5-METHYL-1,3-BENZODIOXOLE

5-METHYL-1,3-BENZODIOXOLE Structure
CAS No.
7145-99-5
Chemical Name:
5-METHYL-1,3-BENZODIOXOLE
Synonyms
ai3-20481;TIMTEC-BB SBB008152;5-methyl-3-benzodioxole;5-METHYL-1,3-BENZODIOXOLE;3,4-methylenedioxy-toluen;1,3-Benzodioxole, 5-methyl-;3,4-(METHYLENEDIOXY)TOLUENE;5-Methylbenzo[d][1,3]dioxole;4-METHYL-1,2-METHYLENEDIOXYBENZENE;1,2-(Methylenedioxy)-4-methylbenzene
CBNumber:
CB0438748
Molecular Formula:
C8H8O2
Molecular Weight:
136.15
MOL File:
7145-99-5.mol
MSDS File:
SDS
Modify Date:
2023/5/9 9:30:20

5-METHYL-1,3-BENZODIOXOLE Properties

Boiling point 199-200 °C (lit.)
Density 1.135 g/mL at 25 °C (lit.)
refractive index n20/D 1.532(lit.)
Flash point 169 °F
storage temp. 2-8°C
CAS DataBase Reference 7145-99-5(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS07
Signal word  Danger
Hazard statements  H302-H318
Precautionary statements  P264-P270-P280-P301+P312-P305+P351+P338-P501
Hazard Codes  Xn
Risk Statements  22-41
Safety Statements  26-39
WGK Germany  3
RTECS  DF4921090
NFPA 704
2
2 0

5-METHYL-1,3-BENZODIOXOLE Chemical Properties,Uses,Production

Uses

3,4-(Methylenedioxy)toluene can be used as a cation scavenger for the selective cleavage of 4-(3,4-dimethoxyphenyl)benzyl (DMPBn) ethers affording the corresponding deprotected products in the presence of trifluoroacetic acid (TFA) in anhydrous CH2Cl2.
It can also be used as a starting material to prepare:

  • 1,3-Benzodioxole-5-carboxaldehyde via photooxidation using CBr4.
  • 6-Methyl-1,3-benzodioxole-5-carboxaldehyde by treating with dichloromethylmethyl ether and TiCl4.

5-METHYL-1,3-BENZODIOXOLE Preparation Products And Raw materials

5-METHYL-1,3-BENZODIOXOLE Suppliers

Global( 87)Suppliers
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Vihita Chem Private Limited +91-9512002673 +91-9512002673 Gujarat, India 122 58 Inquiry
Roshel Laboratories +91-8310388232 +91-9964951765 Karnataka, India 28 58 Inquiry
CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
Pharmaffiliates Analytics and Synthetics P. Ltd +91-172-5066494 Haryana, India 6773 58 Inquiry
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SHANGHAI T&W PHARMACEUTICAL CO., LTD. +86-021-61551413 +8618813727289 China 5738 58 Inquiry
Dayang Chem (Hangzhou) Co.,Ltd. 571-88938639 +8617705817739 China 52861 58 Inquiry
Aromsyn Co., Ltd. +86-0571-85585865 +8613336024896 China 19185 58 Inquiry
GIHI CHEMICALS CO.,LIMITED +8618058761490 China 49999 58 Inquiry
TIMTEC-BB SBB008152 4-METHYL-1,2-METHYLENEDIOXYBENZENE 5-METHYL-1,3-BENZODIOXOLE 3,4-(METHYLENEDIOXY)TOLUENE 1,3-Benzodioxole, 5-methyl- 3,4-methylenedioxy-toluen 5-methyl-3-benzodioxole ai3-20481 5-Methyl-1,3-benzodioxole~1-Methyl-3,4-(methylenedioxy)benzene 1,2-(Methylenedioxy)-4-methylbenzene 5-Methylbenzo[d][1,3]dioxole 7145-99-5 Building Blocks Organic Building Blocks Oxygen Compounds Protected Alcohols/Phenols Building Blocks Chemical Synthesis Organic Building Blocks Oxygen Compounds Protected Alcohols/Phenols Aromatic Hydrocarbons (substituted) & Derivatives