Thianaphthene
- CAS No.
- 95-15-8
- Chemical Name:
- Thianaphthene
- Synonyms
- BENZO[B]THIOPHENE;BENZOTHIOPHENE;BBT;THIONAPHTHENE;BZT;1-BENZOTHIOPHENE;Thiaphthene;ianaphthene;1-Thiaindene;Thianaphtene
- CBNumber:
- CB0683988
- Molecular Formula:
- C8H6S
- Molecular Weight:
- 134.2
- MDL Number:
- MFCD00005864
- MOL File:
- 95-15-8.mol
- MSDS File:
- SDS
| Melting point | 30-33 °C |
|---|---|
| Boiling point | 221-222 °C(lit.) |
| Density | 1.149 g/mL at 25 °C(lit.) |
| refractive index | 1.6332 (estimate) |
| Flash point | >230 °F |
| storage temp. | Store below +30°C. |
| solubility | 0.13g/l |
| form | Crystalline Solid |
| pka | 32.4 |
| Specific Gravity | 1.149 |
| color | White to pink or yellow |
| Water Solubility | insoluble |
| Merck | 14,9303 |
| BRN | 80580 |
| InChIKey | FCEHBMOGCRZNNI-UHFFFAOYSA-N |
| LogP | 3.120 |
| CAS DataBase Reference | 95-15-8(CAS DataBase Reference) |
| FDA UNII | 073790YQ2G |
| NIST Chemistry Reference | Benzo[b]thiophene(95-15-8) |
| EPA Substance Registry System | Benzo[b]thiophene (95-15-8) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H412 | |||||||||
| Precautionary statements | P264-P270-P273-P301+P312-P501 | |||||||||
| Hazard Codes | Xn,Xi,N | |||||||||
| Risk Statements | 22-36/37/38-20/21/22-51/53 | |||||||||
| Safety Statements | 22-24/25-36-26-61 | |||||||||
| RIDADR | UN3077 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 9 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29349990 | |||||||||
| NFPA 704 |
|
Thianaphthene price More Price(46)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 357790 | Thianaphthene 98% | 95-15-8 | 5g | $21.66 | 2024-03-01 | Buy |
| Sigma-Aldrich | 357790 | Thianaphthene 98% | 95-15-8 | 25g | $86.2 | 2024-03-01 | Buy |
| TCI Chemical | B0093 | Benzo[b]thiophene >97.0%(GC) | 95-15-8 | 5g | $19 | 2024-03-01 | Buy |
| TCI Chemical | B0093 | Benzo[b]thiophene >97.0%(GC) | 95-15-8 | 25g | $54 | 2024-03-01 | Buy |
| Alfa Aesar | A12328 | Benzo[b]thiophene, 98+% | 95-15-8 | 5g | $31.65 | 2024-03-01 | Buy |
Thianaphthene Chemical Properties,Uses,Production
Chemical Properties
WHITE TO RED CRYSTALLINE LOW MELTING SOLID
Uses
Thianaphthene may be used in the preparation of 2-thianapthenylphenyllithium, via metalation by n-butyllithium.
Uses
Benzo[b]thiophene is used in the preparation of 2-thianapthenylphenyllithium, via metalation by n-butyllithium. It is used in organic as well as pharmaceutical industry as a component in the synthesis of raloxifene, a breast cancer therapeutic, or hydrodesulfurization reactions.
Uses
Benzo[b]thiophene has application in organic as well as pharmaceutical industry as a component in the synthesis of Raloxifene, a breast cancer therapeutic, or hydrodesulfurization reactions.
Uses
manufacture of pharmaceuticals, thioindigo.
Application
Thianaphthene may be used in the preparation of 2-thianapthenylphenyllithium, via metalation by n-butyllithium.
Reaction of ethyl diazoacetate with thianaphthene has been reported.
Definition
ChEBI: 1-benzothiophene is a benzothiophene and a member of 1-benzothiophenes.
Synthesis Reference(s)
Journal of the American Chemical Society, 69, p. 2008, 1947 DOI: 10.1021/ja01200a053
Tetrahedron, 27, p. 1253, 1971 DOI: 10.1016/S0040-4020(01)90874-9
General Description
Reaction of ethyl diazoacetate with thianaphthene has been reported.
Purification Methods
1-Benzothiophene has the odour of naphthalene. If the IR spectrum is not very good, then suspend it in a faintly alkaline aqueous solution and steam distil it. Extract the distillate with Et2O, dry the extract (CaCl2), filter, evaporate the solvent and fractionate the residue. The distillate sets solid. The sulfoxide has m 142o, the picrate has m 148-149o (yellow crystals from EtOH) and the styphnate has m 136-137o. [Hansch & Lindwall J Org Chem 10, 381 1945, Meyer & Meyer Chem Ber 52B 1249 1919, Weisgerber & Kruber 53 1551 1920, Iddon & Scrowston Adv Heterocycl Chem 11 177 1970, Beilstein 17/2 V 6.]
Thianaphthene Preparation Products And Raw materials
Raw materials
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Preparation Products
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| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8807 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12834 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5889 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20283 | 58 |
| airuikechemical co., ltd. | +86-18353166132 +86-18353166132 | sales02@airuikechemical.com | China | 983 | 58 |
| Hebei Mojin Biotechnology Co.,Ltd | +86-15028179902 | angelia@hbmojin.com | China | 1176 | 58 |
| Hebei Zhuanglai Chemical Trading Co Ltd | +86-16264648883 +86-16264648883 | niki@zlchemi.com | China | 2886 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18751 | 58 |
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View Lastest Price from Thianaphthene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-12-25 | Thianaphthene
95-15-8
|
US $10.00 / kg | 1kg | 99% | 20 ton | Hebei Zhuanglai Chemical Trading Co Ltd | |
 |
2024-12-25 | Thianaphthene
95-15-8
|
US $0.00 / kg | 0.1kg | 99.89% | 10 | Zhejiang Free Trade Zone Violet Trade Co., Ltd. | |
 |
2024-12-24 | thianaphthene
95-15-8
|
US $0.00-0.00 / Kg | 1Kg | 99.9% | 200tons | airuikechemical co., ltd. |
-
- Thianaphthene
95-15-8
- US $10.00 / kg
- 99%
- Hebei Zhuanglai Chemical Trading Co Ltd
-
- Thianaphthene
95-15-8
- US $0.00 / kg
- 99.89%
- Zhejiang Free Trade Zone Violet Trade Co., Ltd.
-
- thianaphthene
95-15-8
- US $0.00-0.00 / Kg
- 99.9%
- airuikechemical co., ltd.
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