerea, E. globules, and others, as well as in apple and strawberry aromas. Also reported found in fresh apple, pears, carrots, peas, soybean, butter, milk, black tea, roast chicken, peanuts, loganberry, honey, white wine and hog plums (Spondias mombins L.).

용도

n-Butyraldehyde is used to make rubberaccelerators, synthetic resins, and plasticizers;and as a solvent.

제조 방법

By dry distillation of calcium butyrate and calcium formate.

정의

ChEBI: A member of the class of butanals that consists of propane bearing a formyl substituent at the 1-position. The parent of the class of butanals.

일반 설명

A clear liquid with a pungent odor. Flash point 20°F. Boiling point 75.7°F (Hawley's). Less dense than water and insoluble in water. Vapors heavier than air.

공기와 물의 반응

Highly flammable. Insoluble in water.

반응 프로필

A colorless liquid, Butyraldehyde can react with oxidizing materials. In contact with strong acids or bases Butyraldehyde will undergo an exothermic condensation reaction. The dry aldehyde may undergo some polymerization reaction. Reacts vigorously with chlorosulfonic acid, nitric acid, sulfuric acid (oleum). [Sax, 9th ed., 1996, p. 607].

위험도

Flammable, dangerous fire risk.

건강위험

n-Butyraldehyde is a mild skin and eye irritant.The liquid in 100% pure form producedmoderate irritation on guinea pig skin. Theirritation resulting from 20 mg in 24 hours on rabbit eye was moderate. A higher dosecould produce severe irritation.
Toxicity of n-butyraldehyde is very low.The effect is primarily narcotic. No toxiceffect, however, was observed in mice from 2-hour exposure at a concentration of 44.6 g/m3.At a higher concentration, 174 g/m3 for30 minutes, it exhibited a general anestheticeffect on rats. Subcutaneous administrationof a high dose, >3 g/kg, produced the sameeffect, affecting the kidney and bladder.

화재위험

Behavior in Fire: Vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Fires are difficult to control due to ease of reignition.

화학 반응

Reactivity with Water No reaction; Reactivity with Common Materials: No reactions; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: May occur in the presence of heat, acids or alkalis; Inhibitor of Polymerization: Not pertinent.

Safety Profile

Moderately toxic by ingestion, inhalation, skin contact, intraperitoneal, and subcutaneous routes. Severe skin and eye irritant. Human immunologcal effects by inhalation: delayed hypersensitivity. See also ALDEHYDES. Highly flammable liquid. To fight fire, use foam, CO2, dry chemical. Incompatible with oxidzing materials. Reacts vigorously with chlorosulfonic acid, HNO3, oleum, H2SO4. When heated to decomposition it emits acrid smoke and fumes

Carcinogenicity

Although butyraldehyde interacts with DNA, no experimental studies of its carcinogenic potency were found.

환경귀착

Butanal does not possess high acute toxicity but is a potent irritant of the skin, eyes, and upper respiratory tract. The mechanism of toxicity probably involves direct reaction between the active aldehyde group and cellular components.

운송 방법

UN1129 Butyraldehyde, Hazard Class: 3; Labels: 3—Flammable liquid

비 호환성

May form explosive mixture with air. Butyraldehyde can presumably form explosive peroxides, and may polymerize due to heat or contact with acids or alkalis. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, caustics, ammonia, aliphatic amines; alkanolamines, aromatic amines. May accumulate static electrical charges, and may cause ignition of its vapors. Possible self-reaction in air; undergoes rapid oxidation to

폐기물 처리

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

n-뷰탈알데히드 준비 용품 및 원자재

원자재

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