TRIMETHYLSILYL ISOTHIOCYANATE
- CAS No.
- 2290-65-5
- Chemical Name:
- TRIMETHYLSILYL ISOTHIOCYANATE
- Synonyms
- ISOTHIOCYANATOTRIMETHYLSILANE;Trimethylsilyl Isothicyanate;TRIMETHYLSILYL ISOTHIOCYANATE;isothiocyanatotrimethyl-silan;Trimethylsilylisothiocyanate,94%;Silane, isothiocyanatotrimethyl-;Trimethylsilyl isothiocyanate,97%;(TriMethylsilyl)isothiocyanate 99%
- CBNumber:
- CB2460765
- Molecular Formula:
- C4H9NSSi
- Molecular Weight:
- 131.27
- MDL Number:
- MFCD00004797
- MOL File:
- 2290-65-5.mol
Melting point | −32.8 °C(lit.) |
---|---|
Boiling point | 143 °C(lit.) |
Density | 0.931 g/mL at 25 °C(lit.) |
vapor density | >1 (vs air) |
refractive index |
n |
Flash point | 95 °F |
storage temp. | 2-8°C |
form | liquid |
Specific Gravity | 0.931 |
Water Solubility | Reacts with water. |
Sensitive | Moisture Sensitive |
Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
BRN | 1745262 |
InChIKey | XLTUPERVRFLGLJ-UHFFFAOYSA-N |
CAS DataBase Reference | 2290-65-5(CAS DataBase Reference) |
FDA UNII | JK38S9F7MN |
EPA Substance Registry System | Isothiocyanatotrimethylsilane (2290-65-5) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() ![]() GHS02,GHS06,GHS08 |
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Signal word | Danger | |||||||||
Hazard statements | H226-H301+H311+H331-H315-H319-H334-H335 | |||||||||
Precautionary statements | P210-P280-P301+P310-P303+P361+P353-P304+P340+P311-P305+P351+P338 | |||||||||
Hazard Codes | T | |||||||||
Risk Statements | 10-23/24/25-36/37/38-42 | |||||||||
Safety Statements | 23-26-36/37-45 | |||||||||
RIDADR | UN 1992 3/PG 3 | |||||||||
WGK Germany | 3 | |||||||||
F | 10-19-21 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 3 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29319090 | |||||||||
NFPA 704 |
|
TRIMETHYLSILYL ISOTHIOCYANATE price More Price(7)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 230766 | Trimethylsilyl isothiocyanate 99% | 2290-65-5 | 50g | $172.4 | 2024-03-01 | Buy |
Sigma-Aldrich | 230766 | Trimethylsilyl isothiocyanate 99% | 2290-65-5 | 10g | $257 | 2024-03-01 | Buy |
Alfa Aesar | L03277 | Trimethylsilyl isothiocyanate 94% | 2290-65-5 | 5g | $43.65 | 2024-03-01 | Buy |
Alfa Aesar | L03277 | Trimethylsilyl isothiocyanate 94% | 2290-65-5 | 25g | $194 | 2024-03-01 | Buy |
Matrix Scientific | 153248 | Trimethylsilyl isothiocyanate 95% | 2290-65-5 | 10g | $222 | 2021-12-16 | Buy |
TRIMETHYLSILYL ISOTHIOCYANATE Chemical Properties,Uses,Production
Chemical Properties
clear colorless to light yellow liquid
Uses
Trimethylsilyl isothiocyanate was used as derivatizing reagent during the synthesis of amino acid thiohydantoins.
Uses
Trimethylsilyl isothiocyanate is used as derivatizing reagent during the synthesis of amino acid thiohydantoins. It participates in ring opening reaction of N-substituted aziridines and cyclohexene oxide.
General Description
Trimethylsilyl isothiocyanate (TMS-ITC) reacts with fullerene-mixed peroxide C60(O)(OOtBu)4 to yield isothiocyanate derivative C60(NCS)(OH)(OOtBu)4. TMS-ITC undergoes condensation with ethyl 2-benzylamino-5-methyl-3-phenylcyclopent-1-enecarboxylate to yield 1-benzyl-5-methyl-7-phenyl-2-thioxo-1,2,3,5,6,7-hexahydrocyclopentapyrimidin-4-one. It participates in ring opening reaction of N-substituted aziridines and cyclohexene oxide.
Purification Methods
The 1H NMR spectrum should have only one peak; if not purify it by repeated fractionation in an all-glass system using a 50cm (4mm internal diameter) column without packing. [Anderson J Am Chem Soc 69 3049 1947, Fehér & Blümcke Chem Ber 90 1934 1957, Neidleim & Hege Synthesis 51 1975, Beilstein 4 III 1861, 4 IV 4011.]
![18306-29-1](/CAS/GIF/18306-29-1.gif)
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TRIMETHYLSILYL ISOTHIOCYANATE Preparation Products And Raw materials
Raw materials
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Preparation Products
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Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18648 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49392 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | China | 52861 | 58 |
Alfa Chemistry | Info@alfa-chemistry.com | United States | 24072 | 58 | |
Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 | 1026@dideu.com | China | 8673 | 58 |
PT CHEM GROUP LIMITED | peter68@ptchemgroup.com | China | 35426 | 58 | |
GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 50000 | 58 |
Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 57511 | 58 |
Qingdao Dexin Chemical Co., Ltd | +86-15553333686 +86-15553333686 | 15553333686@qq.com | China | 2862 | 58 |
Mainchem Co., Ltd. | +86-0592-6210733 | sale@mainchem.com | China | 32360 | 55 |
View Lastest Price from TRIMETHYLSILYL ISOTHIOCYANATE manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2021-07-02 | (Trimethylsilyl)isothiocyanate 99%
2290-65-5
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd |
-
- (Trimethylsilyl)isothiocyanate 99%
2290-65-5
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
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