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n-Butyl vinyl ether

n-Butyl vinyl ether Structure
CAS No.
111-34-2
Chemical Name:
n-Butyl vinyl ether
Synonyms
BUTYL VINYL ETHER;VINYL BUTYL ETHER;1-(ETHENYLOXY)BUTANE;Polyvinox;butoxy-ethene;(BUTYLOXY)ETHYLENE;Bve;NSC 8264;ai3-24225;agrisynthbve
CBNumber:
CB0286024
Molecular Formula:
C6H12O
Molecular Weight:
100.16
MOL File:
111-34-2.mol
MSDS File:
SDS
Modify Date:
2024/8/21 22:41:43

n-Butyl vinyl ether Properties

Melting point −92 °C(lit.)
Boiling point 94 °C(lit.)
Density 0.774 g/mL at 25 °C(lit.)
vapor density 3.5 (vs air)
vapor pressure 42 mm Hg ( 20 °C)
refractive index n20/D 1.400(lit.)
Flash point 15 °F
storage temp. 2-8°C
solubility 3g/l
form Liquid
color Clear
explosive limit 1.2-8.6%(V)
Water Solubility 3 g/L (20 ºC)
BRN 1560217
InChIKey UZKWTJUDCOPSNM-UHFFFAOYSA-N
LogP 3.15 at 20℃
CAS DataBase Reference 111-34-2(CAS DataBase Reference)
NIST Chemistry Reference Butane, 1-(ethenyloxy)-(111-34-2)
EPA Substance Registry System Butyl vinyl ether (111-34-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H315-H317
Precautionary statements  P210-P233-P240-P241-P280-P303+P361+P353
Hazard Codes  F
Risk Statements  11-19-2017/11/19
Safety Statements  9-14-16-33
RIDADR  UN 2352 3/PG 2
WGK Germany  2
RTECS  KN5950000
Autoignition Temperature 437 °F
TSCA  Yes
HS Code  2909 19 90
HazardClass  3
PackingGroup  II
Toxicity LD50 orally in Rabbit: 10000 mg/kg LD50 dermal Rabbit 3300 mg/kg
NFPA 704
3
2 1

n-Butyl vinyl ether price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 110299 Butyl vinyl ether contains 0.01% potassium hydroxide as stabilizer, 98% 111-34-2 100ML ₹1810 2022-06-14 Buy
Sigma-Aldrich(India) 110299 Butyl vinyl ether contains 0.01% potassium hydroxide as stabilizer, 98% 111-34-2 500ML ₹2870 2022-06-14 Buy
Sigma-Aldrich(India) 110299 Butyl vinyl ether contains 0.01% potassium hydroxide as stabilizer, 98% 111-34-2 1L ₹4720 2022-06-14 Buy
Sigma-Aldrich(India) 110299 Butyl vinyl ether contains 0.01% potassium hydroxide as stabilizer, 98% 111-34-2 2L ₹9510 2022-06-14 Buy
TCI Chemicals (India) B0746 Butyl Vinyl Ether (stabilized with Trihexylamine) min. 98.0 % 111-34-2 25ML ₹1500 2022-05-26 Buy
Product number Packaging Price Buy
110299 100ML ₹1810 Buy
110299 500ML ₹2870 Buy
110299 1L ₹4720 Buy
110299 2L ₹9510 Buy
B0746 25ML ₹1500 Buy

n-Butyl vinyl ether Chemical Properties,Uses,Production

Chemical Properties

clear liquid

Uses

Synthesis, copolymerization.

General Description

A liquid. Flash point 0°F. Less dense than water. Vapors heavier than air. May irritate skin and eyes. Used to make other chemicals.

Air & Water Reactions

Highly flammable. Slightly soluble in water; soluble in alcohol and ether. Ethers tend to form unstable peroxides when exposed to oxygen. Ethyl, isobutyl, ethyl tert-butyl, and ethyl tert-pentyl ether are particularly hazardous in this respect. Ether peroxides can sometimes be observed as clear crystals deposited on containers or along the surface of the liquid.

Reactivity Profile

Ethers, such as BUTYL VINYL ETHER can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Mildly toxic by ingestion, skin contact, and inhalation. A skin and eye irritant. A very dangerous fire hazard when exposed to heat or flame. To fight fire, use foam, CO2, dry chemical, alcohol foam. Moderately explosive by spontaneous chemical reaction. Can react with oxidizing materials. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHERS.

Potential Exposure

Butyl vinyl ether is an extremely flammable, colorless liquid. ether like odor. Molecular weight 5 100.2; specific gravity (H2O:1) 5 0.8; boiling point 5 94C; freezing/melting point 5 2112.8C; vapor density (air 5 1) 5 3.5; flash point 5 29.4C (oc); Autoignition temperature 5 255C. Hazard identification (based on NFP A-704 M Rating System): Health 2; flammability 3; reactivity 1 ?. Slightly soluble in water

Shipping

UN2352 Butyl vinyl ether, stabilized, Hazard Class: 3; Labels: 3—Flammable liquid.

Purification Methods

After five washings with equal volumes of water to remove alcohols (made slightly alkaline with KOH), the ether is dried with sodium and distilled under vacuum, taking the middle fraction [Coombes & Eley J Chem Soc 3700 1957]. Store it over KOH. [Beilstein 1 IV 2052.]

Incompatibilities

Vapors may form explosive mixture with air. Moderately explosive by spontaneous chemical reaction. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids,

Global( 288)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
BASF India Limited +91-2262785600 +91-2262785600 Maharashtra, India 209 58 Inquiry
AKASH PHARMA EXPORTS +91-9388123451 +91-9846039283 Kerela, India 470 58 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
BASF India Limited 91-22-67127600 Maharashtra, India 138 58 Inquiry
Hebei Mojin Biotechnology Co., Ltd +86 13288715578 +8613288715578 China 12447 58 Inquiry
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