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ALDICARB-OXIME

CAS No.
1646-75-9
Chemical Name:
ALDICARB-OXIME
Synonyms
Temik Oxime;ALDICARB-OXIME;2-methyl-2-(methylthio)-propanal oxime;2-methyl-2-(methylsulfanyl)propanaldoxime;Propanal, 2-methyl-2-(methylthio)-, oxime;Aldicarb-oxime, 10 μg /μL in acetonitrile;2-methyl-2-(methylthio)propionaldehydeoxime;Propionaldehyde, 2-methyl-2-(methylthio)-, oxime.;N-[2-methyl-2-(methylsulfanyl)propylidene]hydro xylamine;TIANFU-CHEM_Propanal,2-methyl-2-(methylthio)-, oxime 1646-75-9
CBNumber:
CB7258255
Molecular Formula:
C5H11NOS
Molecular Weight:
133.21
MDL Number:
MFCD00221593
MOL File:
1646-75-9.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

ALDICARB-OXIME Properties

Melting point 21.1°C
Boiling point 210°C
Density 1.037 (estimate)
refractive index 1.5216 (estimate)
storage temp. 0-6°C
form liquid
FDA UNII 44OY94U09A
EPA Substance Registry System Aldicarb oxime (1646-75-9)

ALDICARB-OXIME price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC T164670 TemikOxime 1646-75-9 10mg $780 2021-12-16 Buy
TRC T164670 TemikOxime 1646-75-9 25mg $1710 2021-12-16 Buy
Product number Packaging Price Buy
T164670 10mg $780 Buy
T164670 25mg $1710 Buy

ALDICARB-OXIME Chemical Properties,Uses,Production

Uses

Temik Oxime is an intermediate in the synthesis of Aldicarb-d3 Sulfoxide (A514667), which is a labeled Aldicarb Sulfoxide (A514665). Aldicarb Sulfoxide is an analog of Aldicarb (A514650) detected in agricultural products as pesticide residue.

Definition

ChEBI: The oxime resulting from the formal condensation of 2-methyl-2-(methylsulfanyl)propanal with hydroxylamine. Addition of the oxime group to methyl isocyanate forms the final step in the synthesis of the systemic insecticide aldicarb.

General Description

Clear colorless,viscous liquid with an unpleasant sulfurous or musty odor.

Air & Water Reactions

Sensitive to heat. Water soluble. May decompose with prolonged exposure to moisture.

Reactivity Profile

ALDICARB-OXIME is incompatible with oxidizers, acids and alkalis [(NTP, 1992]. Several explosions or violent decompositions have occurred during distillation of alkoxides, which may be attributable to the formation of peroxides of various types. This is especially the case in the presence of acid, Chem. Eng. News, 1974, 52(35), 3. A nickel catalyzed aldoxime rearrangement to an amide, went out of control after changing the solvent employed, J. Loss Prev., 1993, 6(2), 69.

Fire Hazard

ALDICARB-OXIME is combustible.

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2-methyl-2-(methylthio)propionaldehydeoxime ALDICARB-OXIME Aldicarb-oxime, 10 μg /μL in acetonitrile Propanal, 2-methyl-2-(methylthio)-, oxime Propionaldehyde, 2-methyl-2-(methylthio)-, oxime. 2-methyl-2-(methylthio)-propanal oxime 2-methyl-2-(methylsulfanyl)propanaldoxime N-[2-methyl-2-(methylsulfanyl)propylidene]hydro xylamine Temik Oxime TIANFU-CHEM_Propanal,2-methyl-2-(methylthio)-, oxime 1646-75-9 1646-75-9