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2-(TRIMETHYLSILYLOXY)FURAN

2-(TRIMETHYLSILYLOXY)FURAN Structure
CAS No.
61550-02-5
Chemical Name:
2-(TRIMETHYLSILYLOXY)FURAN
Synonyms
TRIMETHYLSILYLOXYFURAN;2-(TRIMETHYLSILOXY)FURAN;2-Furyloxytrimethylsilane;2-(TRIMETHYLSILYLOXY)FURAN;(2-Furyloxy)trimethylsilane;2-(Trimethylsilyloxy)furane;2-(TriMethylsiloxy)furan 97%;Trimethyl(2-furanyloxy)silane;(2-FURANYLOXY)TRIMETHYLSILANE;2-Furyl(trimethylsilyl) ether
CBNumber:
CB0749048
Molecular Formula:
C7H12O2Si
Molecular Weight:
156.25
MOL File:
61550-02-5.mol
MSDS File:
SDS
Modify Date:
2023/6/8 17:06:36

2-(TRIMETHYLSILYLOXY)FURAN Properties

Boiling point 34-35 °C/9 mmHg (lit.)
Density 0.929 g/mL at 25 °C (lit.)
refractive index n20/D 1.436(lit.)
Flash point 76 °F
storage temp. -20°C
solubility sol most organic solvents, e.g. CH2Cl2, Et2O, benzene, THF, MeCN.
form clear liquid
color Colorless to Light orange to Yellow
Specific Gravity 0.950
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
BRN 1423066
CAS DataBase Reference 61550-02-5(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H315-H319-H335
Precautionary statements  P210-P302+P352-P305+P351+P338
Hazard Codes  F,Xi
Risk Statements  11-36/37/38
Safety Statements  26
RIDADR  UN 1993 3/PG 2
WGK Germany  3
10-21
TSCA  No
HS Code  2932.19.5100
HazardClass  3.2
PackingGroup  III
NFPA 704
3
0 0

2-(TRIMETHYLSILYLOXY)FURAN price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 308064 2-(Trimethylsiloxy)furan 97% 61550-02-5 1G ₹5206.83 2022-06-14 Buy
Sigma-Aldrich(India) 308064 2-(Trimethylsiloxy)furan 97% 61550-02-5 5G ₹30071.85 2022-06-14 Buy
TCI Chemicals (India) T1536 2-(Trimethylsilyloxy)furan min. 96.0 % 61550-02-5 5G ₹10800 2022-05-26 Buy
TCI Chemicals (India) T1536 2-(Trimethylsilyloxy)furan min. 96.0 % 61550-02-5 25G ₹37000 2022-05-26 Buy
Product number Packaging Price Buy
308064 1G ₹5206.83 Buy
308064 5G ₹30071.85 Buy
T1536 5G ₹10800 Buy
T1536 25G ₹37000 Buy

2-(TRIMETHYLSILYLOXY)FURAN Chemical Properties,Uses,Production

Physical properties

bp 44–46 °C/17 mmHg; d 0.93 gmL?1.

Uses

2-(Trimethylsilyloxy)furan is a useful reagent for the preparation of natural and synthetic furanones with anticancer activity.

Preparation

Accessible by silylation of 2(5H)-furanone, which is obtained at very low cost by oxidation of furfural.

Purification Methods

Fractionally distil it using a short path column. 1H NMR in CCl4 has : 4.90 (dd, J 1.3Hz, 3H), 6.00 (t, J 3Hz, 4H) and 6.60 (m, 5H). [Yoshii et al. Heterocycles 4 1663 1976.] 4-Trimethylsilyloxy-3-penten-2-one (cis) (acetylacetone enol trimethylsilyl ether) [13257-81-3] M 172.3, b 66-68o/4mm, 61-63o/5mm, d 4 0.917, n D 1.452. Fractionally distil it and store it in glass ampoules which are sealed under N2. It hydrolyses readily in contact with moisture giving, as likely impurities, hexamethyldisiloxane and 2,4-pentanedione. [West J Am Chem Soc 80 3246 1958, Beilstein 4 IV 4003.]

Global( 75)Suppliers
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61550-02-5(2-(TRIMETHYLSILYLOXY)FURAN)Related Search:

TRIMETHYLSILYLOXYFURAN 2-(TRIMETHYLSILOXY)FURAN 2-(TRIMETHYLSILYLOXY)FURAN (2-FURANYLOXY)TRIMETHYLSILANE 2-(TRIMETHYLSILOXY)FURAN, STAB. 2-(Trimethylsilyloxy)furane (2-Furyloxy)trimethylsilane [(2-Furyl)oxy]trimethylsilane 2-Furyl(trimethylsilyl) ether 2-Furyloxytrimethylsilane Trimethyl(2-furanyloxy)silane (furan-2-yloxy)triMethylsilane 2-(TriMethylsiloxy)furan 97% 2- triMethylsilyloxyindane furan Furan, 2-[(trimethylsilyl)oxy]- 61550-02-5 Monoalkoxysilanes Building Blocks Si-O Compounds Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Heterocyclic Building Blocks Furans Monoalkoxysilanes Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Si-O Compounds Synthetic Organic Chemistry Building Blocks Furans Heterocyclic Building Blocks