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Mannose Triflate

CAS No.
92051-23-5
Chemical Name:
Mannose Triflate
Synonyms
MANNOSE TRIFLATE;TATM;TATM USP/EP/BP;MANNOSE TRIFLATE F;beta-D-Mannopyranose;Mannose Triflate?New;Mannose triflate≥ 99%(GC);1,3,4,6-Tetra-O-acetyl-2-O-;Mannose Triflate, ultra pure;Mannose Triflate PLUS, ultra pure
CBNumber:
CB7774955
Molecular Formula:
C15H19F3O12S
Molecular Weight:
480.36
MDL Number:
MFCD00012353
MOL File:
92051-23-5.mol
MSDS File:
SDS
Last updated:2024-07-05 11:27:01

Mannose Triflate Properties

Melting point 118-122 °C
alpha [α]D20 -14~-17゜(c=1,CHCl3)
Boiling point 481.6±45.0 °C(Predicted)
Density 1.50±0.1 g/cm3(Predicted)
refractive index -16 ° (C=1, CHCl3)
storage temp. -20°C
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form Solid
color White to Off-White
optical activity [α]22/D -16°, c = 1 in chloroform
BRN 4341413
InChI InChI=1/C15H19F3O12S/c1-6(19)25-5-10-11(26-7(2)20)12(27-8(3)21)13(14(29-10)28-9(4)22)30-31(23,24)15(16,17)18/h10-14H,5H2,1-4H3/t10-,11-,12+,13+,14-/s3
InChIKey OIBDVHSTOUGZTJ-UBBZJQTNNA-N
SMILES [C@H]1(OC(=O)C)[C@H](OC(=O)C)[C@H](O[C@@H](OC(=O)C)[C@H]1OS(=O)(=O)C(F)(F)F)COC(=O)C |&1:0,5,10,12,17,r|
FDA UNII 0KI8FFQ6TT

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H335-H315-H319
Precautionary statements  P261-P280-P271
Hazard Codes  Xi
Safety Statements  24/25
WGK Germany  3
10-21
HS Code  29329990

Mannose Triflate price More Price(38)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich M1568 Mannose triflate For PET imaging, ≥98% (TLC) 92051-23-5 20mg $27.3 2024-03-01 Buy
Sigma-Aldrich Y0001087 Tetra-O-acetyl-mannose triflate European Pharmacopoeia (EP) Reference Standard 92051-23-5 2each $144 2024-03-01 Buy
Sigma-Aldrich 655112 β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate 98% 92051-23-5 100mg $28.4 2024-03-01 Buy
Sigma-Aldrich Y0001087 Tetra-O-acetyl-mannose triflate European Pharmacopoeia (EP) Reference Standard 92051-23-5 2EA $144 2023-06-20 Buy
TCI Chemical T2307 1,3,4,6-Tetra-O-acetyl-2-O-(trifluoromethanesulfonyl)-beta-D-mannopyranose >98.0%(GC) 92051-23-5 100mg $39 2024-03-01 Buy
Product number Packaging Price Buy
M1568 20mg $27.3 Buy
Y0001087 2each $144 Buy
655112 100mg $28.4 Buy
Y0001087 2EA $144 Buy
T2307 100mg $39 Buy

Mannose Triflate Chemical Properties,Uses,Production

Description

Mannose triflate is a glucose analog. Mannose triflate is a well-known precursor for 18F-FDG synthesis for PET applications. 18F-FDG is an imaging technique for cancer.

Physical properties

White to off-white powder or crystal

Uses

1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-beta-D-mannopyranose is a radiolabelled pharmaceutical preparation for diagnostic aims used in positron emission tomography.

Preparation

The tetraacetyl mannose (1.8 g, 5 mmol) was dissolved in anhydrous CH2Cl2(14 mL) containing dry pyridine (0.9 mL, 11 mmol). This solution was cooled to -15°C, and trifluoromethanesulfonic anhydride (triflic anhydride) (0.9 mL, 5.2 mmol) was added dropwise over 25 min under a nitrogen atmosphere with vigorous stirring. The mixture was then allowed to reach room temperature overnight. The reaction mixture was successively washed with ice-cold saturated aqueous NaHCO3(50 mL) and water (50 mL). The organic layer was dried over anhydrous Na2SO4, filtered, and concentrated on a rotary evaporator.2-Tf-O-AcManwas isolated by column chromatography on silica with hexane :EtOAc=1: 1 as the eluant as white solid Mannose triflate(1.4 g, 56percent).

Mannose Triflate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 237)Suppliers
Supplier Tel Email Country ProdList Advantage
Qingdao Yonghefeng Economic and Trade Co., Ltd.
+86-13375559818 +86-13375559818 cfy69@163.com China 195 58
Zibo Hangyu Biotechnology Development Co., Ltd
+86-0533-2185556 +8617865335152 Mandy@hangyubiotech.com China 10978 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 20314 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 16208 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21671 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32760 60
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29897 58
SHANDONG ZHI SHANG CHEMICAL CO.LTD
+86 18953170293 sales@sdzschem.com China 2931 58
Jinan Carbotang Biotech Co.,Ltd.
+8615866703830 figo.gao@foxmail.com China 7353 58
Hebei Jimi Trading Co., Ltd.
+86 319 5273535 bestoneforyou@sina.com CHINA 288 58

View Lastest Price from Mannose Triflate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Mannose Triflate pictures 2024-07-25 Mannose Triflate
92051-23-5
US $0.00 / G 1G 98%min 30kg/month WUHAN FORTUNA CHEMICAL CO., LTD
TATM pictures 2024-05-10 TATM
92051-23-5
US $50.00-500.00 / kg 10kg 0.99 20tons Zibo Hangyu Biotechnology Development Co., Ltd
		TATM pictures 2024-03-29 TATM
92051-23-5
US $6.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
  • TATM pictures
  • TATM
    92051-23-5
  • US $50.00-500.00 / kg
  • 0.99
  • Zibo Hangyu Biotechnology Development Co., Ltd
  • 		TATM pictures
  • TATM
    92051-23-5
  • US $6.00-1.00 / KG
  • 99%
  • Henan Fengda Chemical Co., Ltd

Mannose Triflate Spectrum

MANNOSE TRIFLATE F 1,3,4,6-Tetraacetate 2-(trifluoromethanesulfonate) -D-Mannopyranose tetraacetyltrifluoromethanesulfonyl-beta-D-mannopyranose Mannose triflate, TATM, 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose 1-O,3-O,4-O,6-O-Tetraacetyl-2-O-(trifluoromethylsulfonyl)-β-D-mannopyranose 1-O,3-O,4-O,6-O-Tetraacetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate Mannose triflate 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethylsulfonyl-β-D-mannopyranose β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate,1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose, Mannose triflate, TATM β-D-Maopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate 1,3,4,6-Tetraacetate 2-(trifluoroMethanesulfonate) 1,3,4,6-Tetra-O-acetyl-2-O-trifluoroMethane 1,3,4,6-Tetra-O-acetyl-2-O-[(trifluoromethyl)sulphonyl]-beta-D-mannopyranose TATM, 1,3,4,6-Tetra-O-acetyl-2-O-triflyl-beta-D-mannopyranose b-D-Mannopyranose,1,3,4,6-tetraacetate 2-(trifluoroMethanesulfonate) beta-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoroMethanesulfonate 98% beta-D-Mannopyranose 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl- β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate(TATM) BETA-D-MANNOPYRANOSE 1,3,4,6-TETRAACETATE 2-TRIFLATE BETA-D-MANNOPYRANOSE, 1,3,4,6-TETRAACETATE 2-(TRIFLUOROMETHANE-SULFONATE) BETA-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-ACETATE 2-O-TRIFLUOROMETHANESULFONATE 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUORO-METHANESULFONYL-BETA-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHANSULFONYL-BETA-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULFONYL-B-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULPHONYL-B-D-MANNOPYRANOSE TATM β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate 1,3,4,6-tetra-O-acetyl-2-O-triflat-beta-D-mannopyranose tetra-O-acetyl-2-O-trifluoromethane-sulfonyl-beta 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUORO-*METHANESULFONY 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-b-D-mannopyranose 1,3,4,6-Tetra-O-acetyl-2-O- 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULFONYL-B-D-MANNOPYRANOSE, TATM 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULFONYL-B-D-MANNOPYRANOSE(MANNOSE TRIFLATE) TETRA-O-ACETYL-2-O-TRIFLUOROMETHANE- & BETA-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-AC& Mannose Triflate PLUS, ultra pure Mannose Triflate, ultra pure packing for GE Microlab Mannose Triflate, ultra pure packing for GE TRACERlab MXFDG Mannose Triflate, ultra pure 1,3,4,6-Tetra-O-Acetyl-2-O-(trifluoromethanesulfonyl)-a-D-mannopyranose Mannose triflate≥ 99%(GC) acetic acid [3,4,6-triacetyloxy-5-(trifluoromethylsulfonyloxy)-2-oxanyl]methyl ester TATM,1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-beta-D-mannopyranose [(2R,3R,4S,5S,6S)-3,4,6-triacetyloxy-5-(trifluoromethylsulfonyloxy)oxan-2-yl]methyl acetate Mannose triflate C15H19F3O12S high quality Cas number:92051-23-5 Tetra-O-acetyl-mannose triflate CRS β-D-Mannopyranose, 1,3,4,6-tetraacetate 2-(trifluoromethanesulfonate) TATM USP/EP/BP 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose β-D-Mannopyranose1,3,4,6-tetra-O-acetate2-O-trifluoromethanesulfonate 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate-β-D-Mannopyranose (2S,3S,4S,5R,6R)-6-(Acetoxymethyl)-3-(((trifluoromethyl)sulfonyl)oxy)tetrahydro-2H-pyran-2,4,5-triyl triacetate 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethylsulfonyl-β-D-mannopyranose MANNOSE TRIFLATE 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose 1,3,4,6-tetra-O-acetyl-2-O-triflat-beta-D-mannopyr