Isobornyl methacrylate
- CAS No.
- 7534-94-3
- Chemical Name:
- Isobornyl methacrylate
- Synonyms
- IBOMA;IBXMA;Acryester IBX;exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl methacrylate;Photomer 2012;Ageflex IBOMA;Light Ester IB;Isoice methacrylate;Isobornyl Methacrylat;ISOBOMYL METHACRYLATE
- CBNumber:
- CB9196470
- Molecular Formula:
- C14H22O2
- Molecular Weight:
- 222.33
- MDL Number:
- MFCD00081070
- MOL File:
- 7534-94-3.mol
- MSDS File:
- SDS
| Melting point | -60 °C |
|---|---|
| Boiling point | 127-129 °C15 mm Hg(lit.) |
| Density | 0.983 g/mL at 25 °C(lit.) |
| vapor pressure | 7.5Pa at 20℃ |
| refractive index |
n |
| Flash point | 225 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| form | Liquid |
| Specific Gravity | 0.985 |
| color | Clear colorless to yellow |
| Viscosity | 8.39mm2/s |
| Water Solubility | negligible |
| InChIKey | HHHKSPVBHWRWNA-QOZQQMKHSA-N |
| LogP | 5.09 |
| CAS DataBase Reference | 7534-94-3(CAS DataBase Reference) |
| Indirect Additives used in Food Contact Substances | ISOBORNYL METHACRYLATE |
| FDA 21 CFR | 177.1010 |
| EWG's Food Scores | 3-6 |
| FDA UNII | 33GSY5DKCQ |
| EPA Substance Registry System | Isobornyl methacrylate (7534-94-3) |
Isobornyl methacrylate price More Price(22)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 392111 | Isobornyl methacrylate technical grade | 7534-94-3 | 100ml | $58.8 | 2024-03-01 | Buy |
| Sigma-Aldrich | 392111 | Isobornyl methacrylate technical grade | 7534-94-3 | 1l | $248 | 2024-03-01 | Buy |
| TCI Chemical | I0617 | Isobornyl Methacrylate (stabilized with MEHQ) >85.0%(GC) | 7534-94-3 | 25g | $31 | 2024-03-01 | Buy |
| TCI Chemical | I0617 | Isobornyl Methacrylate (stabilized with MEHQ) >85.0%(GC) | 7534-94-3 | 500g | $128 | 2024-03-01 | Buy |
| scipoly | M-118 | Isobornyl methacrylate | 7534-94-3 | 200g | $45 | 2024-07-03 | Buy |
Isobornyl methacrylate Chemical Properties,Uses,Production
Description
Isobornyl methacrylate (IBOMA) is an acrylate monomer with a bridging ring structure. It can be used in polymerisation reactions to make other coatings or plastic products. Advantages of IBOMA and its polymers include: high viscosity, good compatibility, low volatility, low toxicity, UV resistance, water resistance, chemical resistance, and low adverse biological effects.
Chemical Properties
CLEAR COLORLESS TO YELLOW LIQUID
Characteristics
Isobornyl methacrylate is a colorless transparent liquid. It is a monomer that unifies hardness and flexibility. Due to its molecular structure, its polymer has excellent high gloss, sharp image, scratch resistance, medium resistance and weather resistance, and Its hygroscopicity is significantly lower than that of MMA (methyl methacrylate). In addition, IBOMA-added acrylic resin has good compatibility with polyester, alkyd and many volatile paint film-forming substances.
Uses
Isobornyl methacrylate is a versatile hydrophobic monomer with a good combination of hardness and flexibility that can improve the chemical and water resistance of polymer systems.
Application
Suitable for manufacturing acrylic resins with high glass transition temperatures (Tg).
Used as a thickening agent, base material, reactive diluent, and curing agent in printing ink formulations, solvent-based high-solid content transparent coatings, and curing coatings.
Suitable for producing decorative protective coatings for PET, PE, and PP soft plastic films, as well as engineering plastic components such as PE, PP, and PC.
Used as a plasticizer in the plastics industry.
Used as a viscosity improver in dental resin.
Preparation
Isobornyl methacrylate was synthesized by direct esterification of camphene and methacrylic acid.
General Description
Isobornyl methacrylate is a reactive solvent with low vapor pressure. It facilitates the free radical polymerization by forming a polymer with high glass transition temperature (Tg).
Flammability and Explosibility
Not classified
Synthesis
Isobornyl methacrylate is obtained by reacting (1S,2S,4S)-(+)-isoborneol and 4-methoxyphenol.Dissolve5g (1S,2S,4S)-(+)-isoborneol in 15 mL toluene. Add 4 mg (0.032 mmol) 4-methoxyphenol to the solution. After the addition of 0.4 g (3.24 mmol)4-dimethylamino pyridine, add a solution of 10 g (64.8 mmol) methacrylic anhydride (MAA) in 10 mL toluene dropwise to the mixture. Heat the reaction mixture to 80 °C. Stir the reaction mixture for 16 hours. After cooling down to room temperature, wash the mixture with 50 mL 1M sodium bicarbonate solution four times. Wash the organic phase with 50 mL brine two times. Separate the organic phase. Remove the toluene by rotary evaporation followed by a fractional distillation under reduced pressure.
1H NMR (CDCl3, 300 MHz): δ(ppm) = 6.06 (dq, 1H, 1); 5.51 (dq, 1H, 2); 4.71 (m ,1H, 4); 1.93 (dd, 3H, 3); 1.87-1.5 (m, 5H, 6,7,8); 1.23-1.04 (m, 2H, 5); 1.012 (s, 3H, 9);0.86 (s, 3H, 10); 0.85 (s, 3H, 11). IR (film): ν(cm-1) = 2954 (CH2), 2879 (CH2), 1715 (C=O) 1454 (CH2), 1157 and 1053 (C=O).
Fig The synthetic method of Isobornyl methacrylate
Isobornyl methacrylate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Gansu Jinyuantai New Material Co., Ltd. | +86-025-86618065 +86-13914714331 | sales@jinyuantaichem.com | China | 73 | 58 |
| Anhui Royal Chemical Co., Ltd. | +86-25-86655873 +8613962173137 | marketing@royal-chem.com | China | 193 | 55 |
| Yancheng Green Chemicals Co.,Ltd | +undefined-86-25-86655873 | info@royal-chem.com | China | 114 | 58 |
| Hubei Ipure Biology Co., Ltd | +8613367258412 | ada@ipurechemical.com | China | 10319 | 58 |
| Qingdao RENAS Polymer Material Co., Ltd. | +86-0532-86867058 +86-18562606086 | sales@qdrenas.com | China | 476 | 58 |
| Henan Alfa Chemical Co., Ltd | +86-18339805032; +8618339805032 | alfa4@alfachem.cn | China | 13227 | 58 |
| Qingdao Zhongke Huatai Industrail Co., Ltd. | +86-532-86898076 +86-15153292017 | zkhtchem@163.com | China | 25 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8812 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-29-81148696 +86-15536356810 | 1022@dideu.com | China | 3882 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12840 | 58 |
Related articles
- Synthesis and Application of Isobornyl methacrylate
- Isbornyl methacrylate is the intermediate of Mitiglinide Calcium.
- Oct 19，2022
View Lastest Price from Isobornyl methacrylate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-11-22 | Isobornyl methacrylate
7534-94-3
|
US $99.00-35.00 / kg | 1kg | 99% | 20ton | Hebei Zhuanglai Chemical Trading Co.,Ltd | |
 |
2024-11-22 | Isobornyl methacrylate
7534-94-3
|
US $0.00 / KG | 1KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | |
 |
2024-11-21 | Isobornyl methacrylate
7534-94-3
|
US $0.00 / Kg/Drum | 1KG | 99% | 1000mt | Jinan Finer Chemical Co., Ltd |
-
- Isobornyl methacrylate
7534-94-3
- US $99.00-35.00 / kg
- 99%
- Hebei Zhuanglai Chemical Trading Co.,Ltd
-
- Isobornyl methacrylate
7534-94-3
- US $0.00 / KG
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
-
- Isobornyl methacrylate
7534-94-3
- US $0.00 / Kg/Drum
- 99%
- Jinan Finer Chemical Co., Ltd
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