n-Butyl vinyl ether
- CAS No.
- 111-34-2
- Chemical Name:
- n-Butyl vinyl ether
- Synonyms
- BUTYL VINYL ETHER;VINYL BUTYL ETHER;1-(ETHENYLOXY)BUTANE;Polyvinox;butoxy-ethene;(BUTYLOXY)ETHYLENE;Bve;NSC 8264;ai3-24225;agrisynthbve
- CBNumber:
- CB0286024
- Molecular Formula:
- C6H12O
- Molecular Weight:
- 100.16
- MOL File:
- 111-34-2.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/1/27 9:38:02
| Melting point | −92 °C(lit.) |
|---|---|
| Boiling point | 94 °C(lit.) |
| Density | 0.774 g/mL at 25 °C(lit.) |
| vapor density | 3.5 (vs air) |
| vapor pressure | 42 mm Hg ( 20 °C) |
| refractive index |
n |
| Flash point | 15 °F |
| storage temp. | 2-8°C |
| solubility | 3g/l |
| form | Liquid |
| color | Clear |
| explosive limit | 1.2-8.6%(V) |
| Water Solubility | 3 g/L (20 ºC) |
| BRN | 1560217 |
| InChIKey | UZKWTJUDCOPSNM-UHFFFAOYSA-N |
| LogP | 3.15 at 20℃ |
| CAS DataBase Reference | 111-34-2(CAS DataBase Reference) |
| NIST Chemistry Reference | Butane, 1-(ethenyloxy)-(111-34-2) |
| EPA Substance Registry System | Butyl vinyl ether (111-34-2) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H315-H317 | |||||||||
| Precautionary statements | P210-P233-P240-P241-P280-P303+P361+P353 | |||||||||
| Hazard Codes | F | |||||||||
| Risk Statements | 11-19-2017/11/19 | |||||||||
| Safety Statements | 9-14-16-33 | |||||||||
| RIDADR | UN 2352 3/PG 2 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | KN5950000 | |||||||||
| Autoignition Temperature | 437 °F | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 2909 19 90 | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | II | |||||||||
| Hazardous Substances Data | 111-34-2(Hazardous Substances Data) | |||||||||
| Toxicity | LD50 orally in Rabbit: 10000 mg/kg LD50 dermal Rabbit 3300 mg/kg | |||||||||
| NFPA 704 |
|
n-Butyl vinyl ether price More Price(6)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 110299 | Butyl vinyl ether contains 0.01% potassium hydroxide as stabilizer, 98% | 111-34-2 | 100ML | ₹1810 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 110299 | Butyl vinyl ether contains 0.01% potassium hydroxide as stabilizer, 98% | 111-34-2 | 500ML | ₹2870 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 110299 | Butyl vinyl ether contains 0.01% potassium hydroxide as stabilizer, 98% | 111-34-2 | 1L | ₹4720 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 110299 | Butyl vinyl ether contains 0.01% potassium hydroxide as stabilizer, 98% | 111-34-2 | 2L | ₹9510 | 2022-06-14 | Buy |
| TCI Chemicals (India) | B0746 | Butyl Vinyl Ether (stabilized with Trihexylamine) min. 98.0 % | 111-34-2 | 25ML | ₹1500 | 2022-05-26 | Buy |
n-Butyl vinyl ether Chemical Properties,Uses,Production
Chemical Properties
clear liquid
Uses
Synthesis, copolymerization.
General Description
A liquid. Flash point 0°F. Less dense than water. Vapors heavier than air. May irritate skin and eyes. Used to make other chemicals.
Air & Water Reactions
Highly flammable. Slightly soluble in water; soluble in alcohol and ether. Ethers tend to form unstable peroxides when exposed to oxygen. Ethyl, isobutyl, ethyl tert-butyl, and ethyl tert-pentyl ether are particularly hazardous in this respect. Ether peroxides can sometimes be observed as clear crystals deposited on containers or along the surface of the liquid.
Reactivity Profile
Ethers, such as BUTYL VINYL ETHER can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
Health Hazard
Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control may cause pollution.
Fire Hazard
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Safety Profile
Mildly toxic by ingestion, skin contact, and inhalation. A skin and eye irritant. A very dangerous fire hazard when exposed to heat or flame. To fight fire, use foam, CO2, dry chemical, alcohol foam. Moderately explosive by spontaneous chemical reaction. Can react with oxidizing materials. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHERS.
Potential Exposure
Butyl vinyl ether is an extremely flammable, colorless liquid. ether like odor. Molecular weight 5 100.2; specific gravity (H2O:1) 5 0.8; boiling point 5 94C; freezing/melting point 5 2112.8C; vapor density (air 5 1) 5 3.5; flash point 5 29.4C (oc); Autoignition temperature 5 255C. Hazard identification (based on NFP A-704 M Rating System): Health 2; flammability 3; reactivity 1 ?. Slightly soluble in water
Shipping
UN2352 Butyl vinyl ether, stabilized, Hazard Class: 3; Labels: 3—Flammable liquid.
Purification Methods
After five washings with equal volumes of water to remove alcohols (made slightly alkaline with KOH), the ether is dried with sodium and distilled under vacuum, taking the middle fraction [Coombes & Eley J Chem Soc 3700 1957]. Store it over KOH. [Beilstein 1 IV 2052.]
Incompatibilities
Vapors may form explosive mixture with air. Moderately explosive by spontaneous chemical reaction. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids,
n-Butyl vinyl ether Preparation Products And Raw materials
Raw materials
Preparation Products
1of4
chevron_right| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| BASF India Limited | +91-2262785600 +91-2262785600 | Maharashtra, India | 209 | 58 | Inquiry |
| AKASH PHARMA EXPORTS | +91-9388123451 +91-9846039283 | Kerela, India | 470 | 58 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6257 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6768 | 58 | Inquiry |
| BASF India Limited | 91-22-67127600 | Maharashtra, India | 138 | 58 | Inquiry |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615531157085 | China | 8808 | 58 | Inquiry |
| Hebei Mujin Biotechnology Co.,Ltd | +86 13288715578 +8613288715578 | China | 12809 | 58 | Inquiry |
| Baoji Guokang Bio-Technology Co., Ltd. | 0917-3909592 13892490616 | China | 9304 | 58 | Inquiry |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | China | 5868 | 58 | Inquiry |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21628 | 55 | Inquiry |
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