하프늄 클로라이드
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하프늄 클로라이드 속성
- 녹는점
- 432 °C (lit.)
- 끓는 점
- 315.47°C (estimate)
- 밀도
- 1.89 g/cm3
- 증기압
- 1 mm Hg ( 190 °C)
- 저장 조건
- Inert atmosphere,Room Temperature
- 용해도
- 메탄올과 아세톤에 용해됩니다.
- 물리적 상태
- 가루
- 색상
- 하얀색
- 수용성
- 물, 메탄올, 아세톤에 용해됩니다.
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- 감도
- Moisture Sensitive
- Merck
- 14,4588
- crystal system
- Monoclinic
- Space group
- P2/c
- Lattice constant
a/nm b/nm c/nm α/o β/o γ/o V/nm3 0.6327 0.7377 0.62 90 109.05 90 0.2735
- 노출 한도
- ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
- InChIKey
- PDPJQWYGJJBYLF-UHFFFAOYSA-J
- CAS 데이터베이스
- 13499-05-3(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | C | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 34 | ||
| 안전지침서 | 26-36/37/39-45 | ||
| 유엔번호(UN No.) | UN 3260 8/PG 2 | ||
| WGK 독일 | 3 | ||
| F 고인화성물질 | 9-21 | ||
| TSCA | Yes | ||
| 위험 등급 | 8 | ||
| 포장분류 | II | ||
| HS 번호 | 28273985 | ||
| 기존화학 물질 | KE-18187 |
하프늄 클로라이드 C화학적 특성, 용도, 생산
화학적 성질
Hafnium(IV) chloride is the inorganic compound with the formula HfCl4. This colourless solid is the precursor to most hafnium organometallic compounds. It has a variety of highly specialized applications, mainly in materials science and as a catalyst.물리적 성질
White monoclinic crystal; sublimes at 317°C; melts at 432°C at 33 atm (triple point); critical temperature 452.5°C; critical pressure 53.49 atm; critical volume 314 cm3/mol.
용도
Hafnium chloride tetrahydrofuran complex is an efficient catalyst for the Diels-Alder cycloadditions, Ziegler-Natta polymerization of alkenes. It is used as control rods in nuclear reactors and in manufacture of light bulb filaments.제조 방법
Hafnium(IV) chloride can be prepared(i) by chlorination of hafnium dioxide in the presence of carbon:
HfO2 + 2Cl2 + C → HfCl4 + 2CO
It also may be prepared by several other methods, such as
(ii) reaction of carbon tetrachloride with hafnium dioxide above 450°C;
(iii) heating a mixture of hafnium dioxide and carbon above 700°C;
and (iv) reaction of chlorine with hafnium at elevated temperatures.
화학 반응
Hafnium(IV) chloride hydrolyzes, evolving hydrogen chloride:HfCl4 + H2O→ HfOCl2+ 2 HCl
Aged samples thus often are contaminated with oxychlorides, which are also colourless.
THF forms a monomeric 2:1 complex:
HfCl4+ 2 OC4H8→HfCl4(OC4H8)2
하프늄 클로라이드 준비 용품 및 원자재
원자재
준비 용품
하프늄 클로라이드 공급 업체
글로벌( 205)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Zhuoer Chemical Co., Ltd | 02120970332; +8613524231522 |
sales@zhuoerchem.com | China | 2904 | 58 |
| WUXI HONOR SHINE CHEMICAL CO.,LTD | +86-0510-83593312 +8619805123561 |
sales@honorshinechem.com | China | 67 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-29-81148696 +86-15536356810 |
1022@dideu.com | China | 3882 | 58 |
| Hebei Saisier Technology Co., LTD | +86-18400010335 +86-18034520335 |
admin@hbsaisier.cn | China | 1015 | 58 |
| Hebei Longbang Technology Co., LTD | +86-18633929156 +86-18633929156 |
admin@hblongbang.com | China | 941 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 |
sales@capot.com | China | 29791 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21634 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29884 | 58 |
| SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 |
sales@sdzschem.com | China | 2930 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28172 | 58 |
하프늄 클로라이드 관련 검색:
지르코늄 옥시염화물 옥타수화물 산화 하프늄 염화티탄(Ⅳ) 사염화탄소 바나듐 트리염화물 펜타메틸사이클로펜타디에닐하프늄(IV) 트리클로라이드 하프늄 클로라이드 하프늄분 하프늄(IV) 염화테트라히드로푸란 착물 (1:2)
Zirconium tetrachloride
HAFNIUM OXYCHLORIDE
BIS(PENTAMETHYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE
BIS(ISOPROPYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE
HAFNIUM DICHLORIDE OXIDE
CYCLOPENTADIENYLHAFNIUM TRICHLORIDE
BIS(T-BUTYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE
BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE
BIS(ETHYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE