TITANIUM(III) FLUORIDE
- CAS No.
- 13470-08-1
- Chemical Name:
- TITANIUM(III) FLUORIDE
- Synonyms
- TiF3;TSCS(13470-08-1);TITANIUM FLUORIDE;TITANIUM TRIFLUORIDE;itanium(III)fluoride;TITANIUM(III) FLUORIDE;titaniumfluoride(tif3);Titanium fluoride(F3Ti);Titanium fluoride (TiF3);Titanium(III)fluoride99%
- CBNumber:
- CB6377711
- Molecular Formula:
- F3Ti
- Molecular Weight:
- 104.86
- MDL Number:
- MFCD00042544
- MOL File:
- 13470-08-1.mol
| Melting point | 1200 °C |
|---|---|
| Boiling point | 1400 °C |
| Density | 3.4 g/mL at 25 °C(lit.) |
| solubility | insoluble in H2O, dilute acid solutions, alkaline solutions |
| form | Crystalline Powder |
| Specific Gravity | 3.4 |
| color | Red to brown |
| Water Solubility | Sparingly soluble. It hydrolyses in water. |
| Sensitive | Air & Moisture Sensitive |
| Exposure limits |
ACGIH: TWA 2.5 mg/m3 NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3 |
| CAS DataBase Reference | 13470-08-1(CAS DataBase Reference) |
| EPA Substance Registry System | Titanium fluoride (TiF3) (13470-08-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 20/21/22-34-32-14 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 3260 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10 | |||||||||
| Hazard Note | Corrosive | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 28261990 | |||||||||
| NFPA 704 |
|
TITANIUM(III) FLUORIDE price More Price(7)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 399817 | Titanium(III) fluoride | 13470-08-1 | 5g | $63.7 | 2024-03-01 | Buy |
| Alfa Aesar | 013079 | Titanium(III) fluoride | 13470-08-1 | 10g | $57.65 | 2024-03-01 | Buy |
| Alfa Aesar | 013079 | Titanium(III) fluoride | 13470-08-1 | 50g | $273 | 2023-06-20 | Buy |
| Strem Chemicals | 93-2224 | Titanium(III) fluoride, min. 98% | 13470-08-1 | 5g | $41 | 2024-03-01 | Buy |
| Strem Chemicals | 93-2224 | Titanium(III) fluoride, min. 98% | 13470-08-1 | 25g | $149 | 2024-03-01 | Buy |
TITANIUM(III) FLUORIDE Chemical Properties,Uses,Production
Chemical Properties
Red to brown crystalline powder
Blue rhombic crystals are stable in air and unusually resistant to acids and bases. Sublimation begins at about 930°C in a less than 0.1 mm vacuum. M.p. >1100°C; d%5 2.98. Insoluble in water and alcohol. Disproportionation to TiF4 and Ti begins at 950°C.
Uses
It is used as a laboratory chemicals & for manufacture of chemicals.
Production Methods
Titanium metal is hydrogenated at 600-700°C. It is then placed in a small nickel boat and inserted into the horizontal nickel tube (closed at one end). The hydride is fluorinated with gaseous HF. The open end of the tube has a cooling jacket and is sealed with picein to a copper cover. Two copper tubes are silver-soldered into the cover and serve as an inlet and outlet for the hydrogen; the inlet tube also contains a concentric silver tube for introducing HF. The output gases pass through an empty polyethylene bottle, a bubble counter filled with paraffin oil and a polyethylene trap to freeze excess HF gas. The closed end of the reaction tube is placed in a tubular furnace. The temperature is measured externally. After thoroughly flushing the apparatus with Hs, fluorination followed with a 1 4 mixture of H2 and HF for four to five hours. The HF flow is first started at a temperature above 200°C. The water temperature in the cooling jacket should be higher than 20°C to prevent condensation of the HF. After completion of the fluorination, the product is left to cool in a stream of hydrogen. The yield is 90%.
TITANIUM(III) FLUORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | China | 52861 | 58 |
| Alfa Chemistry | Info@alfa-chemistry.com | United States | 24072 | 58 | |
| Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 | 1026@dideu.com | China | 9003 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 49999 | 58 |
| Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 57511 | 58 |
| Mainchem Co., Ltd. | +86-0592-6210733 | sale@mainchem.com | China | 32360 | 55 |
| J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |