TITANIUM(III) FLUORIDE

TITANIUM(III) FLUORIDE 구조식 이미지
카스 번호:
13470-08-1
상품명:
TITANIUM(III) FLUORIDE
동의어(영문):
TiF3;TSCS(13470-08-1);TITANIUM FLUORIDE;TITANIUM TRIFLUORIDE;itanium(III)fluoride;TITANIUM(III) FLUORIDE;titaniumfluoride(tif3);Titanium fluoride(F3Ti);Titanium fluoride (TiF3);Titanium(III)fluoride99%
CBNumber:
CB6377711
분자식:
F3Ti
포뮬러 무게:
104.86
MOL 파일:
13470-08-1.mol
MSDS 파일:
SDS

TITANIUM(III) FLUORIDE 속성

녹는점
1200 °C
끓는 점
1400 °C
밀도
3.4 g/mL at 25 °C(lit.)
용해도
insoluble in H2O, dilute acid solutions, alkaline solutions
물리적 상태
결정성 분말
Specific Gravity
3.4
색상
빨간색에서 갈색으로
수용성
거의 용해되지 않음. 물에서 가수분해됩니다.
감도
Air & Moisture Sensitive
Crystal Structure
VF3 type
crystal system
Three sides
Space group
R3c
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.5430.5431.36490901200.3488
노출 한도
ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
CAS 데이터베이스
13470-08-1(CAS DataBase Reference)
EPA
Titanium fluoride (TiF3) (13470-08-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C
위험 카페고리 넘버 20/21/22-34-32-14
안전지침서 26-36/37/39-45
유엔번호(UN No.) UN 3260 8/PG 2
WGK 독일 3
F 고인화성물질 10
위험 참고 사항 Corrosive
TSCA Yes
위험 등급 8
포장분류 II
HS 번호 28261990
기존화학 물질 KE-33928
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P363 다시 사용전 오염된 의류는 세척하시오.
NFPA 704
0
3 2
W

TITANIUM(III) FLUORIDE C화학적 특성, 용도, 생산

화학적 성질

Red to brown crystalline powder
Blue rhombic crystals are stable in air and unusually resistant to acids and bases. Sublimation begins at about 930°C in a less than 0.1 mm vacuum. M.p. >1100°C; d%5 2.98. Insoluble in water and alcohol. Disproportionation to TiF4 and Ti begins at 950°C.

용도

It is used as a laboratory chemicals & for manufacture of chemicals.

생산 방법

Titanium metal is hydrogenated at 600-700°C. It is then placed in a small nickel boat and inserted into the horizontal nickel tube (closed at one end). The hydride is fluorinated with gaseous HF. The open end of the tube has a cooling jacket and is sealed with picein to a copper cover. Two copper tubes are silver-soldered into the cover and serve as an inlet and outlet for the hydrogen; the inlet tube also contains a concentric silver tube for introducing HF. The output gases pass through an empty polyethylene bottle, a bubble counter filled with paraffin oil and a polyethylene trap to freeze excess HF gas. The closed end of the reaction tube is placed in a tubular furnace. The temperature is measured externally. After thoroughly flushing the apparatus with Hs, fluorination followed with a 1 4 mixture of H2 and HF for four to five hours. The HF flow is first started at a temperature above 200°C. The water temperature in the cooling jacket should be higher than 20°C to prevent condensation of the HF. After completion of the fluorination, the product is left to cool in a stream of hydrogen. The yield is 90%. 

TITANIUM(III) FLUORIDE 준비 용품 및 원자재

원자재

준비 용품


TITANIUM(III) FLUORIDE 공급 업체

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