cyclamen aldehyde
- CAS No.
- 103-95-7
- Chemical Name:
- cyclamen aldehyde
- Synonyms
- 3-(4-Isopropylphenyl)-2-methylpropanal;Cyclamal;2-METHYL-3-(P-ISOPROPYLPHENYL)PROPIONALDEHYDE;3-p-cumenyl-2-methylpropionaldehyde;3-(4-ISOPROPYLPHENYL)ISOBUTYRALDEHYDE;3-(4-ISOPROPYLPHENYL)-2-METHYLPROPIONALDEHYDE;(R,S)-p-Isopropyl-α-methylhydro-cinnamaldehyde;3-p-;FEMA 2743;aldehydeb
- CBNumber:
- CB9246702
- Molecular Formula:
- C13H18O
- Molecular Weight:
- 190.28
- MDL Number:
- MFCD00024160
- MOL File:
- 103-95-7.mol
| Boiling point | 270 °C(lit.) |
|---|---|
| Density | 0.95 g/mL at 25 °C(lit.) |
| vapor pressure | 0.3Pa at 20℃ |
| FEMA | 2743 | 2-METHYL-3-(P-ISOPROPYLPHENYL)PROPIONALDEHYDE |
| refractive index |
n |
| Flash point | 228 °F |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Chloroform (Slightly), Ethyl Acetate, Methanol (Slightly) |
| form | Oil |
| color | Colourless liquid. |
| Odor | Powerful floral-green with a characteristic cucumber-melon note used in floral types. |
| Viscosity | 7.1mm2/s |
| Odor Type | floral |
| Water Solubility | 66mg/L at 20℃ |
| JECFA Number | 1465 |
| Stability | Hygroscopic |
| LogP | 3.4 at 35℃ |
| CAS DataBase Reference | 103-95-7(CAS DataBase Reference) |
| Substances Added to Food (formerly EAFUS) | 2-METHYL-3-(P-ISOPROPYLPHENYL) PROPIONALDEHYDE |
| EWG's Food Scores | 1-2 |
| FDA UNII | 4U37UX0E1E |
| EPA Substance Registry System | Benzenepropanal, .alpha.-methyl-4-(1-methylethyl)- (103-95-7) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H317-H412 | |||||||||
| Precautionary statements | P261-P264-P272-P273-P280-P302+P352 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | MW4900000 | |||||||||
| HS Code | 29122990 | |||||||||
| Toxicity | The acute oral LD50 value in rats was reported as 3*81 g/kg (Jenner, Hagan, Taylor, Cook & Fitzhugh, 1964). | |||||||||
| NFPA 704 |
|
cyclamen aldehyde price More Price(16)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | W274305 | 2-Methyl-3-(p-isopropylphenyl)propionaldehyde ≥95%, FCC, FG | 103-95-7 | sample-k | $54.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | W274305 | 2-Methyl-3-(p-isopropylphenyl)propionaldehyde ≥95%, FCC, FG | 103-95-7 | 1kg | $139 | 2024-03-01 | Buy |
| Sigma-Aldrich | W274305 | 2-Methyl-3-(p-isopropylphenyl)propionaldehyde ≥95%, FCC, FG | 103-95-7 | 5kg | $511 | 2024-03-01 | Buy |
| Sigma-Aldrich | S405361 | 3-(4-ISOPROPYLPHENYL)-2-METHYLPROPIONALDEHYDE Aldrich | 103-95-7 | 1g | $179 | 2024-03-01 | Buy |
| TCI Chemical | I0377 | 3-(4-Isopropylphenyl)isobutyraldehyde >92.0%(GC) | 103-95-7 | 25mL | $78 | 2024-03-01 | Buy |
cyclamen aldehyde Chemical Properties,Uses,Production
Description
2-Methyl-3-(p-isopropylphenyl) propionaldehyde has a strong, flowery odor. May be prepared by condensation of cuminic aldehyde and propionaldehyde followed by hydrogenation in the presence of a catalyst.
Chemical Properties
The commercially available racemate is a colorless to yellowish liquid with an intense floral odor reminiscent of Cyclamen europaeum (cyclamen, sowbread).
Production. Two main processes are used for the industrial synthesis of cyclamen aldehyde:
1) Alkaline condensation of 4-isopropylbenzaldehyde and propanal results, via the aldol, in the formation of 2-methyl-3-(4-isopropylphenyl)-2-propenal. The unsaturated aldehyde is hydrogenated selectively to the saturated aldehyde in the presence of potassium acetate and a suitable catalyst, such as palladium–alumina:
2) Friedel–Crafts reaction of isopropylbenzene and 2-methylpropenal diacetate (methacrolein diacetate) in the presence of titanium tetrachloride/boron trifluoride etherate gives cyclamen aldehyde enolacetate, which is hydrolyzed to aldehyde:
Uses. Cyclamen aldehyde is an important component for obtaining special blossomnotes in perfume compositions, particularly the cyclamen type. Because of its fresh, floral aspect, it is also used as the top note in many other blossomfragrances.
Chemical Properties
2-Methyl-3-(p-isopropylphenyl)-propionaldehyde has a strong, flowery odor
Occurrence
Reported found in nutmeg and starfruit.
Uses
Cyclamal, is an ingredient in perfume. It can also be used in the synthesis of Cyclamen Alcohol (C987655).
Uses
Cyclamen Aldehyde is a very powerful, floral, green note used in many perfumery applications to blend into fresh, floral, green or ozonic/marine accords. It is an ingredient with growing use and importance in helping to build replacement accords for materials disappearing from the Perfumers’ palette. Cyclamen has good overall stability except in extremes of pH. It has good tenacity and substantivity and represents very good value for money in new creations.In addition to its use in numerous perfume compositions, cyclamen aldehyde is an intermediate for the preparation of fungicides and fungistatic substances.
Preparation
By condensation of cuminic aldehyde and propionaldehyde followed by hydrogenation in the presence of a catalyst
Definition
ChEBI: Xi-3-(4-Isopropylphenyl)-2-methylpropanal is a monoterpenoid.
Safety Profile
Moderately toxic by ingestion. A human skin irritant. See also ALDEHYDES. When heated to decomposition it emits acrid smoke and irritating fumes.
Synthesis
Cyclamen aldehyde is synthesized from Cuminaldehyde plus Ropionaldehyde by condensation followed by selective hydrogenation and finally dehydrogenation of the Cyclamen alcohol to aldehyde.
cyclamen aldehyde Preparation Products And Raw materials
Raw materials
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Preparation Products
cyclamen aldehyde Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12840 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5893 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8617732866630 | bess@weibangbio.com | China | 18154 | 58 |
| Hebei Kingfiner Technology Development Co.Ltd | +86-15532196582 +86-15373005021 | lisa@kingfinertech.com | China | 3010 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
| SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2930 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39894 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49374 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29811 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5857 | 58 |
View Lastest Price from cyclamen aldehyde manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-11-05 | cyclamen aldehyde
103-95-7
|
US $0.00-0.00 / KG | 1KG | 99% | 500000kg | Hebei Weibang Biotechnology Co., Ltd | |
 |
2024-10-11 | cyclamen aldehyde
103-95-7
|
US $5.00-2.00 / KG | 1KG | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD | |
 |
2024-06-18 | cyclamen aldehyde
103-95-7
|
US $0.00-0.00 / kg | 1kg | 0.99 | 50000kg | Hebei Kingfiner Technology Development Co.Ltd |
-
- cyclamen aldehyde
103-95-7
- US $0.00-0.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
-
- cyclamen aldehyde
103-95-7
- US $5.00-2.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD
-
- cyclamen aldehyde
103-95-7
- US $0.00-0.00 / kg
- 0.99
- Hebei Kingfiner Technology Development Co.Ltd
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