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Boc-Glycine hydrazide

CAS No.
6926-09-6
Chemical Name:
Boc-Glycine hydrazide
Synonyms
BUTTPARK 77\04-08;BOC-GLYCINE HYDRAZIDE;Boc-Glycinehydrazide8%;Boc-Glycinehydrazide,98%;Butoxycarbonylglycine hydrazide;Boc-Glycine hydrazide USP/EP/BP;N-TERT-BUTOXYCARBONYLGLYCYLHYDRAZIDE;tert-Butyl (2-hydrazinyl-2-oxoethyl);2-Aminoacetohydrazide, 2-BOC protected;tert-butyl (2-hydrazino-2-oxoethyl)carbamate
CBNumber:
CB9323340
Molecular Formula:
C7H15N3O3
Molecular Weight:
189.21
MDL Number:
MFCD01570558
MOL File:
6926-09-6.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

Boc-Glycine hydrazide Properties

Melting point 111-115
Boiling point 386.5±25.0 °C(Predicted)
Density 1.139±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form solid
pka 11.40±0.46(Predicted)
color Beige

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P271-P260-P280
Hazard Codes  Xi,Xn
Risk Statements  22
HazardClass  IRRITANT
HS Code  2928009090

Boc-Glycine hydrazide price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC B809885 tert-ButylN-(2-Hydrazinyl-2-oxoethyl)carbamate 6926-09-6 50mg $45 2021-12-16 Buy
AK Scientific E007 Boc-Glycinehydrazide 6926-09-6 1g $47 2021-12-16 Buy
Biosynth Carbosynth FB38781 Boc-glycine hydrazide 6926-09-6 2g $60 2021-12-16 Buy
Apolloscientific OR2444 2-Aminoacetohydrazide,2-BOCprotected 6926-09-6 1g $83 2021-12-16 Buy
SynQuest Laboratories 4158-1-X1 N-tert-butoxycarbonylglycylhydrazide 6926-09-6 1g $92 2021-12-16 Buy
Product number Packaging Price Buy
B809885 50mg $45 Buy
E007 1g $47 Buy
FB38781 2g $60 Buy
OR2444 1g $83 Buy
4158-1-X1 1g $92 Buy

Boc-Glycine hydrazide Chemical Properties,Uses,Production

Uses

Boc-Glycine hydrazide is used as organic synthesis intermediate and pharmaceutical intermediate, mainly used in laboratory research and development process and chemical production process.

Synthesis

Synthesis_6926-09-6
N-Protected Hydrazides 2a-l; General Procedure The protected amino acid 1 (2 equiv) and EDAC (2 equiv) were dissolved in the minimum amount of CH2Cl2 at 0 ??C. The mixture was stirred at 0 ??C for 2 h. PhthNNH2 (1 equiv) was added and the mixture was stirred at 0 ??C for 1 h and then at r.t. overnight. Distillation of the solvent under reduced pressure gave a product which was dissolved in EtOAc and washed successively with 1 M KHSO4, sat. aq NaHCO3, and brine. The organic layer was then dried (Na2SO4), filtered, and concentrated in vacuo. The residue was precipitated with Et2O to yield compound 2. If necessary, the residue was purified by column chromatography (silica gel, hexane- EtOAc, 3:7 to 7:3). Compounds 4a-l; General Procedure Aminomethylated polystyrene resin (3 equiv; 1.1 mmol/g, 100-200 mesh) was conditioned for 10 min at r.t. in CH2Cl2. Then 2 (1 equiv) was added, and the mixture was slowly stirred for 24 h at r.t. The mixture was filtered and the solvent was evaporated in vacuo to give product 4. Compound 4h, yield 89%.

Boc-Glycine hydrazide Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 113)Suppliers
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15865262812 info@lihengpharm.com CHINA 938 58
BOC-GLYCINE HYDRAZIDE BUTTPARK 77\04-08 N-TERT-BUTOXYCARBONYLGLYCYLHYDRAZIDE Butoxycarbonylglycine hydrazide 2-Aminoacetohydrazide, 2-BOC protected tert-Butyl (2-hydrazino-2-oxoethyl)carbamate, 2-[(tert-Butoxycarbonyl)amino]acetohydrazide HydrazinocarbonylMethyl-carbaMic acid tert-butyl ester, 95%+ tert-butyl (2-hydrazino-2-oxoethyl)carbamate tert-butyl N-(2-hydrazino-2-oxo-ethyl)carbamate tert-butyl N-(2-hydrazinyl-2-oxoethyl)carbamate tert-butyl N-(2-hydrazinyl-2-oxo-ethyl)carbamate tert-Butyl (2-hydrazinyl-2-oxoethyl) N-(2-hydrazino-2-keto-ethyl)carbamic acid tert-butyl ester N-(2-hydrazino-2-oxoethyl)carbamic acid tert-butyl ester Boc-Glycinehydrazide,98% Hydrazinocarbonylmethyl-carbamic acid tert-butyl ester tert-butyl N-[(hydrazinecarbonyl)methyl]carbamate Boc-Glycinehydrazide8% Glycine, N-[(1,1-dimethylethoxy)carbonyl]-, hydrazide ert-butylN-(2-hydrazinyl-2-oxoethyl)carbamate Boc-Glycine hydrazide USP/EP/BP 6926-09-6 926-09-6 6926/9/6