Hafnium Chloride
- CAS No.
- 13499-05-3
- Chemical Name:
- Hafnium Chloride
- Synonyms
- HfCl4;HAFNIUM TETRACHLORIDE;HAFNIUM CHLORIDE;Hafnium chloride(HfCl4);1.0% Zr);0.05% Zr);Formula HfCl4;JACS-13499-05-3;Hafnium(IV) chL;Tetrachlorohafnium
- CBNumber:
- CB00123336
- Molecular Formula:
- Cl4Hf
- Molecular Weight:
- 320.3
- MDL Number:
- MFCD00011034
- MOL File:
- 13499-05-3.mol
- MSDS File:
- SDS
Melting point | 432 °C (lit.) | ||||||||||||||
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Boiling point | 315.47°C (estimate) | ||||||||||||||
Density | 1.89 g/cm3 | ||||||||||||||
vapor pressure | 1 mm Hg ( 190 °C) | ||||||||||||||
storage temp. | Inert atmosphere,Room Temperature | ||||||||||||||
solubility | Soluble in methanol and acetone. | ||||||||||||||
form | Powder | ||||||||||||||
color | White | ||||||||||||||
Water Solubility | Soluble in water, methanol and acetone. | ||||||||||||||
Hydrolytic Sensitivity | 7: reacts slowly with moisture/water | ||||||||||||||
Sensitive | Moisture Sensitive | ||||||||||||||
Merck | 14,4588 | ||||||||||||||
crystal system | Monoclinic | ||||||||||||||
Space group | P2/c | ||||||||||||||
Lattice constant |
|
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Exposure limits |
ACGIH: TWA 0.5 mg/m3 NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3 |
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InChIKey | PDPJQWYGJJBYLF-UHFFFAOYSA-J | ||||||||||||||
CAS DataBase Reference | 13499-05-3(CAS DataBase Reference) | ||||||||||||||
EWG's Food Scores | 1 | ||||||||||||||
FDA UNII | CNZ9V5JM5H | ||||||||||||||
EPA Substance Registry System | Hafnium chloride (HfCl4), (T-4)- (13499-05-3) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05 |
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Signal word | Danger | |||||||||
Hazard statements | H290-H314 | |||||||||
Precautionary statements | P234-P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
Hazard Codes | C | |||||||||
Risk Statements | 34 | |||||||||
Safety Statements | 26-36/37/39-45 | |||||||||
RIDADR | UN 3260 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
F | 9-21 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | II | |||||||||
HS Code | 28273985 | |||||||||
NFPA 704 |
|
Hafnium Chloride price More Price(24)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 258202 | Hafnium(IV) chloride 98% | 13499-05-3 | 10g | $40.2 | 2024-03-01 | Buy |
Sigma-Aldrich | 258202 | Hafnium(IV) chloride 98% | 13499-05-3 | 50g | $120 | 2024-03-01 | Buy |
Alfa Aesar | 011834 | Hafnium(IV) chloride, 98+% (metals basis excluding Zr), Zr <2.7% | 13499-05-3 | 2.5g | $19.1 | 2023-06-20 | Buy |
Alfa Aesar | 011834 | Hafnium(IV) chloride, 98+% (metals basis excluding Zr), Zr <2.7% | 13499-05-3 | 25g | $62.9 | 2023-06-20 | Buy |
Strem Chemicals | 72-0751 | Hafnium(IV) chloride, sublimed grade (99.9+%-Hf, <1.0% Zr) | 13499-05-3 | 10g | $70 | 2024-03-01 | Buy |
Hafnium Chloride Chemical Properties,Uses,Production
Chemical Properties
Hafnium(IV) chloride is a chemical compound with the formula HfCl4. It is a white, crystalline solid that is primarily used in the production of hafnium metal.
Uses
Hafnium Chloride is an excellent water soluble crystalline Hafnium source for uses compatible with chlorides. Chloride compounds can conduct electricity when fused or dissolved in water. Chloride materials can be decomposed by electrolysis to chlorine gas and the metal.
Safety
When working with hafnium(IV) chloride, appropriate personal protective equipment should be worn to minimize exposure. Regarding environmental impact data, hafnium(IV) chloride does not pose significant risks if handled and disposed of properly.
Synthesis
Hafnium Chloride can be produced by the procedures:
The reaction of carbon tetrachloride and hafnium oxide at above 450 ℃;
HfO2 + 2 CCl4 → HfCl4 + 2 COCl2
Structure and conformation
Solid hafnium chloride is a polymer with octahedral Hf centers. Of the six chloride ligands surrounding each Hf centre, two chloride ligands are terminal and four bridge to another Hf centre. In the gas phase, both ZrCl4 and HfCl4 adopt the monomeric tetrahedral structure seen for TiCl4.
Hafnium Chloride Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Zhuoer Chemical Co., Ltd | 02120970332; +8613524231522 | sales@zhuoerchem.com | China | 2905 | 58 |
WUXI HONOR SHINE CHEMICAL CO.,LTD | +86-0510-83593312 +8619805123561 | sales@honorshinechem.com | China | 60 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-29-81148696 +86-15536356810 | 1022@dideu.com | China | 3878 | 58 |
Hebei Saisier Technology Co., LTD | +86-18400010335 +86-18034520335 | admin@hbsaisier.cn | China | 1003 | 58 |
Hebei Longbang Technology Co., LTD | +86-18032476855 +86-18032476855 | admin@hblongbang.com | China | 939 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21667 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29888 | 58 |
SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2931 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
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View Lastest Price from Hafnium Chloride manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-09-13 | HAFNIUM CHLORIDE
13499-05-3
|
US $5.00 / KG | 1KG | 99% | 20TONS | Hebei Longbang Technology Co., Ltd | ||
2021-08-12 | HAFNIUM CHLORIDE
13499-05-3
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | ||
2019-07-06 | HAFNIUM CHLORIDE
13499-05-3
|
US $1.00 / KG | 1G | 98% | 100KG | Career Henan Chemical Co |
- HAFNIUM CHLORIDE
13499-05-3
- US $5.00 / KG
- 99%
- Hebei Longbang Technology Co., Ltd
- HAFNIUM CHLORIDE
13499-05-3
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
- HAFNIUM CHLORIDE
13499-05-3
- US $1.00 / KG
- 98%
- Career Henan Chemical Co
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