3-Phenoxybenzaldehyde
- CAS No.
- 39515-51-0
- Chemical Name:
- 3-Phenoxybenzaldehyde
- Synonyms
- 3-PHENOXYBENZALDEHYDE;META PHENOXY BENZALDEHYE;3-PhenoxybenzaL;AKOS BBS-00003181;Phenoxybenzaldehyde;3-Phenoxy-benzaldehy;5-Phenoxybenzaldehyde;3-phenoxy-benzaldehyd;3-FORMYLDIPHENYL ETHER;M-PHENOXY BENZALDEHYDE
- CBNumber:
- CB1697209
- Molecular Formula:
- C13H10O2
- Molecular Weight:
- 198.22
- MDL Number:
- MFCD00003353
- MOL File:
- 39515-51-0.mol
- MSDS File:
- SDS
| Melting point | 13 °C |
|---|---|
| Boiling point | 169-169.5 °C11 mm Hg(lit.) |
| Density | 1.147 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Chloroform, Dichloromethane (Slightly), Methanol (Slightly) |
| form | Oil |
| color | Colourless to Pale Yellow |
| Sensitive | Air Sensitive |
| BRN | 511662 |
| InChIKey | MRLGCTNJRREZHZ-UHFFFAOYSA-N |
| CAS DataBase Reference | 39515-51-0(CAS DataBase Reference) |
| FDA UNII | 2ZI2173196 |
| EPA Substance Registry System | Benzaldehyde, 3-phenoxy- (39515-51-0) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H410 | |||||||||
| Precautionary statements | P273-P301+P312+P330 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 22-26 | |||||||||
| Safety Statements | 23-24/25-45-38-28 | |||||||||
| RIDADR | UN2810 - class 6.1 - PG 3 - EHS - Toxic, liquids, organic, n.o.s., HI: all | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | CU7560200 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29124900 | |||||||||
| Toxicity | LD ipr-mus: >500 mg/kg JAFCAU26,954,78 | |||||||||
| NFPA 704 |
|
3-Phenoxybenzaldehyde price More Price(19)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 191752 | 3-Phenoxybenzaldehyde 98% | 39515-51-0 | 5g | $40 | 2024-03-01 | Buy |
| Sigma-Aldrich | 191752 | 3-Phenoxybenzaldehyde 98% | 39515-51-0 | 25g | $40.2 | 2024-03-01 | Buy |
| TCI Chemical | P0960 | 3-Phenoxybenzaldehyde >97.0%(GC) | 39515-51-0 | 25g | $84 | 2024-03-01 | Buy |
| TCI Chemical | P0960 | 3-Phenoxybenzaldehyde >97.0%(GC) | 39515-51-0 | 500g | $694 | 2024-03-01 | Buy |
| TRC | P297800 | 3-Phenoxybenzaldehyde | 39515-51-0 | 2.5g | $65 | 2021-12-16 | Buy |
3-Phenoxybenzaldehyde Chemical Properties,Uses,Production
Chemical Properties
clear light yellow to amber liquid, insoluble in water, soluble in alcohol, benzene, toluene and other organic solvents.
Uses
3-phenoxybenzaldehyde is an important intermediate for the synthesis of pyrethroid pesticides phenothrin, cypermethrin, deltamethrin,fenvalerate, fenpropathrin, flucythrinate, cyhalothrin, etc.
Preparation
Synthesis of 3-Phenoxybenzaldehyde: 3-phenoxybenzoic acid is generated by catalytic oxidation of 3-phenoxytoluene, followed by electrolytic reduction to obtain Phenoxybenzyl alcohol , and then selective oxidation with sodium hypochlorite to obtain 3-Phenoxybenzaldehyde.
Production Methods
3-Phenoxybenzaldehyde is prepared by adding, at a relatively low temperature, a mixture of a 3-phenoxybenzyl halide and a 3-phenoxybenzal halide to a mixture of hexamethylenetetramine, acetic acid and water, the amounts of the water and acid bearing certain relationships to the amount of the mixture of halides, then heating the resulting mixture to a specified temperature level and maintaining it at that level for a specified period of time.
https://patents.google.com/patent/US4229380A/en
General Description
Enantioselective autoinduction during asymmetric hydrocyanation of 3-phenoxybenzaldehyde catalyzed by cyclo[(R)-phenylalanyl-(R)-histidyl] has been investigated. It undergoes hydrogenation catalyzed by Au/Pt bimetallic core/shell nanoparticles to yield 3-phenoxyphenyl methanol.
Safety Profile
Moderately toxic by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating vapors.
Degradation
3-Phenoxybenzoic acid(3-PBA) and 3-phenoxybenzaldehyde are the most common intermediates in the degradation pathways of Type Il pyrethroids by bacteria, except the cyfluthrin degradation in Brevibacterium aureum DG-12, the beta-cyfluthrin degradation in Pseudomonas stutzeri S1, and the fenpropathrin degradation in Clostridium sp. ZP3(Chen et al.2013a; Saikia et al.2005;Zhang et al.2011b).
3-Phenoxybenzaldehyde Preparation Products And Raw materials
Raw materials
1of4
Preparation Products
1of3
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8810 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5889 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8617732866630 | bess@weibangbio.com | China | 18152 | 58 |
| Henan Bao Enluo International TradeCo.，LTD | +86-17331933971 +86-17331933971 | deasea125996@gmail.com | China | 2472 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18751 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
| Hangzhou FandaChem Co.,Ltd. | +8615858145714 | FandaChem@Gmail.com | China | 9150 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32957 | 60 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +8618949832763 | info@tnjchem.com | China | 2986 | 55 |
View Lastest Price from 3-Phenoxybenzaldehyde manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-11-26 | 3-Phenoxy-benzaldehyde
39515-51-0
|
US $10.00 / KG | 1KG | 99% | 10 mt | Hebei Weibang Biotechnology Co., Ltd | |
 |
2024-11-19 | 3-Phenoxybenzaldehyde
39515-51-0
|
US $29.00 / g | 98.61% | 10g | TargetMol Chemicals Inc. | ||
 |
2024-10-29 | 3-Phenoxybenzaldehyde
39515-51-0
|
US $0.00-0.00 / KG | 1KG | 99% | 500000kg | Hebei Weibang Biotechnology Co., Ltd |
-
- 3-Phenoxy-benzaldehyde
39515-51-0
- US $10.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
-
- 3-Phenoxybenzaldehyde
39515-51-0
- US $29.00 / g
- 98.61%
- TargetMol Chemicals Inc.
-
- 3-Phenoxybenzaldehyde
39515-51-0
- US $0.00-0.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd